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Ch. 15 - Solutions I. How Solutions Form Definitions Types of Solutions Dissolving Rate of Dissolving
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A. Definitions Solution - Solution - homogeneous mixture Solvent Solvent - present in greater amount Solute Solute - substance being dissolved
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A. Definitions Solute Solute - KMnO 4 Solvent Solvent - H 2 O
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B. Types of Solutions Based on state of solvent. All solid-liquid-gas combos are possible. EX: dental amalgam (alloy of silver, mercury, etc.) liquid solute, solid solvent solid solution
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C. Dissolving Solvation occurs at the surface of the solute solvent particles surround solute particles (+/- attraction) solute particles are pulled into solution
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C. Dissolving NaCl dissolving in water
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D. Rate of Solution Solids dissolve faster... more stirring small particle size (increased surface area) high temperature
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D. Rate of Solution Gases dissolve faster... no shaking or stirring high pressure low temperature
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A. Concentration Concentrated solution large amount of solute Dilute solution small amount of solute
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A. Concentration % by Volume usu. liquid in liquid EX: 10% juice = 10mL juice + 90mL water % by Mass usu. solid in liquid EX: 20% NaCl = 20g NaCl + 80g water
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A. Concentration SATURATED SOLUTION no more solute dissolves UNSATURATED SOLUTION more solute dissolves SUPERSATURATED SOLUTION becomes unstable, crystals form concentration
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B. Solubility Solubility maximum grams of solute that will dissolve in 100 g of solvent at a given temperature varies with temperature based on a saturated solution
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B. Solubility Solubility Curve shows the dependence of solubility on temperature
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B. Solubility Solids are more soluble at... high temperatures. Gases are more soluble at... low temperatures. high pressures (Henry’s Law).
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Ch. 15 - Solutions III. Particles in Solution “Like Dissolves Like” Electrolytes Colligative Properties
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A. “Like Dissolves Like” NONPOLAR POLAR Detergents polar “head” with long nonpolar “tail” can dissolve both types
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B. Electrolytes Electrolyte Non- Electrolyte solute exists as ions only - + salt - + sugar solute exists as molecules only - + acetic acid Weak Electrolyte solute exists as ions and molecules
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B. Electrolytes Dissociation separation of +/- ions when an ionic compound dissolves in water
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B. Electrolytes Ionization breaking apart of polar covalent molecules into ions when dissolving in water
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C. Colligative Properties properties of solutions that depend only on solute concentration Freezing Point Depression solutes lower the f.p. of a solvent Boiling Point Elevation solutes raise the b.p. of a solvent
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C. Colligative Properties View Flash animation.Flash animation Freezing Point Depression
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C. Colligative Properties Solute particles “get in the way.” Boiling Point Elevation
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C. Colligative Properties Effect increases as the solute concentration increases. Uses: antifreeze making ice cream salting icy roads
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