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Description & importance
CRYSTAL DEFECTS Description & importance
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FUNDAMENTALS Metals are not perfect neither at the macrolevel and nor at the microlevel Contain a number of different types of crystalline defects (at the atomic level) Defects are important in many processes e.g. diffusion, deformation
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TYPES OF DEFECTS A. POINT DEFECTS OR ZERO-DIMENSIONAL DEFECTS
In pure metals In alloys 1. VACANCY 2. SELF-INTERSTITIAL 1. SUBSTITUTIONAL IMPURITY 2. INTERSTITIAL IMPURITY Important in strengthening Important in diffusion
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Mechanism of diffusion
VACANCY
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B. Line defects or one-dimensional defects
Edge dislocation Screw dislocation VERY IMPORTANT IN PLASTIC DEFORMATION
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C. Planar (surface) defects or two-dimensional defects
1. Stacking Fault Perfect stacking Extrinsic stacking fault Intrinsic stacking fault A A A A B B A A A A B B B B A A A A C C C C B B B B A A A A C C C C B B A A A A C C C C B B B B A A A A
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2. Grain Boundaries
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D. Volume defects or three-dimensional defects
Some scientists classify grains as volume defects
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QUESTIONS
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Some basics on alloys Two types Compounds E.g. Fe3C, CuAl2
Solid solutions Substitutional Solid solution E.g. Brass (Cu-Zn) Cu-10%Zn or Cu-30%Zn Interstitial Solid solution E.g. Steel (Fe-C) Fe-0.2%C or Fe-0.4%C Cu Zn Fe C
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PHASE DIAGRAMS
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