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Strong vs Weak Acids/Bases

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1 Strong vs Weak Acids/Bases
Strong acids or bases dissociate completely while weaker acids and bases only partially dissociate.

2 Strong vs Weak Acid Strong Acid:
HCl (aq)  H+ (aq) + Cl- (aq) Exists only in the form of ions HCl + H2O  H3O Cl- The actual ion species (Lots of H3O+ ) Weak Acid: CH3COOH (acetic acid-vinegar is 4-18% acetic acid by mass) CH3COOH H2O  H3O CH3COO- (Little of H3O+) Most of the aa is in the combined form to the left of 

3 Experimental Evidence for Strong vs Weak Acids
Solutions with many charged ions will conduct electricity better which can be measured with a qualitative (showing a general change) or quantitative (giving exact numbers) device. The conductivity device shown shows qualitative differences. strong acid weak acid

4 The Organic Acid Group In the COOH group, the doubly bonded oxygen and the other oxygen exert a strong pull on the hydrogen’s electron. Under the right circumstances, this causes the hydrogen proton to leave its electron with the group and split off as a hydrogen ion which then attaches to a water molecule to form a hydronium ion. CH3COOH H2O  CH3COO H3O+

5 Dilute/Concentrated - Not the same as Weak/Strong
Dilute and concentrated refers to the molarity of a solution (particles of acid/base per volume of solution). Weak vs Strong refers to the % ionization of an acid/base. A 10.0 M HF (aq) solution is CONCENTRATED but WEAK. A .001 M HCl (aq) solution is DILUTE but STRONG A 10.0 M HF(aq) solution actually has less H3O+ than a .1M HCl(aq) solution even though it is 100X more concentrated – because it is much less ionized.

6 Using the Table of Relative Strengths of Acids and Bases

7 Using the Table of Relative Strengths of Acids and Bases

8 Neutral Water’s Ionization
H2O + H2O kJ  H3O+ (aq) + OH- (aq) at 25o C

9 Water’s Ionization Constant
H2O + H2O kJ  H3O+ (aq) + OH- (aq) at 25o C Kw = [H3O][OH-] = 1 x 10-14 [H3O] = 1 x 10-7 [OH-] = 1 x 10-7 Note that with neutral water at 25o C, the concentrations of H3O+ and OH- are equal.

10 Water’s [H3O+] Over 25o C H2O + H2O kJ  H3O+ (aq) + OH- (aq) at 25o C At temperatures above 25 C, the equilibrium shifts right. This produces more [H3O+] and [OH-]. More [H3O+] typically means greater acidity but not here. Since the [H3O+] = [OH-] , the water is still neutral (although its pH drops due to the extra hydronium [H3O+] ions).

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