 Motivation  Cd 3 As 2, being a Dirac-type semimetal (DTS), is of considerable research interest due to its high electron mobility, and being a 3D analogue.

Slides:



Advertisements
Similar presentations
Room Temperature Tunneling Behaviors of Boron Nitride Nanotubes Functionalized with Gold Quantum Dots CNMS User Project Highlight Scientific Achievement.
Advertisements

FABRICATION PROCESSES
Behaviour of Ruthenium in high temperature oxidising conditions Ulrika Backman & Ari Auvinen & Jorma Jokiniemi & Maija Lipponen& Riitta Zilliacus SAFIR.
Preparation & Characterization of heterogeneous catalyst
Structural Properties of Electron Beam Deposited CIGS Thin Films Author 1, Author 2, Author 3, Author 4 a Department of Electronics, Erode Arts College,
OPOLEOpole University Institute of Physics, Plasma Spectroscopy Group I am from.. 1.
For the exclusive use of adopters of the book Introduction to Microelectronic Fabrication, Second Edition by Richard C. Jaeger. ISBN © 2002.
Section 12.4: Phase Changes
1 Microelectronics Processing Course - J. Salzman - Jan Microelectronics Processing Oxidation.
High-temperatures in-situ XRD studies of CrN and TiN films Experimental: XRD at high T Experimental: XRD at high T XRD patterns, lattice parameter evolution.
Transport phenomena in chemical processes part II Michał Araszkiewicz PhD.
MSE-630 Dopant Diffusion Topics: Doping methods Resistivity and Resistivity/square Dopant Diffusion Calculations -Gaussian solutions -Error function solutions.
Surface Characterization by Spectroscopy and Microscopy
SEM microscope By: Doug, Holly & Oleg. Scanning Electron Microscope vs. Optical Microscope Advantages Continuously variable magnification High resolution.
The Deposition Process

ECE/ChE 4752: Microelectronics Processing Laboratory
Thin Film Deposition Prof. Dr. Ir. Djoko Hartanto MSc
 Molar Mass And Molar Mass Distribution Molecular Weight Determination Laser Light Scattering Chromatography Size Exclusion (GPC) Mass Spectroscopy.
Internal Flow: Mass Transfer Chapter 8 Section 8.9.
EE143 – Ali Javey Section 5: Thin Film Deposition Part 2: Chemical Methods Jaeger Chapter 6.
Bader Al Salman Abstract In this work, we use chemical vapor deposition (CVD) technique to synthesize CdS 1D-nanostructures (nanobelts & Sea-Urchin like.
Atomic Emission Spectrometry
State of Matter Exam Review Rules for the Game 1.Everyone must solve the problem. 2.Everyone must agree on the final answer 3.Final answers are written.
Using Dilution Refrigerator Technology to perform experiments on MoS2 Mateusz Zuba, Chen, Yung-Fu, State University of New York at Oswego  Motivation.
Lecture 12.0 Deposition. Materials Deposited Dielectrics –SiO2, BSG Metals –W, Cu, Al Semiconductors –Poly silicon (doped) Barrier Layers –Nitrides (TaN,
Heuristics for Process Design
Shamil Baldeosingh Dasney Joseph Walter McKinley March 4 th, 2010 EML 4905 Senior Design Project Advisor: Dr. K. H. Wu March 24,
PREPARATION OF ZnO NANOWIRES BY ELECTROCHEMICAL DEPOSITION
Zn x Cd 1-x S thin films were characterized to obtain high quality films deposited by RF magnetron sputtering system. This is the first time report of.
Vapor-Liquid-Solid Growth of ZnSiN2
Growth and Analysis of MOCVD Grown Crystalline GaAs Andrew Howard, Dr. S. Phillip Ahrenkiel SDSM&T Nanoscience Department NSF REU Grant # Objectives.
Phase Rule and Phase Equilibria
Chapter 13: States of Matter
Methods in Surface Physics Experimentation in Ultra-High Vacuum Environments Hasan Khan (University of Rochester), Dr. Meng-Fan Luo (National Central University)
Carrier Mobility and Velocity
Crystal Growth Techniques
Synthesis Rutile titania nanofibers are synthesized using electrospinning and sol-gel coating techniques. A large sheet of nylon-6 nanofibers are synthesized.
Gas-to Solid Processing surface Heat Treating Carburizing is a surface heat treating process in which the carbon content of the surface of.
Chapter 13: States of Matter
Technology Thin films ZnO:Al were prepared by RF diode sputtering from ZnO + 2wt % Al 2 O 3 target. It is a plasma assisted deposition method which involves.
States of Matter Section 1: Matter. A. Matter - anything that takes up space and has mass; matter is composed of tiny particles.
STAR Testing Review 8th Grade Science Structure of Matter Periodic Table Structure of Matter Periodic Table.
Sputter deposition.
Reminders Quiz#2 and meet Alissa and Mine on Wednesday –Quiz covers Bonding, 0-D, 1-D, 2-D, Lab #2 –Multiple choice, short answer, long answer (graphical.
University of Arkansas Fayetteville, Arkansas Plasma Diagnostics for the Deposition of Nanomaterials (Alumina) Jay Mehta Undergraduate.
Scanning capacitance microscopy
Scanning Electron Microscopy
Conventional SEM Specimen at high vacuum – requires sample fixation and dehydration or freezing. Charging is minimized by coating sample with metal or.
Conductive epitaxial ZnO layers by ALD Conductive epitaxial ZnO layers by ALD Zs. Baji, Z. Lábadi, Zs. E. Horváth, I. Bársony Research Centre for Natural.
M.S. Hossain, N.A. Khan, M. Akhtaruzzaman, A. R. M. Alamoud and N. Amin Solar Energy Research Institute (SERI) Universiti Kebangsaan Malaysia (UKM) Selangor,
Laser drilling of a Copper Mesh
Robust Synthesis of Nanostructures C.F.Jeff Wu* Georgia Institute of Technology (joint with Tirthankar Dasgupta*, Christopher Ma +, Roshan Joseph*, Z L.
Influence of deposition conditions on the thermal stability of ZnO:Al films grown by rf magnetron sputtering Adviser : Shang-Chou Chang Co-Adviser : Tien-Chai.
Atomic Absorption Spectroscopy
The 3 States of Matter. Kinetic Theory : Concepts for “States” of Matter All atoms and molecules are always in Motion Molecules in solids, liquids and.
2-D Nanostructure Synthesis (Making THIN FILMS!)
EQ: HOW IS BIOLOGY STUDIED AS A SCIENCE? THE NATURE OF SCIENCE Jacqueline Irizarry, Eboni Harris, Nick Karpiw.
Behaviour of agricultural/food materials under stress
Flame Emission Spectrometry
SINGLE CRYSTALS ISSUES TO ADDRESS -What is single crystal ?
Chemical Vapor Transport (CVT)
HEAT EXCHANGER DESIGNPROJECT ME 414 Thermal Fluid System Design
Synthesis Results Future Work Conclusions
Heuristics for Process Design
Changes of State Chapter 3 Section 3.
MASS RELATIONSHIPS IN CHEMICAL REACTIONS.
K.Nagasawa1), H.Nakatsugawa1) and Y.Okamoto2)
Polymer Characterization
N.Yavarishad1, T.Hosseini1, E.Kheirandish1,C.P.Weber2 and N.Kouklin1
Presentation transcript:

 Motivation  Cd 3 As 2, being a Dirac-type semimetal (DTS), is of considerable research interest due to its high electron mobility, and being a 3D analogue of graphene whose electron mobility is much higher than that of silicon  Due to its three dimensional structure, Cd 3 As 2 could be used for constructing electronic devices rather than just performing as a laboratory for electrons in a DTS  Objectives  Understand interdependent relationships between elemental concentrations, temperature gradients, total and partial pressures, mass transport, and diffusion  Determine and optimize the general parameters that are required to produce crystalline platelets of cadmium arsenide by the process of chemical vapor deposition  Verify platelets are of Cd 3 As 2 using energy-dispersive X-ray spectroscopy and crystalline surfaces using scanning electron microscopy

 Use chemical vapor deposition furnace with flow rate of inert gas and optional vacuum pump to achieve lower pressures  Evaporate target consisting of chunks of Cd 3 As 2 by increasing temperature beyond the evaporating points of both species. Target concentrations begin to diffuse along the tube in all directions due to pressure created by heat gradient in furnace. Flow rate of argon directs evaporated target to the right. Vapors deposit at the sublimation temperature of tube and undergo reaction and by-products exit  Temperature, pressure, flow rate, reaction time variables adjusted to optimize growth  Use EDX analysis to confirm platelets are Cd 3 As 2. Obtain SEM images to confirm crystallinity, obtain electron mobility Furnace end 700 °C 100 °C 25 °C 100 °C25 °C

Platelets display microscopically smooth surfaces with leaf like morphology around edges as seen from SEM images (below) Platelets are formed in various sizes ranging approximately from 1 to 5mm. Repeatable semicrystalline (smooth surface) product growth experiments occured when using the conditions of samples 11 and 12 and repeatable polycrystalline (rough surface) product growth occurred under the conditions of samples 1 through 5 High conductivity measured at 9.06X10^5 S/m with an electron mobility measured at 4158 cm^2/Vs