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Published byJeffery McLaughlin Modified over 8 years ago
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Solubility How much of a solute will dissolve in a solvent at a given temperature High solubility – soluble more solute dissolves Low solubility – insoluble Less solute dissolves Saturated Solution Contains as much solute as can possibly be dissolved under the existing conditions of T and P
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Solubility (Table G and F) Unsaturated Solution Contains less than the max amount of solute that can be dissolved Supersaturated Solution Contains a greater amount of solute than is needed to form saturated solution Very unstable Solute will recrystallize
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Factors that Affect Solubility Nature of solute and solvent “ like dissolves like” Polar solvents dissolve polar solutes (and ionic solutes) Water, alcohol, and ammonia dissolve salt Nonpolar solvents dissolve nonpolar solutes Oil, hexane, and benzene are nonpolar solvents Temperature Solutions of solids dissolved in liquids (salt in water) Increase T, increase solubility Decrease T, decrease solubility Solutions of gases dissolved in liquids (CO 2 in soda) Increase T, decrease solubility Decrease T, increase solubility
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Factors that Affect Solubility Pressure Only affects gases in liquids Increase P, increase solubility of gas
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Rate of a Substance Dissolving Surface Area Increase surface area, increase rate of dissolving Powered form produces greatest rate Stirring Increases the rate of dissolving Temperature See previous notes
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Table G
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Colligative Properties Properties that are based on the amount of a substance present When a solute is added to water (such as salt) it interferes with the water’s ability to freeze or boil FP/MP is lowered which means that ice will melt at a lower T than normal BP is raised above normal boiling point
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Colligative Properties Molecular vs. Ionic Solutes Molecular substances (like sugar) do not produce ions when dissolved in water Therefore they do not have as great of an effect on MP/FP/BP as ionic solutes do Ionic solutes will dissolve into ions therefore they produce more particles in solution And will have a greater effect on MP/FP/BP The more ions produced the greater the effect MgCl 2 has a greater effect than NaCl because it makes more ions in solution The more concentrated a solution is, the greater the effect on MP/FP/BP A 2M solution has a greater effect than a 1M solution
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