1. Metal-Organic Frameworks for Energy Applications
Hailong Wang, Qi-Long Zhu, Ruqiang Zou, Qiang Xu 
Chem 
Volume 2, Issue 1, Pages (January 2017)
DOI: /j.chempr
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2. Chem 2017 2, 52-80DOI: ( /j.chempr )
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3. Figure 1
Schematic Illustration of MOFs, MOF Composites, and MOF Derivatives as well as Their Conversions
Chem 2017 2, 52-80DOI: ( /j.chempr )
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4. Figure 2 Crystal Structures of Four Representative MOFs (A) MOF-5.
(B) HKUST-1.
(C) Mg-MOF-74.
(D) ZIF-8.
C, gray; O, red; and N, blue. The yellow ball represents the porosities, and the yellow line shows the topology of ZIF-8.
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5. Figure 3
Schematic Illustration of Immobilization of the Au/Ni Nanoparticles by the MIL-101 Matrix by a Double-Solvent Method Combined with a Liquid-Phase Concentration-Controlled Reduction Strategy
Reprinted with permission from Zhu et al.41 Copyright 2013 American Chemical Society.
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6. Figure 4 Photocatalytic H2 Evolution over a POM-Implanted MOF Catalyst
(A) Schematic illustration showing synergistic visible-light excitation of the MOF framework and multi-electron injection into the encapsulated POMs.
(B) Time-dependent HER TONs of a MOF catalyst with methanol as the sacrificial electron donor.
Reprinted with permission from Zhang et al.46 Copyright 2015 American Chemical Society.
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7. Figure 5 Photo-Induced CO2 Reduction over a MOF Catalyst
(A) 3D structure of PCN-222.
(B) Gas sorption isotherms of PCN-222.
(C) Mott-Schottky plots for PCN-222.
(D) Time-dependent amount of HCOO− under visible-light irradiation.
Reprinted with permission from Xu et al.15 Copyright 2015 American Chemical Society.
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8. Figure 6 MOF-Based Proton Conductors
(A) Honeycomb layer structure of {(NH4)2(adp)[Zn2(ox)3]·3H2O}n without showing NH4+, solvent molecules, or hydrogen atoms. Reprinted with permission from Sadakiyo et al.58 Copyright 2009 American Chemical Society.
(B) The crystal structure of MIL-53(Fe and Al). Reprinted with permission from Shigematsu et al.60 Copyright 2011 American Chemical Society.
C, light blue; O, red. The blue atoms show functional groups (–NH2, –OH, or –COOH).
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9. Figure 7 MOF Film for Proton Conduction
(A) Schematic illustration of the nanosheet-constructed MOF nanofilm.
(B and C) Structure model of the MOF nanofilm.
(D) Proton conductivity of the MOF nanofilm under various RH conditions. Inset: proton conductivity versus adsorbed water of the MOF nanofilm under 95% RH.
(E) Least-squares fitting is shown as a solid line. Inset: typical Nyquist plot of the MOF nanofilm measured under 98% RH at room temperature.
Reprinted with permission from Xu et al.64 Copyright 2013 American Chemical Society.
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10. Figure 8
Schematic Illustration of Pyrolysis of the MOF Composite Comprising MIL-101-NH2 Encapsulating Thiourea and Cobalt Chloride in the Nanopores to Yield the Honeycomb-like Porous Catalysts
Reprinted with permission from Zhu et al.74 Copyright 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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11. Figure 9 MOF-Based Supercapacitors
(A) Schematic construction of nMOF supercapacitors. Reprinted with permission from Choi et al.76 Copyright 2014 American Chemical Society.
(B) Structure and nanocrystal morphology of nMOF-867 and comparison of stack capacitances among various EDLC materials. Reprinted with permission from Sheberla et al.79 Copyright 2016 Nature Publishing Group.
(C) A space-filling diagram of idealized Ni3(HITP)2 (Ni, green; F, lime; N, blue; C, gray; B, brown; H, white).
(D) Comparison of BET-surface-area-normalized areal capacitances among various EDLC materials.
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12. Figure 10
Synthetic Scheme for Preparation of MOFs and Their Derivatives
(A) ZIF-8 crystals and NC.
(B) ZIF-67 crystals and GC.
(C) Bimetallic ZIF (BMZIF) and N/Co-doped GC.
(D) Core-shell crystals and
Reprinted with permission from Tang et al.32 Copyright 2015 American Chemical Society.
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13. Figure 11 MOF Derivative and Corresponding Performance as a LIB Anode
(A) Schematic illustration of the synthesis procedure of N-doped graphene analogous particles and model of N doping.
(B) Cycling performance at a current density of 100 mA g−1.
(C) Rate performance at different current densities from 100 to 1,600 mA g−1.
Reprinted with permission from Zheng et al.82 Copyright 2014 Nature Publishing Group.
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14. Figure 12
Crystal Structure of MOF and Corresponding Performance as a LIB Cathode
(A) Crystal structure of {Cu(2,7-AQDC)}n.
(B) Charge-discharge profile of MOF battery.
(C) Cyclic performance of battery in 50 cycles.
(D) Cyclic voltammetry plot of battery.
Reprinted with permission from Zhang et al.87. Copyright 2014 American Chemical Society.
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15. Figure 13
Crystal Structure of MOF and Corresponding Performance in a Li-S Battery
(A) Crystal structure of Ni-MOF.
(B) Cycling performance of Ni-MOF/S composite at 0.1, 0.2, and 0.5 C rates at a voltage range of 1.5–3.0 V and schematic illustration of the interaction between polysulfides and Ni-MOF.
Reprinted with permission from Zheng et al.90 Copyright 2014 American Chemical Society.
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16. Figure 14
Preparation Process of the Porous MoCx Nano-octahedra Used as Electrocatalysts for the HER
Reprinted with permission from Wu et al.94 Copyright 2015 Nature Publishing Group.
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17. Figure 15 Fabrication of Hybrid Co3O4-Carbon Porous Nanowire Arrays
The scale bar represents 5 μm.
Reprinted with permission from Ma et al.100 Copyright 2014 American Chemical Society.
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