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base line corrections linearnon-linear linear base line with step in c p.

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Presentation on theme: "base line corrections linearnon-linear linear base line with step in c p."— Presentation transcript:

1

2 base line corrections linearnon-linear linear base line with step in c p

3 leading edge of a standard like In or H 2 0 onset narrow peak broad peak onset maximum end glass transition ½ of step hight 1 st order transitions

4 Table of Content Introduction Basics of Calorimetry Thermal Transitions Examples Transitions Phase Diagrams Miscibility Thermal History

5 Calorimetric Analysis of Polymers course of polymerization transreactions chain scission radiation induced degradation thermal degradation chain stripping leaving carbonaceous residue curing of thermosets... Phase behaviour (estimation of a phase diagram) mesophase behaviour (processing) history (themoreversible) gelation thermal transitions (Tg, Tm, Tcr...) bound water in hydrogels crystallization and ordering...

6 Thermal Transitions transition temperatures, transition enthalpie glass transitioncold crystallizationrecrystallization crystallization melting brittle/viscous miscibility thermal history polymorphism mesophases phase diagram kinetics degree of crystallization purity


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