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π΄= π΄ π π βππ‘ LAB #2 Radioactive decay calculation ;
π΄= π΄ π π βππ‘ π= ππ2 π 1/2 π΄= π΄ π π β π 1/2 π‘ Where as: A= activity at time (t) π΄ π = the initial activity (t=0) π= decay constant t= time π 1/2 = the half-life 1 πΆπ= ππΆπ 1 πΆπ= ππΆπ 1 πΆπ= 10 β6 ππΆπ 1 πΆπ= 3.7Γ π΅π dpm πΆπ=ππ’ππ ππΆπ=ππππππ’πππ ππΆπ=πππππππ’πππ ππΆπ=ππππππ’πππ π΅π=πππππ’ππππ Very Important Note:- A & π΄ π should have the same unit Also, t & π 1/2 should have the same unit For instant, if (A) is in mCi ( π΄ π ) MUST be in mCi And if (t) is in years ( π 1/2 ) MUST be in years
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Example1 :- Given 10 mCi of 32P, which has a half-life of 14.2 days, find the quantity remaining after 60days. π΄= π΄ π π β π 1/2 π‘ π΄ 0 =10ππΆπ, π΄ π‘ =??? π 1/2 =14.2πππ¦π π‘=60πππ¦π π΄ π‘ =10 π βππ π΄ π‘ =10 π β2.93 π΄ π‘ =10Γ0.0534 β΄π΄ π‘ =0.534 ππΆπ Example2 :- if the initial activity of the radionuclide mentioned above was 52 Β΅Ci, then the activity after 4 hours would be: π΄ 0 =52Β΅πΆπ, π΄ π‘ =??? π 1/2 =14.2πππ¦π π‘=4βππ’ππ =0.166 πππ¦π π΄ π‘ =52 π βππ π΄ π‘ =52 π β7.70Γ 10 β3 π΄ π‘ =52Γ0.992 π΄ π‘ =51.6 Β΅πΆπ
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B) To how many MBq does this correspond? (99mTc Half life =6 hr)
Ex.3; A) If 20mCi of 99mTc is needed for a diagnostic test, and if 4 hours elapse between preparing of the radioisotope and its use in the test, how many mCi must be prepared? B) To how many MBq does this correspond? (99mTc Half life =6 hr) π΄= π΄ π π β π 1/2 π‘ π΄ 0 =20ππΆπ, π΄ π‘ =??? π 1/2 =6βπ π‘=β4 βπ A) π΄ π‘ =20 π βππ2 6 β4 π΄ π‘ =20 π 0.46 π΄ π‘ =20Γ1.59 β΄π΄ π‘ =31.8 ππΆπ B) β΄π΄ π‘ =31.8 ππΆπ=0.0318πΆπ= π΅π= ππ΅π
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B) and 4 p.m. on the same day (t1/2 =6 hr) π΄= π΄ π π β0.693 π 1/2 π‘
Ex.4; At 11 a.m. the99mTc radioactivity was measured as 9 mCi on a certain day. What was the activity at 8 a.m. B) and 4 p.m. on the same day (t1/2 =6 hr) π΄= π΄ π π β π 1/2 π‘ π΄ 0 =9ππΆπ, π΄ π‘ =??? π 1/2 =6βπ π΄) π‘ 1 =11ππ π‘π 8ππ=β3 βπ B) π‘ 2 =11ππ π‘π 4ππ=5 βπ A) π΄ π‘ =9 π βππ2 6 β3 π΄ π‘ =9 π 0.35 π΄ π‘ =9Γ1.41 β΄π΄ π‘ =12.7 ππΆπ B) π΄ π‘ =9 π βππ2 6 5 π΄ π‘ =9 π β0.58 π΄ π‘ =9Γ0.56 β΄π΄ π‘ =5.05 ππΆπ
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Ex.5; What is the half-life of an isotope if it decays to 12.5% of its radioactivity in 18 minutes? π΄= π΄ π π β π 1/2 π‘ π΄ 0 =100%, π΄ π‘ =12.5% π 1/2 =??? π‘=18min π΄ π΄ π = π β π 1/2 π‘ π΄ π‘ π΄ π = = π βππ2 π 1/2 18 = π βππ2 π 1/2 18 ππ =ππ π βππ2 π 1/2 18 ππ = βππ2 π 1/2 18 β΄ π 1/2 = βππ2 ππ 12.5/ =6 πππ
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Practice Problems π΄= π΄ π π β0.693 π 1/2 π‘
π΄= π΄ π π β π 1/2 π‘ 1. A Phosphorous-32 source has a half-life of days and had an activity of 75,000 dpm as of 12/2/92. What was the activity as of 12/28/92? π΄ 0 =75,000 πππ, π΄ π‘ =??? π 1/2 =14.28πππ¦ π‘=12/2/92 π‘π 12/28/92=26πππ¦ 2. A 55mCi Sr-90 source was assayed on 6/1/88. What would the activity be on 6/1/93? (The half-life of Sr-90 is 29.1 years) H.W. π΄ 0 =55ππΆπ, π΄ π‘ =??? π 1/2 =29.1π¦ππππ π‘=6/1/88 π‘π 6/1/93=5π¦ππππ 3. An 60 mCi iodine solution of I-131 was created and then left on a laboratory shelf for two weeks before it was used. What was the activity of the solution at the time it was used? (Iodine-131 has a half-life of 8.04 days) π΄ 0 =???, π΄ π‘ =60ππΆπ, π 1/2 =8.04πππ¦π π‘=β 4Γ7 =β28πππ¦π 4. A radon air sample was collected and then counted 4 hours later. If the sample count showed an activity of 5E4 pCi, what was the activity on the sample at the time it was collected? (Radon-222 has a half-life of days) π΄ 0 =???, π΄ π‘ =5πΈ4 ππΆπ π 1/2 = πππ¦π π‘=β 4 24 =0.166 πππ¦π
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Practice Problems π΄= π΄ π π β0.693 π 1/2 π‘
π΄= π΄ π π β π 1/2 π‘ 5. A 10.5 Ci Co-60 radiography source was prepared 3 years ago, having a half-life of years. What is the activity today? π΄ 0 =10.5 πΆπ, π΄ π‘ =??? π 1/2 =5.271 π¦ππππ π‘=3 π¦ππππ βπ‘ππππ¦= π¦ππππ 6. A pure alpha source reads 244,000 dpm today. It is a Po-210 source which has a half-life of days. If the source was manufactured a year ago, what the activity at the time it was manufactured? π΄ 0 = πππ, π΄ π‘ =??? π 1/2 =138.8 πππ¦π π‘=π‘ππππ¦β1π¦πππ πππ= πππ¦π 7. A Cs-137 source has an activity of 750 mCi, with a half-life of years. How long will it take for the source to be read less than 100 mCi? H.W. π΄ 0 =750ππΆπ, π΄ π‘ =100ππΆπ π 1/2 =30.17 π¦ππππ π‘=??? 8. An air sample was collected in a thorium storage building and was counted immediately, yielding 2.5E3 pCi/l. The sample was recounted 5 minutes later giving an activity of only 59.4 pCi/l. What is the half-life and the most likely isotope on the sample? H.W. π΄ 0 =2.5πΈ3ππΆπ/π, π΄ π‘ =59.4ππΆπ/π π =??? π‘=5ππππ
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A curie (Ci) is a deprecated non-SI unit of radioactivity
defined as 1 Ci = 3.7 Γ 10ΒΉβ° decays per second. Therefore, 1 Ci = 3.7Β·10ΒΉβ° Bq (exactly) and 1 Bq = Β·10β»ΒΉΒΉ Ci. One curie is roughly the activity of 1 gram of the radium isotope Β²Β²βΆRa. A becquerel (Bq) is the SI derived unit of radiation activity. The Bq is defined as the activity of a quantity of radioactive material in which one nucleus decays per second. The becquerel is therefore equivalent to an inverse second, sβ»ΒΉ.
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