Which of the following solubility product expressions is incorrect?

Slides:



Advertisements
Similar presentations
COMMON ION EFFECT.
Advertisements

SOLUBILITY Saturated Solution BaSO 4(s)  Ba 2+ (aq) + SO 4 2- (aq) Equilibrium expresses the degree of solubility of solid in water. Equilibrium expresses.
Precipitation Equilibria. Solubility Product Ionic compounds that we have learned are insoluble in water actually do dissolve a tiny amount. We can quantify.
Equilibrium and Solubility 1.Solubility rules for common ions 2.Using the solubility product, K sp, to calculate solubility - molar solubility, gram solubility.
Solubility. Definition Q. How do you measure a compound’s solubility? A. The amount of that compound that will dissolve in a set volume of water. This.
Precipitation Equilibrium
Aqueous Equilibria Entry Task: Feb 28 th Thursday Question: Provide the K sp expression for calcium phosphate, K sp = 2.0 x From this expression,
Lecture 71/31/07. Solubility vs. Solubility constant (K sp ) What is the difference? BaSO 4 (s) ⇄ Ba 2+ (aq) + SO 4 2- (aq) Ba 2+ (aq) + SO 4 2- (aq)
Solubility Product Constant 6-5 Ksp. is a variation on the equilibrium constant for a solute-solution equilibrium. remember that the solubility equilibrium.
Lecture 102/11/06. Solubility PbCl 2 (s) ⇄ Pb 2+ (aq) + 2Cl - (aq)
Solubility Product Constants Silver chloride, AgCl,is rather insoluble in water. Careful experiments show that if solid AgCl is placed in pure water and.
Lecture 92/05/07 Seminar Today. If HCl is added slowly to a solution that is 0.10 M Pb 2+ and 0.01 M Ag +. K sp (AgCl) = 1.6 x K sp (PbCl 2 ) =
Acid-Base Equilibria and Solubility Equilibria Chapter
The Solubility Product Principle. 2 Silver chloride, AgCl,is rather insoluble in water. Careful experiments show that if solid AgCl is placed in pure.
The K sp of chromium (III) iodate in water is 5.0 x Estimate the molar solubility of the compound. Cr(IO 3 ) 3 (s)  Cr 3+ (aq) + 3 IO 3 - (aq)
Chapter 17 Equilibrium in the Aqueous Phase. Clickers in Action © 2009 W. W. Norton & Company, Inc.2 What are the major species present in an aqueous.
Solubility Product Constant
Solubility Product Constant
PRECIPITATION REACTIONS Chapter 17 Part 2 2 Insoluble Chlorides All salts formed in this experiment are said to be INSOLUBLE and form precipitates when.
A salt, BaSO4(s), is placed in water
© 2009, Prentice-Hall, Inc. Solubility of Salts (Ksp) Consider the equilibrium that exists in a saturated solution of BaSO 4 in water: BaSO 4 (s) Ba 2+
Section 4: Solubility Equilibrium. Objectives Explain what is meant by solubility product constants, and calculate their values. Calculate solubilities.
1 Solubility Equilibria all ionic compounds dissolve in water to some degree –however, many compounds have such low solubility in water that we classify.
Chapter 18 Solubility and Complex-Ion Equilibria
Unit 7 - Chpt 16 - Solubility equilibria and Quantitative analysis Solubility equilibria and Ksp Predict precipitation Qualitative analysis HW set1: Chpt.
Chapter 16 Lesson 1 Solubility and Complex Ion Equilibria.
LO 6.1 The student is able to, given a set of experimental observations regarding physical, chemical, biological, or environmental processes that are reversible,
Solubility Allows us to flavor foods -- salt & sugar. Solubility of tooth enamel in acids. Allows use of toxic barium sulfate for intestinal x-rays.
PRECIPITATION REACTIONS
Ionic Equilibria III: The Solubility Product Principle
Copyright Sautter SOLUBILITY EQUILIBRIUM Solubility refers to the ability of a substance to dissolve. In the study of solubility equilibrium we.
Chapter 18 The Solubility Product Constant. Review Quiz Nuclear Chemistry Thermochemistry –Hess’s Law –Heats (Enthalpies) of…
CHAPTER 4 Reactions in Aqueous Solutions. VOCABULARY Page 94 Define all terms.
1 Chapter Seventeen Additional Aspects of Aqueous Equilibria.
Aqueous Equilibria Chapter 17 Additional Aspects of Aqueous Equilibria You love Chemistry You might have doubts, but deep, deep, deep down you know there.
Solubility Chapter 17. No only do acids and bases dissolve in aqueous solutions but so do ionic compounds –Many ionic compounds tend to be strong electrolytes.
Chapter 21 Notes, part III Ksp and Common Ion Effect.
The Solubility Product Principle Chapter 20. Solubility: the amount of compound that dissolves in a specified volume. Usually expressed as grams per Liter.
Solubility & SOLUBILITY PRODUCT CONSTANTS. Solubility Rules All Group 1 (alkali metals) and NH 4 + compounds are water soluble. All nitrate, acetate,
Chemistry 1011 Slot 51 Chemistry 1011 TOPIC Solubility Equilibrium TEXT REFERENCE Masterton and Hurley Chapter 16.1.
Solubility Equilibria 16.6 AgCl (s) Ag + (aq) + Cl - (aq) K sp = [Ag + ][Cl - ]K sp is the solubility product constant MgF 2 (s) Mg 2+ (aq) + 2F - (aq)
Solubility Equilibrium Solubility Product Constant Ionic compounds (salts) differ in their solubilities Most “insoluble” salts will actually dissolve.
Solubility Equilibria
The Solubility Product Principle Chapter 20. __________: the amount of compound that dissolves in a specified volume. Usually expressed as grams per Liter.
SOLUBILITY I. Saturated Solution BaSO 4(s)  Ba 2+ (aq) + SO 4 2- (aq) Equilibrium expresses the degree of solubility of solid in water. Ksp = solubility.
1 What weight of sulfur (FW = ) ore which should be taken so that the weight of BaSO 4 (FW = ) precipitate will be equal to half of the percentage.
CH 8 Solubility Rules & Net Ionic Equations. Chemical Reactions Many chemical reactions take place in solution. This means that the ionic compounds are.
1 PRECIPITATION REACTIONS Solubility of Salts Section 18.4.
E 12 Water and Soil Solve problems relating to removal of heavy –metal ions and phosphates by chemical precipitation
Acid-Base Equilibria and Solubility Equilibria Chapter 16.
N OTES 17-3 Obj. 17.4, S OLUBILITY P RODUCTS A.) Consider the equilibrium that exists in a saturated solution of BaSO 4 in water: BaSO 4 (
Common-Ion EffectCommon-Ion Effect  Similar to acids and bases  There is a “common ion” when 2 salt solutions are mixed together.
Solubility Constant (Ksp). © 2009, Prentice-Hall, Inc. Solubility of Salts (Ksp) Consider the equilibrium that exists in a saturated solution of BaSO.
1 16 Ionic Equilibria III: The Solubility Product Principle.
1 20 Ionic Equilibria III: The Solubility Product Principle.
SOLUBILITY – The maximum amount of solute that will dissolve in a specific amount of solvent EQUILIBRIA WITH SALTS SATURATED – A solution where the solid.
Solubility Equilibria Will it all dissolve, and if not, how much will?
K sp and the Solubility Product Constant. K sp The Solubility Product Constant The study of __________ _________ compounds.
Ionic Equilibria III: The Solubility Product Principle
Solubility and Solubility Product
The Solubility Product Principle
Solubility and Complexation Equilibria
Chapter 16 Solubility and Complex Ion Equilibria.
Precipitation Equilibrium
A salt, BaSO4(s), is placed in water
Solubility Lesson 8 Review Notes.
Solubility Equilibria
Ionic Equilibria III: The Solubility Product Principle
Solubility Product Constant
Solubility Product Constant
Presentation transcript:

Which of the following solubility product expressions is incorrect? 1. {image} 2. 3. 4. 5. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Calculate the solubility product constant for lead fluoride, PbF2 Calculate the solubility product constant for lead fluoride, PbF2. Its molar solubility is 2.1 x 10-3 mole per liter at 25°C. 4.4 x 10-6 4.2 x 10-7 9.3 x 10-7 9.3 x 10-9 3.7 x 10-8 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

The solubility of bismuth sulfide is 1. 8 x 10-5 g/100 The solubility of bismuth sulfide is 1.8 x 10-5 g/100. mL of water at 18°C. Calculate the Kspfor Bi2S3 at 18°C. 6.0 x 10-36 3.4 x 10-23 5.7 x 10-31 5.8 x 10-12 3.2 x 10-8 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Calculate the molar solubility of aluminum hydroxide at 25°C Calculate the molar solubility of aluminum hydroxide at 25°C. Its Kspis 1.9 x 10-33. 1.2 x 10-9 M 4.2 x 10-15 M 2.9 x 10-9 M 4.4 x 10-14 M 9.3 x 10-9 M 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

How many grams of AgCl will dissolve in 1. 0 L of 0. 25 M KCl How many grams of AgCl will dissolve in 1.0 L of 0.25 M KCl? Ksp (AgCl)= 1.8 x 10-10 1.0 x 10-7 2.6 x 10-8 6.4 x 10-9 7.8 x 10-8 2.5 x 10-9 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

If NaCl is added to a 0.010 M solution of AgNO3in water at 25°C, at what [Cl-] does precipitation of AgCl begin? Ksp for AgCl = 1.8 x 10-10. 1.0 x 10-10 M 1.3 x 10-6 M 1.8 x 10-8 M 1.8 x 10-12 M 1.3 x 10-10 M 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Calculate the concentration of sulfate ion in a saturated solution of barium sulfate to which barium chloride has been added until [Ba+2] = 0.1 M at 25°C. Ksp for BaSO4 = 1 x 10-10. 1 x 10-5 M 1 x 10-8 M 1 x 10-9 M 1 x 10-7 M 1 x 10-6 M 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

What is the minimum concentration of bromide ion required to limit the concentration of silver ion in solution to a maximum of 1.0 x 10-9 M? Ksp for AgBr is 3.3 x 10-13. 1.0 x 10-9 M 3.3 x 10-4 M 1.1 x 10-7 M 5.0 x 10-6 M 3.3 x 10-22 M 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Which of the following salts would not be expected to be more soluble in acidic solution than in pure water? Fe(OH)3 FeS ZnCO3 AgI Hg2(CH3COO)2 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

I, II, and IV II, III, and IV I, IV, and V II and V II, III, IV, and V Consider the following system: Some solid AgCl is in contact with its saturated aqueous solution. Gaseous NH3is then bubbled through the solution slowly with swirling until all the AgCl dissolves. Choose the response which includes all the true statements, and no others. I. At the point at which all the AgCl has dissolved [Ag+] = [Cl-]. II. The AgCl dissolves due to formation of the complex ion, [Ag(NH3)2]+. III. As the NH3 is added to the solution, the [Cl-] increases. IV. The solution remains saturated with silver chloride as long as any solid AgCl remains. V. The solubility of silver chloride in aqueous ammonia solution is greater than in pure water. I, II, and IV II, III, and IV I, IV, and V II and V II, III, IV, and V 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Calculate the concentration of free Ni2+ in 1 Calculate the concentration of free Ni2+ in 1.0 M [Ni(NH3)6](NO3)2 at 25°C. Kd for [Ni(NH3)6]2+ is 1.8 x 10-9. 1.6 x 10-5 M 0.012 M 3.2 x 10-4 M 0.084 M 4.4 x 10-5 M 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50