1. Nomenclature of Chemical substance

2. Nomenclature of Hydrocarbon International Union of Pure and Applied Chemistry (IUPAC) The IUPAC name of an alkane with an unbranched chain of carbon atoms consists of two parts: －－ a prefix that indicates the number of carbon atoms in the chain; －－ the ending that indicates the species

3. Nomenclature of Hydrocarbon Prefixs used in the IUPAC system to indicate one to 20 carbon atoms in a chain

4. Nomenclature of Hydrocarbon 烷烃（ Alkanes ）： -ane 甲烷－ methane, 乙烷－ ethane, 己烷－ hexane 烷烃基（烷基－ alkyl ） 方法：删去 -ane ，加上 -yl ； 如甲基： methyl ； 乙基： ethyl ； 正丁基： n-butyl ； 异丙基： iso-propyl; (n-: normol, 正； iso- ：异； neo- ：新 ) 命名原则 alphabetical order 3-ethyl-3-methyl-pentane 表示相同的基团数 3,3-dimethyl-pentane ( 2:di-, 3:tri-, 4:tetre-, 5:penta-; 6:hexa- …….) 在字母序中不考虑表示数字的字.

5. Nomenclature of Hydrocarbon 烯烃 (Alkenes) ： -ene 乙烯－ ethene ；丙稀－ propene ；戊烯－ pentene. 双键的位置： 2-pentene ； 2-methyl-2-pentene. 1,3 －丁二烯－ 1,3-butadiene 烯烃基（ alkylene ） 乙烯基： vinyl 氯乙烯－ vinyl chloride 炔烃 (Alkynes) ： -yne 乙炔－ ethyne 丙炔－ propyne; 4- 甲基 -2- 己炔－ 4-methyl-2-hexyne

6. Nomenclature of Derivative 醇（ Alcohols ）： -ol 乙醇－ ethanol, 异丙醇－ iso-propanol, HOCH 2 CH 2 OH: 1,2-ethanediol (ethylene glycol); CH 3 CH(OH)CH 2 OH: 1,2-propanediol (propylene glycol); HOCH 2 CH(OH)CH 2 OH: 1,2,3-propanetriol (glycerol). 醚（ Ethers ） 烷烃为母链，烷氧基为取代基 (OR) ， 烷氧基的命名：数字前缀加 oxy, 如甲氧基： methoxy; 乙氧基 ethoxy; C-C-C-O-C-C-C-C － propoxybutane. 氧两边的烷基为取代基，醚作母链： 丙基丁基醚－ propyl butyl ether 特例： 乙醚－ CH 3 CH 2 OCH 2 CH 3 : diethyl ether, ethyl ether, ether

7. Nomenclature of Derivative 胺（ Amines ） 以胺为母体－ amine; 乙胺－ ethylamine; 丙胺－ propylamine 以胺为取代基： amino- ；乙胺－ aminoethane; 丙胺－ aminopropane (CH 3 ) 2 CHCH 2 CH 2 NH 2 － 1-amino-3-methylbutane (isopentylamine) CH 3 CH 2 CH 2 CH(CH 3 )CH 2 NHCH 3 － N-methyl-1-amino-2-methylpentane NH 2 (CH 2 ) 6 NH 2 － 1,6-diaminohexane (hexamethylenediamino) 如有几个取代基，胺基作 amino- ； 4- 胺基苯酚－ 4-aminophenol. 苯胺： aniline ；４ - 氯 - 苯胺－ 4-chloroaniline (p-chloroaniline) 四甲基氢氧化铵： Tetramethylammonium hydroxide 三甲基戊基碘化铵 trimethylpentylammonium iodide

8. Nomenclature of Derivative 醛（ Aldehydes ）： -al CH 3 CH 2 CHO: propanal; (CH 3 ) 2 CHCH 2 CHO: 3-methylbutanal; CH 3 CH 2 CH(CH 3 )CHO: 2-methylbutanal 苯甲醛－ benzaldehyd e （俗名） 不饱和醛： -enal H 2 C=CH-CHO: propenal CHO-CH=(CH 3 )CCH 2 CH 2 CH=C(CH 3 )CHO 3,7-dimethyl-2,6-octadienal. 酮（ Ketones ）酮作母体 : -one 丙酮－ 2-propanone ； 4- 甲基 -3- 己酮－ 4-methyl-3-hexanone ２ - 甲基 - 环己酮－ 2-methyl-cyclohexanone

9. Nomenclature of Derivative 羧酸 (Carboxylic acid) 饱和酸： -anoic acid 甲酸－ methanoic acid ( 俗名： formic acid); 乙酸－ ethanoic acid ( 俗名： acetic acid) 3- 甲基 - 丁酸－ 3-methyl-butanoic acid 不饱和酸： -enoic acid 丙烯酸－ 2-propenoic acid; 3- 苯基 -2- 丙烯酸－ 3-phenyl-2-propenoic acid 5- 羟基 - 己酸－ 5-hydroxyhexanoic acid 5- 羰基 - 己酸－ 5-oxo-hexanoic acid 二羧酸： -dioic acid 柠檬酸－ 2-hydroxy-1,2,3-propanetricarboxylic acid (citric acid) 酸酐 （ Acid anhydrides ） : oic anhydride 乙酸酐－ ethanoic anhydride (acetic anhydride)

10. Nomenclature of Derivative The order of precedence of serval functional group 3- 羰基 - 丁醇－ 3-hydroxy-butanone 5-hydroxyhexanoic acid 苯甲酸－ benzoic acid

11. Nomenclature of Derivative 酯（ Esters ） The examples of derivation of names of esters 酰卤（ Acid halides ） -oyl 乙酰氯： CH 3 COCl ethanoyl chloride (acetyl chloride) 苯甲酰溴： benzoyl bromide （ benzene ） 酰胺：乙酰胺： acetamide

12. Nomenclature of Derivative 酯（ Esters ） The examples of derivation of names of esters 酰卤（ Acid halides ） -oyl 乙酰氯： CH 3 COCl ethanoyl chloride (acetyl chloride) 苯甲酰溴： benzoyl bromide （ benzene ） 酰胺：乙酰胺： acetamide

13. Unit Two Inorganic Chemistry Lesson One The Nomenclature of Inorganic Compounds PrefixesNumber of Atoms mono- or mon-1 di-2 tri-3 tetra- or tetr-4 penta- or pent-5 hexa-6 hepta-7 octa-8 nona-9 deca-10

14. Unit Two Inorganic Chemistry Lesson One The Nomenclature of Inorganic Compounds Naming Binary Compounds of Nonmetals 氧化物： oxide (oxygen); 氮化物： nitride (nitrogen) ； 五氧化二磷： diphosphoric pentoxide; 氧化二氮： dinitrogen oxide 五氧化二氮： dinitrogen pentoxide 卤化物 氯化物 : chloride (chlorine) 氟化物： fluoride (fluorine) 溴化物： bromide (bromine) 碘化物： iodide (iodine)

22. ClO4-perchlorate ion ClO3-chlorate ionClO2-chlorite ionClO- hypochlorite ion

23. Unit Two Inorganic Chemistry Lesson One The Nomenclature of Inorganic Compounds Naming Ionic Compounds Ionic compounds are composed of cations and anions. 阳离子（ Names of Cations ） Na +, sodium ion; Fe 2+ and Fe 3+, iron (II) ion and iron (III) ion, rescpectively. 铜离子 copper (II) ion, copper (I) ion; 阴离子（ Names of anions ） F - － fluoride; Cl - － chloride; Br - － bromide; I - － iodide; N -3 － nitride ； O= － oxide 含氧阴离子： -ate 硝酸根离子 NO 3- － nitrate ； 亚硝酸根离子 NO 2 － － nitrite ； 硫酸根离子 SO 4 2- － sulfate ；亚硫酸根离子 SO 3 2- － sulfite. 含氢阴离子：加上 hydrogen HS - － hydrogen sulfide ion HCO 3- － hydrogen carbonate ion

24. Nomenclature of inorganic substances 卤素含氧酸根阴离子： 高氯酸 ClO 4 － － perchlorate ；氯酸 ClO 3 － － chlorate 亚氯酸 ClO 2 － － chlorite ； 次氯酸 ClO － － hypochlorite -- 化物： -ide 氧化物： oxide (oxygen); 氮化物： nitride (nitrogen) ； 氧化钙 : calcium oxide 氯化物 — chloride (chlorine) CaCl 2 calcium chloride 氟化物 — fluoride (fluorine) CaF 2 calcium fluoride 溴化物 — bromide (bromine) CaBr 2 calcium bromide 碘化物 — iodide (iodine) CaI 2 calcium iodide

25. Nomenclature of inorganic substances 卤素含氧酸根阴离子： 高氯酸 ClO 4 － － perchlorate ；氯酸 ClO 3 － － chlorate 亚氯酸 ClO 2 － － chlorite ； 次氯酸 ClO － － hypochlorite ChlorateClO 3- BromateBrO 3- IodateIO 3- NitrateNO 3- PhosphatePO 4 3- SulfateSO 4 2- CarbonateCO 3 2-

26. Unit Two Inorganic Chemistry 含氧酸根阴离子： Special anions CrO 4 2- Chromate Cr 2 O 7 2- Dichromate MnO 4 - Permanganate C 2 H 3 O 2- Acetate CN - Cyanide OH - Hydroxide O 2 2- Peroxide

27. Nomenclature of inorganic substances Naming Inorganic Acids Monatomic anions Cl - chlorideS 2- sulfideP 3- phosphideF-F- fluoride Polyatomic ions NH 4 + ammoniumH3O+H3O+ hydr-oxoniumNO 3 -nitrateNO 2 - nitrite ClO - hypochloriteClO 2 - chloriteClO 3 -chlorateClO 4 - perchlorate SO 3 2- sulfiteSO 4 2- sulfateHSO 3 - bisulfiteHCO 3 - bicarbonate CO 3 2- carbonatePO 4 3- phosphateHPO 4 2- hydrogen phosphate H 2 PO 4 - dihydrogen phosphate CrO 4 2- chromateCr 2 O 7 2- dichromateBO 3 3- orthoborateAsO 4 3- arsenate C 2 O 4 2- oxalateCN - cyanideSCN - thiocyanateMnO 4 - permanganate

28. Nomenclature of inorganic substances 离子化合物的命名 （ Names of ionic compounds ） CuSO 4 · 5H 2 O － copper (II) sulfate pentahydrate The number of cations and anions per formula need not be included in the compound name because anions have characteristic charges, and the charge of the cation has already been established by its name. There are as many cations and anions as needed to get a neutral compound with the lowest possible integral subscripts.

29. Nomenclature of inorganic substances Naming Inorganic Acids Replace the -ate ending of an anion with “ -ic acid ” or replace the -ite ending with “ -ous acid. ” If the anion ends in -ide, add the prefix hydro- and change the ending to “ -ic acid. ”

30. Naming Acid Salts The anions of acid salt are named with the word “ hydrogen ” placed before the name of the normal anion. HSO 4 - is the hydrogen sulfate ion. To denote two atoms, the prefix di- is used. HPO 4 2- is the hydrogen phosphate ion, while H 2 PO 4 - is the dihydrogen phosphate ion. In an older naming system, the prefix bi- was used instead of the word hydrogen when one of two hydrogen atoms was replaced. Thus, HCO 3 - was called the bicarbonate ion instead of the more modern name, hydrogen carbonate ion. Nomenclature of inorganic substances

31. Naming Hydrates Some stable ionic compounds are capable of bonding to a certain number of molecules of water per formula unit. Thus, copper (II) sulfate forms the stable CuSO 4 ·5H 2 O, with five molecules of water per CuSO4 unit. This type of compound is called a hydrate. The name of the compound is the name of the anhydrous (without water) compound with a designation for the number of water molecules appended. Thus, CuSO 4 ·5H 2 O is called copper(II) sulfate pentahydrate. The 5 multiples everything after it until the next centered dot or the end of the formula. Thus, included in CuSO 4 ·5H 2 O are ten H atoms and nine O atoms (five from the water and four in the sulfate ion).

32. International Union Of Pure And Applied Chemistry ---- --IUPAC 无机化学命名法 IUPAC 2005 年推荐 (Nomenclature of Inorganic Chemistry – IUPAC Recommendations 2005)

33. IUPAC Nomenclature of Inorganic Chemistry, commonly referred to by chemists as the Red Book, is a collection of recommendations on inorganic chemical nomenclature published at irregular intervals by the International Union of Pure and Applied Chemistry (IUPAC). The last full edition was published in 2005, in both paper and electronic versions. A revision of the Red Book was therefore initiated in 1998. This revised Red Book will supersede not only the 1990 Red Book but also, where appropriate, Nomenclature of Inorganic Chemistry II -Recommendations 2000 (Red Book II). One of the main changes from the old Red Book is the different organization of material, adopted to improve clarity. Overall, the emphasis on additive nomenclature (generalized from the classical nomenclature of coordination compounds) which was already apparent in the 1990 Red Book, is reinforced. The reader facing the problem of how to name a given compound or species may find help in several ways. A flowchart is provided which will in most cases guide the user to a section or chapter where rules can be found for generating at least one possible name. A more detailed subject index is also provided, as well as an extended guide to possible alternative names of a wide range of simple inorganic compounds.

34. Name the following compounds by the IUPAC system (1)(CH 3 ) 2 CH-CH 2 -CHOH-(CH 3 ) 2 (2)CH 2 (OH)-CH (OH)- CH 2 (OH) (3)CH 2 =CH-CH=CH-CH= CH 2 (4)CH 3 - CH 2 -O-CH 2 -CH 2 -CH 3 (5)CH 3 -CH 2 -COONH 2 (CH 3 ) 2 (6)CH 3 - CH 2 -COCl (7)CH 2 OH-CHOH -CH 2 -N(CH 3 ) 2 (8)CH 3 - CHBr-CHBr-CH 2 -CH 2 -COOH (9) (10) CH 3 - CHBr-CHBr-CH 2 -CH 2 -COOH