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Structure and Bonding in Organic Chemistry Electron Configurations Lewis Dot Structures Hybridization Orbital depictions.

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Presentation on theme: "Structure and Bonding in Organic Chemistry Electron Configurations Lewis Dot Structures Hybridization Orbital depictions."— Presentation transcript:

1 Structure and Bonding in Organic Chemistry Electron Configurations Lewis Dot Structures Hybridization Orbital depictions

2 Organic Chemist’s Periodic Table

3 Molecular Model of Aspirin

4

5 Nucleus is a Tiny Fraction of the Volume of an Atom

6 Orbitals are Probabilities

7 2s Orbital Has a Node

8 Bonding in H 2 Sigma (  Bond

9 Wave Depiction of H 2

10 Molecular Orbitals Mathematical Combination of Atomic Orbitals

11 Antibonding Molecular Orbital Destructive Overlap Creates Node

12  and  * of H 2

13 Energy Released When Bond Forms

14

15 Electron Configurations

16

17 Ground State Electron Configurations

18 The p Orbital

19 p x, p y, p z

20 Electron Configuration of Carbon

21 Lewis Dot Structure of Methane

22 All Have the Same Geometry All Have 4 Regions of Electron Density

23 Tetrahderal Geometry

24 Methane Representations

25 In Ground State 2 bonding sites, 1 lone pair

26 sp 3 Hybridization 4 Regions of electron Density link link

27 Hybridization of 1 s and 3 p Orbitals – sp 3

28 sp 3 is Tetrahedral Geometry Methane

29 Ammonia Tetrahedral Geometry Pyramidal Shape

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31 Orbital Depiction of Ethane, C 2 H 6, the  bond

32

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34 Depictions of 2-Methylbutane

35

36 Bonding Characteristics of Period 2 Elements

37 “Saturated” with Hydrogen

38 A Model of a Saturated Hydrocarbon

39 sp 2 Hybridization 3 Regions of Electron Density

40 Hybridization of 1 s and 2 p Orbitals – sp 2

41 An sp 2 Hybridized Atom

42 The  bond Overlap of 2 parallel p Orbitals

43 Ethylene CH 2 =CH 2

44 Views of Ethylene, C 2 H 4

45 Ethylene

46 Formaldehyde

47 sp Hybridization 2 Regions of Electron Density

48 The sp Orbital

49 Acetylene, C 2 H 2, 1  bond 2 perpendicular  bonds

50 Drawing Structures

51 Octane Representations

52 Condensed Formulas

53 Line-Angle Structures are Often Used as a Short-hand

54 Line-Angle Structures

55

56 Line-Angle structure Superimposed on Lewis Structure

57 Double Bonds are Shown

58 For Cyclic Structures, Draw the Corresponding Polygon

59 Drawing Clear Structures

60 Structures take Cues from Models

61 Some Steroids

62 Benzene can be drawn as one of two resonance structures

63 Some Line-Angle Structures


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