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ACIDS + BASES
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ACIDS Properties: (other than tasting sour and being corrosive) 1) React with metals 2) React with carbonates 3) Conduct electricity 4) Turn blue litmus paper red 5) Neutralize bases ACIDS ARE CORROSIVE
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1) ACIDS REACT WITH METALS
If you swallowed a penny, what would happen? (DON’T TRY THIS AT HOME!!!) penny hydrochloric acid penny HCl penny acid
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1) ACIDS REACT WITH METALS
2HCl(aq) + Zn(s) H2(g) + ZnCl2(aq)
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2) ACIDS REACT WITH CARBONATES
What happens when you put baking soda (sodium bicarbonate) into vinegar? HC2H3O2(aq) + NaHCO3(aq) CO2(g) + H2O(l) + NaC2H3O2(aq)
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3) ACIDS CONDUCT ELECTRICITY
Acids are made of ions, so in water these ions separate and can conduct electricity Hydrogen ion is what makes an acid acidic HCl(aq) H+(aq) + Cl-(aq)
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IONIZATION IN WATER H+ Cl- H+ Cl- H+ Cl- Strong acids ionize completely in water, while weak acids only ionize slightly
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NEGATIVELY-CHARGED ELECTRODE POSITIVELY-CHARGED ELECTRODE
IONIZATION IN WATER - + H+ H+ NEGATIVELY-CHARGED ELECTRODE Cl- POSITIVELY-CHARGED ELECTRODE Cl- H+ Cl- Cl- H+
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4) ACIDS TURN BLUE LITMUS PAPER RED
Blue litmus paper is an indicator and turns red when it touches acid
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5) ACIDS NEUTRALIZE BASES
Acids can neutralize bases, so adding an acid to a base can neutralize their caustic nature HCl(aq) + NaOH(aq) H2O(l) + NaCl(aq) Hydrochloric acid + sodium hydroxide water + salt (sodium chloride) Corrosive + caustic non-corrosive + non-corrosive
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BASES Properties: (other than tasting bitter, feeling slippery) 1) Conduct electricity 2) Turn red litmus paper blue 3) Turns phenolphthalein pink 4) Neutralize acids BASES ARE CAUSTIC
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1) BASES CONDUCT ELECTRICITY
Bases are made of ions, so in water these ions separate and can conduct electricity hydroxide ion makes bases basic NaOH(aq) Na+(aq) + OH-(aq)
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2) BASES TURN RED LITMUS PAPER BLUE
Red litmus paper is an indicator and turns blue when it touches base
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3) BASES TURN PHENOLPHTALEIN PINK
Phenolphtalein is colourless, and turns pink in bases (above pH 8.2) while remaining colourless in acids.
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4) BASES NEUTRALIZE ACIDS
Bases can neutralize acids, so adding a base to an acid can eliminate their corrosiveness Example: Antacids to neutralize stomach acid 2HCl(aq) + CaCO3(aq) CaCl2(aq) + H2CO3(aq) H2CO3(aq) H2O(l) + CO2(g)
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HOW TO MAKE ACIDS + BASES
ACIDS: 1) Non-metal + oxygen non-metal oxide 2) Non-metal oxide + water ACID! EXAMPLE: N2 + 2O2 2NO2 NO2 + H2O HNO3 BASES: 1) Metal + oxygen Metal oxide 2) Metal oxide + water BASE! EXAMPLE: 2Mg + O2 2MgO MgO + H2O Mg(OH)2
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ACID-BASE INDICATORS Indicators change color depending on whether a substance is acidic or basic
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Different indicators change colour at specific pH ranges
ACID-BASE INDICATORS Different indicators change colour at specific pH ranges
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The strength of an acid or base is measured with pH
power hydrogen pH = power of hydrogen
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pH = -log [H+] pH Logarithm with base 10
Calculating pH pH = -log [H+] Logarithm with base 10 Concentration of hydrogen ions
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At 25°C: From 0 to 14, with 7 being NEUTRAL
pH Scale At 25°C: From 0 to 14, with 7 being NEUTRAL pH < 7 acidic pH = 7 neutral pH > 7 basic
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pH Scale
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pH Scale Every pH level is 10x more concentrated than the level above.
i.e. pH 4 is 10x more concentrated than pH 5 pH 3 is 100x more concentrated than pH 5
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Recall: Polyatomic ions have modified names in acids
ACID NAMING Recall: Polyatomic ions have modified names in acids Polyatomic ion name Acid anion name Example sulfate sulfuric H2SO4 sulfuric acid chlorate chloric HClO3 chloric acid carbonate carbonic H2CO3 carbonic acid phosphate phosphoric H3PO4 phosphoric acid
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Recall: Most acids have hydrogen
ACID NAMING Recall: Most acids have hydrogen 1) Naming: HCl(aq) H2SO4(aq) Sulfuric acid Hydrochloric acid OXYACID BINARY ACID
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H BrO3 = HBrO3(aq) bromic acid ACID NAMING
2) Writing the chemical formula: bromic acid 1 + 1 - H BrO3 = HBrO3(aq)
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ACID NAMING Oxyacids with polyatomic ions that end in “ite” are given the ending “ous” Polyatomic ion name Acid anion name Example sulfite sulfurous H2SO3 sulfurous acid chlorite chlorous HClO2 chlorous acid carbonite carbonous H2CO2 carbonous acid phosphite phosphorous H3PO3 phosphorous acid
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ACID NAMING 1) Naming: HNO2(aq) nitrite = nitrous acid
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H BrO2 = HBrO2(aq) bromous acid ACID NAMING
2) Writing the chemical formula: bromous acid 1 + 1 - H BrO2 = HBrO2(aq)
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HOMEWORK Page 228 # 1, 3 – 8
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