Quantities of As in Florida
Purpose Determine the relative magnitude of arsenic from CCA-treated wood versus the amounts from other arsenic sources Determine the relative magnitude of arsenic from CCA-treated wood versus the amounts from other arsenic sources Evaluate arsenic inputs, outputs, and reservoirs Evaluate arsenic inputs, outputs, and reservoirs
Inputs/Outputs/Reservoirs CCA-treated Wood CCA-treated Wood Non-CCA Pesticides Non-CCA Pesticides Geologic Sources Geologic Sources Fuels Fuels Fertilizers Fertilizers Food Sources Food Sources Wastes Disposed Within State Wastes Disposed Within State Hydrosphere Hydrosphere
Methods
Methods: CCA Input: 31.2 million ft 3 /yr Extrapolated from Industry Statistics Extrapolated from Industry Statistics Average retention of 0.45 pcf (22% arsenic) (million ft 3 /yr)(retention) = 1,400 metric tons As/yr = 1,400 metric tons As/yr AWPA,AWPI,SFPA~0.38 pcf (US) Florida Questionairre~0.76 pcf
Methods: non-CCA Pesticides Cattle Dipping Vats Cattle Dipping Vats (Historical Use) (Historical Use) MSMA/DSMA/Cacodylic Acid (Current Use) MSMA/DSMA/Cacodylic Acid (Current Use) Agriculture Agriculture Golf Course Use Golf Course Use
MSMA/DSMA in Agriculture From the Nat. Center for Food and Ag. Policy, 2002
MSMA Use in Golf Courses Input = (Surface Area of Golf Courses) (Fraction of Golf Courses that Use MSMA) (Application Rate) Surface Area = Total Area from Florida Golf Courses Fraction of Golf Courses that Use MSMA = 0.96 (Ma et al. 2000) Application Rate = 11.7 lbs/acre/yr (from Hawaiian Study) Input ~ 500 metric tons As/yr Input ~ 500 metric tons As/yr
MSMA Stored in Golf Courses DERM 1999: 16.9 mg/kg DERM 1999: 16.9 mg/kg (0 to 1 or 2 ft composites) (0 to 1 or 2 ft composites) Ma et al. 2000: 69.2 mg/kg Ma et al. 2000: 69.2 mg/kg Mass = (Surface Area of Golf Courses) x (Concentration) x (Concentration)
Results
InputsConc.ppm Metric tons As/yr CCA-Treated Wood 3,1001,400 MSMAAgriculture Golf Courses 2,8001, GeologicPhosphateLimestone FuelsCoalPetroleum HydrosphereRainRivers Food Sources FishShellfish Chicken Manure SUM2,500
Outputs Input Flux ~ 2,500 metric tons As/yr Conc.ppm Metric tons As/yr GeologicPhosphate HydrosphereRivers WastesWastewater WTE Air Emissions <0.01< Output Flux ~ 10% of Input
Accessible Reservoir Conc.ppm Metric tons As CCA-Treated Wood 3,10024,000 Other Arsenicals Cattle Dipping Golf Courses (Ma) Golf Courses (DERM) 1600 (sol’n) 69171,2002,50011,000 Geologic Phosphogypsum Stacks Limestone in Use 435,0003,400 HydrosphereLakesGroundwater Surface Soil ,4002,500 SUM47,000-56,000
Summary/Conclusions Approx. 2,500 metric tons As imported per yr Approx. 2,500 metric tons As imported per yr CCA-treated wood (60%) CCA-treated wood (60%) Arsenical pesticides,MSMA (20%) Arsenical pesticides,MSMA (20%) Geologic Sources (15%) Geologic Sources (15%) About 10% of the imported As is exported Majority accumulates over time About 10% of the imported As is exported Majority accumulates over time
Recommendations In order to limit As impacts In order to limit As impacts Reduce use of MSMA Reduce use of MSMA Properly dispose CCA-treated wood Properly dispose CCA-treated wood Minimize impacts of CCA-treated wood currently in service Minimize impacts of CCA-treated wood currently in service
Questions? Draft Report posted at