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8.3 – NOTES Decomposition
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C. Decomposition reactions a single compound breaks down to produce two or more products
usually requires heat, light, or electricity; air bags inflating is a result of a decomposition reaction (sodium azide) difference b/t heating and burning – heating does not require oxygen, but burning does
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1. Metallic chlorates will produce metal chlorides and oxygen gas;
2 NaClO3 2 NaCl + 3 O2 Ga(ClO3)3 GaCl O2
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2. Carbonates will produce a metal oxide and carbon dioxide;
PbCO3 PbO + CO2 Al2(CO3)3 Al2O3 + 3 CO2
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3. Metallic hydroxides will produce a metal oxide and water vapor
2 LiOH Li2O + H2O Ti(OH)4 TiO2 + 2 H2O
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4. Certain acids will produce a nonmetallic oxide and water; these are the only two Chem I is responsible for knowing; acids are aqueous Carbonic acid H2CO3 H2O + CO2 Sulfurous acid H2SO3 H2O + SO2
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5. Certain metal oxides will produce the elements; metal must be an inactive metal or one with a low reactivity; Au, Ag, Pt, etc.; metal oxides are usually solid 2HgO 2Hg + O2 2Au2O3 4Au + 3O2
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6. Electrolysis of molten salts will produce the elements; molten means liquid
Molten LiBr: 2LiBr 2Li + Br2 CaCl2 Ca + Cl2
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