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Other units of concentration
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Dilution Equation MV = MV Molarity (volume) before dilution
= molarity (volume) after dilution How many liters of 12 M H2SO4 do you need to make 1.2 L of .75 M? 12 M (V) = .75 M (1.2 L) V = .075 L (75 mL)
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Mass Percent Mass percent = mass of solute x 100 mass of solution
Or = grams of solute x 100 grams of solute + grams of solvent
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Problem 35 g of NaCl is dissolved in 115 g of water, what is the mass percent? What is the molarity if the final solution has a density of 1.1 g/mL? 35 g / (35g + 115g) x 100 23 % 35 g x 1 mol/ g= mol NaCl 150 g x 1mL / 1.1 g = mL = L M = mol / L M = 4.4 M
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Convert Convert 1.2 M CuSO4 solution to mass percent, if the solution has a density 1.1 g/mL. 1.2 M= 1.2 mol CuSO4 / 1 L solution 1.2 mol x g / 1 mol = g 1 L = 1000 mL x 1.1 g/1 mL = 1100 g of solution Mass percent = g / 1100 g x100 = 17 %
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More practice 55 g of CaCl2 is dissolved in 115 g of water, what is the mass percent? What is the molarity if the final solution has a density of 1.1 g/mL?
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More Convert 1.9 M Ca(NO3)2 solution to mass percent, if the solution has a density 1.3 g/mL.
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Parts per thousand/million etc.
Mass percent can also be called parts per hundred (although it never is) Parts per thousand is the same as mass percent except instead of multiplying by a 100 you multiply by 1000. Parts per million is multiplied by 1,000,000 Pollen counts are normally reported in this
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Mole Fraction
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Mole Fraction (these calculations are not in your book)
Mole Fraction or molar fraction is represented by the Greek letter chi, = mole solute/mole solution
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Convert Convert a 2.3 M of water solution of aluminum nitrate Al(NO3)3 to mole fraction of aluminum nitrate if the density of the solution is 1.14 g/mL. 2.3 M = 2.3 mol Al(NO3)3 /1 L solution 2.3 mol x g/ 1 mol = g Al(NO3)3 1 L = 1000 mL x 1.14 g/1 mL = 1140 g solution 1140 g g = g water g x 1 mol / g = mol = 2.3 mol/ ( ) mol = .060
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Another Convert a 1.4 M solution of strontium sulfate, SrSO4, in water to mole fraction if the density of the solution is 1.24 g/mL. 1.4 M = 1.4 mol SrSO4 /1 L solution 1.4 mol x g/ 1 mol = g SrSO4 1 L = 1000 mL x 1.24 g/1 mL = 1240 g solution 1240 g – g = g water g x 1 mol / g = mol = 1.4 mol/ ( ) mol = .025
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