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6.6 – NOTES Naming Ionic Compounds

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1 6.6 – NOTES Naming Ionic Compounds

2 3. Naming ionic compounds
a. Monatomic cations are known by their name. For example, Na+ is sodium. b. Monatomic anions have the ending “ide,” which means negative. For example, O-2 is known as oxide. Polyatomic ions have their normal names. c. Cations with more than one oxidation state: the oxidation state must be specified.

3 Traditional naming: makes use of Latin name; uses suffix –ic for higher oxidation state and –ous for lower oxidation state of the metal Stock system: this is one to know; makes use of English name; uses Roman numerals to denote the oxidation state

4 Examples: RbNO2 rubidium nitrite CuSO4 cupric sulfate copper (II) sulfate

5 Fe(HSO4)2 ferrous bisulfate iron (II) bisulfate (NH4)3PO4 ammonium phosphate

6 Al2(SO3)3 aluminum sulfite Pb(CO3)2 lead (IV) carbonate Plumbic carbonate

7 FeCl3 ferric chloride iron (III) chloride SnI4 stannic iodide tin (IV) iodide


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