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Bonding in Transition Metal Compounds

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Presentation on theme: "Bonding in Transition Metal Compounds"— Presentation transcript:

1 Bonding in Transition Metal Compounds
Does the octet rule (or something like it) work for these compounds? Counting d electrons. CrO42- Ni(NH3)62+ Cr(H2O)5Cl2+

2 Counting d-electron Configurations

3 Bonding in Transition Metal Compounds
Does the octet rule (or something like it) work for these compounds? Counting d electrons. CrO42- Ni(NH3)62+ Cr(H2O)5Cl2+

4 Does the octet rule (or something like it) work for these compounds?
Special Case: Counting d electrons for “organometallics” Fe(CO)5 Ni(CO)4 Cp2Fe Bz2Cr

5 Draw a Lewis Structure for Ni(NH3)62+

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7 Crystal Field Theory

8 Donor-Acceptor MO Theory

9 Molecular Orbital Theory: Full

10 Molecular Orbital Theory: Simple

11 Counting d-electron Configurations

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13 How do we predict/explain transition metal structures?

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