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Structure and Bonding in Organic Chemistry

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Presentation on theme: "Structure and Bonding in Organic Chemistry"— Presentation transcript:

1 Structure and Bonding in Organic Chemistry
Electron Configurations Lewis Dot Structures Hybridization Orbital depictions

2 Organic Chemist’s Periodic Table

3 Molecular Model of Aspirin

4

5 Nucleus is a Tiny Fraction of the Volume of an Atom

6 Orbitals are Probabilities

7 Electron Configurations

8

9 Ground State Electron Configurations

10 The p Orbital

11 px, py, pz

12 Bonding in H2 Sigma (s) Bond

13 Energy Released When Bond Forms

14 Electron Configuration of Carbon

15 In Ground State 2 bonding sites, 1 lone pair

16 Lewis Dot Structure of Methane

17 sp3 Hybridization 4 Regions of electron Density

18 Hybridization of 1 s and 3 p Orbitals – sp3

19 sp3 is Tetrahedral Geometry Methane

20 Methane Representations

21 All Have the Same Geometry All Have 4 Regions of Electron Density

22 Tetrahedral Geometry

23 Ammonia Tetrahedral Geometry Pyramidal Shape

24

25 Orbital Depiction of Ethane, C2H6 , the s bond

26

27

28 Depictions of 2-Methylbutane

29

30 Bonding Characteristics of Period 2 Elements

31 “Saturated” with Hydrogen

32 A Model of a Saturated Hydrocarbon

33 sp2 Hybridization 3 Regions of Electron Density

34 Hybridization of 1 s and 2 p Orbitals – sp2

35 An sp2 Hybridized Atom

36 The p bond Overlap of 2 parallel p Orbitals

37 Ethylene CH2=CH2

38 Views of Ethylene, C2H4

39 Ethylene

40 Formaldehyde

41 sp Hybridization 2 Regions of Electron Density

42 The sp Orbital

43 Acetylene, C2H2, 1 s bond 2 perpendicular p bonds

44 Drawing Structures

45 Octane Representations

46 Condensed Formulas

47 Line-Angle Structures are Often Used as a Short-hand

48 Line-Angle Structures

49

50 Line-Angle structure Superimposed on Lewis Structure

51 Double Bonds are Shown

52 For Cyclic Structures, Draw the Corresponding Polygon

53 Drawing Clear Structures

54 Structures take Cues from Models

55 Some Steroids

56 Benzene can be drawn as one of two resonance structures

57 Some Line-Angle Structures


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