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Chapter 10 STRUCTURE AND SYNTHESIS OF ALCOHOLS

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Presentation on theme: "Chapter 10 STRUCTURE AND SYNTHESIS OF ALCOHOLS"— Presentation transcript:

1 Chapter 10 STRUCTURE AND SYNTHESIS OF ALCOHOLS

2 NOMENCLATURE OF ALCOHOLS: THE PRIORITY LIST
acids esters aldehydes ketones alcohols amines alkenes alkynes alkanes ethers halides Decreasing priority Chapter 10: Structure and Synthesis of Alcohols

3 BOILING POINTS: A COMPARATIVE STUDY

4 FACTORS INFLUENCING THE ACIDITY OF ALCOHOLS
pKa (in water) 15.5 15.7 15.9 16.5 18.0 Substitution Pattern of R CH3OH H2O CH3CH2OH (CH3)2CHOH (CH3)3COH pKa (in water) 15.9 12.2 18.0 5.4 Inductive Effect CH3CH2OH CCl3CH2OH (CH3)3COH (CF3)3COH pKa (in water) 18.0 10.0 3. Resonance Effect Chapter 10: Structure and Synthesis of Alcohols


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