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Properties of Water
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Chemical Bonds In a water molecule, each hydrogen atom forms a single covalent bond with the oxygen atom. The chemical bond in which electrons are shared between atoms is called a covalent bond. In a water molecule, each hydrogen atom shares two electrons with the oxygen atom.
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Covalent Bonds in the water molecule means electrons are shared between the Oxygen and Hydrogen atoms
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Non-Polar Molecules Covalent Bonds that have equal sharing of electrons make Non-Polar Molecules E.g. Carbon Dioxide (CO2) covalent bonds Oxygen atom (O) Carbon atom (C) Carbon dioxide (CO2 )
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Polar Bonds: unequal sharing of electrons
A water molecule is polar because there is an uneven distribution of electrons between the oxygen and hydrogen atoms. The oxygen end has a slight negative charge and the hydrogen is slightly positive (-) (+) (+)
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Because oxygen has 8 protons in its nucleus and hydrogen only has 1, oxygen has a stronger attraction for electrons than hydrogen. Hydrogen Oxygen
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Draw this “froggy faced” water molecule
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Chemical Bonds Van der Waals Forces: A slight attraction that develops between the oppositely charged areas of nearby molecules
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Chemical Bonds Although van der Waals forces are not as strong as ionic bonds or covalent bonds, they can hold molecules together, especially when there are millions of molecules or the molecules are very large.
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Chemical Bonds Weak forces form between the molecules on the surface of a gecko’s foot and the molecules on the surface of the wall. The combined strength of all these weak forces allows the gecko to grip the wall. Photo Credit: top: Kellar Autumn & Ed Florance; bottom: © Mark Moffett/Minden Pictures, Inc.
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Hydrogen Bonds A type of van der Waals force, Hydrogen Bonds are between Hydrogen and another atom & create weak attractions between oppositely charged areas of a molecule Hydrogen “Bonding” between water molecules gives water some unique properties
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Hydrogen Bond - Because of their partial positive and negative charges, polar molecules like water can attract each other. hydrogen bonds (1: 17 , great overview of H bonds)
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Example: Water molecules
Hydrogen bonds are not as strong as covalent or ionic bonds. Draw this on your notes
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Example: DNA molecules are held together on their inside by billions of weak Hydrogen Bonds
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Hydrogen Bonds: weak polar covalent “bonds”
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A single water molecule may be involved in as many as four hydrogen bonds at a time.
Water’s ability to form multiple hydrogen bonds is responsible for many of its special properties The solid form of water (ice) floats because of the internal spaces created by hydrogen bonds
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Water and Energy Storage
Water absorbs heat more slowly & keeps its heat energy longer (cools off more slowly) than many other substances because of it’s Hydrogen bonds. This affects Earth’s weather patterns- water absorbs heat when its hot, then releases heat when its cold so air temperatures are more stable near large bodies of water
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Fish love water’s unique properties!
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Water and Energy Water can absorb a lot of energy in the form of heat because of its Hydrogen bonds This means it takes a lot of energy and time to heat & boil water because more is needed to break the water to water attractive forces created by hydrogen bonds
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Water and Energy Water releases a lot of energy when it cools down & absorbs a lot of energy as it heats up Organisms use this fact to cool their bodies: Water on the skin carries away heat when the water evaporates into the air
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Cohesion is an attraction between molecules of the same substance.
Because of hydrogen bonds, water is extremely cohesive; water molecules like other water molecules! Water’s cohesion causes water molecules on its surface to be drawn inward, towards each other. This is why drops of water form beads on smooth surfaces.
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Surface Tension Surface Tension is a type of cohesion
Surface Tension (Cohesion) explains why some insects and spiders can walk on a pond's surface.
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Cohesion and Surface Tension
-On the surface of a cup of water, there are few water molecules, so each molecule is very strongly attracted to it’s neighbor. This creates Surface Tension -Deep inside the cup, there are many more water molecules. Each molecule has many neighbors, so its attraction to each neighbor is less strong (weaker) Inside a cup of water
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Adhesion is an attraction between molecules of different substances.
E.g. water and glass The surface of water in a glass graduated cylinder dips in the center because adhesion between water molecules and glass molecules is stronger than cohesion between water molecules.
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Adhesion between water and glass causes water to rise in a narrow tube against the force of gravity.
This effect is called capillary action.
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Capillary action, caused by water’s attraction to plant surfaces (adhesion) draws water out of the roots of a plant and up into its stems and leaves. Cohesion (attraction of water to water) holds the column of water together as it rises.
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Draw this on the back of your notes:
Adhesion: water attracted to other things Cohesion: water to water attraction Adhesion: water attracted to other things
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Properties of Water Videos
The Properties of Water (4:12 H2O in living things biology) Water Structure and Hydrogen Bonding (3:06, cells need water, covalent bonds, + & - ends of H2O, ) hydrogen bonds (1: 17 , great overview of H bonds) Amoeba sisters Properties of Water (6:50 H-bonds, transport in trees-ad&cohesion, walking on water, Universal solvent, floating ice, specific heat, evaporative cooling, )
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Write these on the back of your notes Solutions and Suspensions
A mixture is made of two or more things (elements or compounds) that are physically mixed but not chemically combined Two types of mixtures can be made with water: Solutions and Suspensions
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Write these on the back of your notes Solutions and Suspensions
1. Solution- a type of mixture of two or more substances in which the particles of the substances are evenly spread out or distributed
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Water is the Universal Solvent
Because water is a polar molecule, many things dissolve in water Solvent- dissolving agent of a solution; its present in the larger amount: there’s always more solvent Example: water Solute- substance dissolved in the solvent; there’s less amount of solute Example: Kool-aid
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Solvent and Solute Solute = Sugar Solvent
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Solutions When a crystal of table salt is placed in warm water, sodium and chloride ions are attracted to the polar water molecules. Cl - Cl - Na+ When an ionic compound such as sodium chloride is placed in water, water molecules surround and separate the positive and negative ions. Na+ Water Water Ion: + or – charged atom or molecule
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Ions break away from the crystal and are surrounded by water molecules.
Cl - Cl - Na+ Na+ Water Water The ions gradually become evenly dispersed in the water, forming a solution of salt water
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Polar water mixes well with other charged substances, like NaCl,
but water does NOT mix well with nonpolar (and therefore non-charged) substances, ex. Oil, CO2 (soda)
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Water Loving and Fearing
Add these two words to your Vocab list for Ch 2 Hydrophilic means water loving these substances dissolve in water since they are charged or polar, like water e.g. NaCl Na+ + Cl- (hydro=water, philic=liking, phobic=fearing) Hydrophobic means water “fearing” these substances will NOT dissolve in water because they are nonpolar e.g. oils Add these two words to your Vocab list for Ch 2
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How can we clean oils from our hands and clothes by using water?
Soaps have a split personality They are long molecules with a polar (hydrophilic) end and non-polar (hydrophobic) end. The hydrophobic ends “run” away from water and “hides” inside a hydrophilic cover Soap has a hydrophilic head that is in contact with water and a center of hydrophobic tails, which can be used to isolate grime, which is mostly oil & dirt
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How soaps work The polar end allows soaps to dissolve in water while the non-polar end interacts with oils & move them away from the water The water loving outside can now be washed away with water, carrying away their contained oil particles with them Hydrophilic on the outside Hydrophobic on the inside
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Suspensions: mixture of water and non-dissolved material
Some materials do not dissolve when placed in water but are separate pieces in the liquid, some are so small that they do not settle out but can stay in suspension as long as it is moving The movement of water molecules keeps the small particles suspended.
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Suspensions in Biology
The blood that circulates through your body is mostly water, which contains many dissolved compounds. -Blood also contains blood cells and other undissolved particles that remain in suspension as the blood moves through the body When blood is taken out of circulation, blood cells settle to the to the bottom of a test tube
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Write these on the back of your notes Acids, Bases, and pH
A water molecule can react to form hydrogen (H+) and hydroxide (OH-) ions. Water’s pH is neutral because # H+ = # OH- Water is neutral (pH=7) because the number of positive hydrogen ions (H+) made equals the number of negative hydroxide ions (OH-) made
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pH scale: measurement system used to show the concentration of hydrogen ions (H+) in solution; pH ranges from 0 to 14
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When H+ does NOT equal OH –
Write these on the back of your notes Acids, Bases, and pH When H+ does NOT equal OH – the pH is NOT in balance & we use the pH scale to show how acidic or basic the solution is
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Write these on the back of your notes Acids, Bases, and pH
Properties of Acids & Bases Acid Base - More H More OH- - pH is less than pH is greater than 7 pH < pH > 7
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Water & the pH scale Acid Precipitation is rain, snow, or fog that has a pH lower than 5.6, as low as 1.5. It is created when water reacts with Sulfur and Nitrogen oxides created from burning fossil fuels to created Sulfuric and Nitric Acids. These then lower pH in soils, ponds, and lakes which can then endanger natural ecosystems
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