Chapter 11(b) Properties of Solutions (cont’d). Copyright © Houghton Mifflin Company. All rights reserved.11b–2.

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Presentation transcript:

Chapter 11(b) Properties of Solutions (cont’d)

Copyright © Houghton Mifflin Company. All rights reserved.11b–2

Copyright © Houghton Mifflin Company. All rights reserved.11b–3 Figure 11.14: Phase diagrams for pure water (red lines) and for an aqueous solution containing a nonvolatile solute (blue lines).

Copyright © Houghton Mifflin Company. All rights reserved.11b–4

Copyright © Houghton Mifflin Company. All rights reserved.11b–5 Figure 11.15: (a) Ice in equilibrium with liquid water. (b) Ice in equilibrium with liquid water containing a dissolved solute (shown in pink).

The addition of antifreeze lowers the freezing point of water in a car’s radiator.

Figure 11.16: A tube with a bulb on the end that is covered by a semipermeable membrane.

Figure 11.17: The normal flow of solvent into the solution (osmosis) can be prevented by applying an external pressure to the solution. The minimum pressure required to stop the osmosis is equal to the osmotic pressure of the solution.

Copyright © Houghton Mifflin Company. All rights reserved.11b–9 Figure 11.18: (a) A pure solvent and its solution (containing a nonvolatile solute) are separated by a semipermeable membrane through which solvent molecules (blue) can pass but solute molecules (green) cannot. The rate of solvent transfer is greater from solvent to solution than from solution to solvent. (b) The system at equilibrium, where the rate of solvent transfer is the same in both directions.

Copyright © Houghton Mifflin Company. All rights reserved.11b–10 Figure 11.19: Representation of the functioning of an artificial kidney.

Figure 11.20: Reverse osmosis.

Copyright © Houghton Mifflin Company. All rights reserved.11b–12 Figure 11.21: (a) Residents of Catalina Island off the coast of southern California are benefiting from a new desalination plant that can supply 132,000 gallons a day, or one-third of the island's daily needs. (b) Machinery in the desalination plant for Catalina Island.

Copyright © Houghton Mifflin Company. All rights reserved.11b–13 Figure 11.22: In an aqueous solution a few ions aggregate, forming ion pairs that behave as a unit.

Copyright © Houghton Mifflin Company. All rights reserved.11b–14

Copyright © Houghton Mifflin Company. All rights reserved.11b–15 Figure 11.23: The Tyndall effect.

Copyright © Houghton Mifflin Company. All rights reserved.11b–16

Copyright © Houghton Mifflin Company. All rights reserved.11b–17 Figure 11.24: A representation of two colloidal particles.

Figure 11.25: The Cottrell precipitator installed in a smokestack. The charged plates attract the colloidal particles because of their ion layers and thus remove them from the smoke.