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ENERGY & CHEMICAL CHANGE
REVISION
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ENTHALPY Energy changes in reactions related to bond energy changes
HEAT OF REACTION (ΔH) as the energy absorbed or released in a chemical reaction.
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ENERGY DIAGRAMS EXOTHERMIC REACTIONS are reactions that release energy. ENDOTHERMIC REACTIONS are reactions that absorb energy
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ENDOTHERMIC REACTIONS
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EXOTHERMIC REACTIONS
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PROPERTIES Activation energy is the minimum energy needed for a reaction to occur. When bonds break energy is absorbed When bonds form energy is released
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PROPERTIES activated complex is the temporary unstablecompound formed when activation energy is reached
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Potential energy of the reactants and products
PROPERTIES Potential energy of the reactants and products
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PROPERTIES Change in enthalpy H
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INFLUENCE OF A CATALYST
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REVISION RATE OF REACTION
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REACTION RATE reaction rate is the change in concentration of reactants or products per unit time.
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Time Mass of beaker
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COLLISION THEORY Chemical reactions occur when reactant particles collide to form product particles Molecules need to collide with the correct orientation Molecules need to collide with enough energy
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MAXWELL-BOLTZMANN DISTRIBUTION CURVE
Reaction rate is directly proportional to the Number of collisions per time Portion with sufficient kinetic energy Portion that collide with the correct orientation
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FACTORS THAT AFFECT THE RATE OF CHEMICAL REACTIONS
nature of reacting substances Concentration Pressure surface area Temperature catalyst
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NATURE OF REACTING SUBSTANCES
1st ionisation energy
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CONCENTRATION & PRESSURE
Higher concentration means more particles, more particles means more collisions, more collisions mean more molecules with EA
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TEMPERATURE High temperature means the particles move faster
it means more collisions between molecules withEA
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CATALYST A catalyst increases the rate of reaction by providing an alternative route with a lower activation energy. It reduces the net / total activation energy positive catalyst is a substance that increases the rate of a chemical reaction without itself undergoing a permanent change
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Chemical reactions occur when reactant particles collide to form product particles
Molecules need to collide with the right orientation Molecules need to collide with enough energy Reaction rate is directly proportional to the Number of collisions per time Portion with sufficient kinetic energy Portion that collide with the correct orientation CONCENTRATION
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CONCENTRATION
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Chemical reactions occur when reactant particles collide to form product particles
Molecules need to collide with the right orientation Molecules need to collide with enough energy Reaction rate is directly proportional to the Number of collisions per time Portion with sufficient kinetic energy Portion that collide with the correct orientation TEMPERATURE
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TEMPERATURE
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Chemical reactions occur when reactant particles collide to form product particles
Molecules need to collide with the right orientation Molecules need to collide with enough energy Reaction rate is directly proportional to the Number of collisions per time Portion with sufficient kinetic energy Portion that collide with the correct orientation SURFACE AREA
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SURFACE AREA
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Chemical reactions occur when reactant particles collide to form product particles
Molecules need to collide with the right orientation Molecules need to collide with enough energy Reaction rate is directly proportional to the Number of collisions per time Portion with sufficient kinetic energy Portion that collide with the correct orientation CATALYST
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CATALYST
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