Quantization via Fractional Revivals Quantum Optics II Cozumel, December, 2004 Carlos Stroud, University of Rochester Collaborators:

Slides:



Advertisements
Similar presentations
The Schrödinger Wave Equation 2006 Quantum MechanicsProf. Y. F. Chen The Schrödinger Wave Equation.
Advertisements

Quantum Harmonic Oscillator
Physical Chemistry 2nd Edition
Quantum One: Lecture 6. The Initial Value Problem for Free Particles, and the Emergence of Fourier Transforms.
The Quantum Mechanics of Simple Systems
Quantum One: Lecture 5a. Normalization Conditions for Free Particle Eigenstates.
Atomic Vibrations in Solids: phonons
Quantum One: Lecture 3. Implications of Schrödinger's Wave Mechanics for Conservative Systems.
Wavepacket1 Reading: QM Course packet FREE PARTICLE GAUSSIAN WAVEPACKET.
Wavefunction Quantum mechanics acknowledges the wave-particle duality of matter by supposing that, rather than traveling along a definite path, a particle.
No friction. No air resistance. Perfect Spring Two normal modes. Coupled Pendulums Weak spring Time Dependent Two State Problem Copyright – Michael D.
Review Three Pictures of Quantum Mechanics Simple Case: Hamiltonian is independent of time 1. Schrödinger Picture: Operators are independent of time; state.
Random Matrices Hieu D. Nguyen Rowan University Rowan Math Seminar
Quantum Dynamics of a Kicked Harmonic Oscillator Laura Ingalls Huntley Prof. Calvin Stubbins Franklin & Marshall College Department of Physics & Astronomy.
The Klein Gordon equation (1926) Scalar field (J=0) :
Quantum Mechanics from Classical Statistics. what is an atom ? quantum mechanics : isolated object quantum mechanics : isolated object quantum field theory.
Schrödinger Wave Equation 1 Reading: Course packet Ch 5.7 SCHROEDINGER WAVE EQUATION (both images from Wikipedia.com)
The Harmonic Oscillator
Modern Physics lecture 3. Louis de Broglie
Ch 9 pages ; Lecture 21 – Schrodinger’s equation.
Lattice Vibrations, Part I
Lecture 10 Harmonic oscillator (c) So Hirata, Department of Chemistry, University of Illinois at Urbana-Champaign. This material has been developed and.
Vibrational Spectroscopy
Chang-Kui Duan, Institute of Modern Physics, CUPT 1 Harmonic oscillator and coherent states Reading materials: 1.Chapter 7 of Shankar’s PQM.
Semi-classics for non- integrable systems Lecture 8 of “Introduction to Quantum Chaos”
Physical Chemistry 2nd Edition
Quantum Mechanics (14/2) CH. Jeong 1. Bloch theorem The wavefunction in a (one-dimensional) crystal can be written in the form subject to the condition.
Ch 9 pages Lecture 22 – Harmonic oscillator.
Ch 3. The Quantum Mechanical Postulates
Physics 452 Quantum mechanics II Winter 2012 Karine Chesnel.
6.852: Distributed Algorithms Spring, 2008 April 1, 2008 Class 14 – Part 2 Applications of Distributed Algorithms to Diverse Fields.
Physical Chemistry 2 nd Edition Thomas Engel, Philip Reid Chapter 18 A Quantum Mechanical Model for the Vibration and Rotation of Molecules.
MODULE 1 In classical mechanics we define a STATE as “The specification of the position and velocity of all the particles present, at some time, and the.
Time-dependent Schrodinger Equation Numerical solution of the time-independent equation is straightforward constant energy solutions do not require us.

Ch 4. Using Quantum Mechanics on Simple Systems
1 MODELING MATTER AT NANOSCALES 4. Introduction to quantum treatments The variational method.
Modern Physics (II) Chapter 9: Atomic Structure
Quantum Chemistry: Our Agenda (along with Engel)
Advanced methods of molecular dynamics 1.Monte Carlo methods 2.Free energy calculations 3.Ab initio molecular dynamics 4.Quantum molecular dynamics III.
MS310 Quantum Physical Chemistry
Quantum Mechanical Cross Sections In a practical scattering experiment the observables we have on hand are momenta, spins, masses, etc.. We do not directly.
Path Integral Quantum Monte Carlo Consider a harmonic oscillator potential a classical particle moves back and forth periodically in such a potential x(t)=

Chapter 5: Quantum Mechanics
Modern Physics lecture X. Louis de Broglie
2. Time Independent Schrodinger Equation
The Hydrogen Atom The only atom that can be solved exactly.
CHAPTER 6 Quantum Mechanics II
量子力學導論 Chap 1 - The Wave Function Chap 2 - The Time-independent Schrödinger Equation Chap 3 - Formalism in Hilbert Space Chap 4 - 表象理論.
Chapter 3 Postulates of Quantum Mechanics. Questions QM answers 1) How is the state of a system described mathematically? (In CM – via generalized coordinates.
Topic I: Quantum theory Chapter 7 Introduction to Quantum Theory.
Phonons Packets of sound found present in the lattice as it vibrates … but the lattice vibration cannot be heard. Unlike static lattice model , which.
Quantum One.
Quantum Theory of Hydrogen Atom
Solutions of Schrodinger Equation
The Hydrogen Atom The only atom that can be solved exactly.
QUANTUM TRANSITIONS WITHIN THE FUNCTIONAL INTEGRATION REAL FUNCTIONAL
Time Dependent Two State Problem
Lecture 3 The Schrödinger equation
Concept test 15.1 Suppose at time
Christopher Crawford PHY 520 Introduction Christopher Crawford
Christopher Crawford PHY 520 Introduction Christopher Crawford
Quantum One.
Concept test 15.1 Suppose at time
Quantum One.
Quantum Theory of Hydrogen Atom
Quantum Two Body Problem, Hydrogen Atom
Quantum Mechanics Postulate 4 Describes expansion
Linear Vector Space and Matrix Mechanics
Presentation transcript:

Quantization via Fractional Revivals Quantum Optics II Cozumel, December, 2004 Carlos Stroud, University of Rochester Collaborators: David Aronstein Ashok Muthukrishnan Hideomi Nihira Mayer Landau Alberto Marino

Quantization via Stationary States Quantization is normally described in terms of discrete transitions between stationary states. Stationary states are a complete basis so it cannot be wrong. But, it leads to a particular way of looking at quantum mechanics that is not the most general. Bohr Orbits only orbits with integer n are allowed. Feynman path integral shows us that more general orbits are included in the propagator.

Feynman Propagator Propagator for wave function from x,t to x’,t’ is sum of the exponential of the classical action over all possible paths between the two points. Stationarity limits us to integer-action orbits. In dynamic problems other orbits may contribute.

Rydberg wave packet dynamics Decays and revivals involve non-integer orbits

Rydberg wave packet dynamics Schrödinger “Kitten” States Such superpositions of classically distinguishable states of a single degree of freedom are often termed “Schrödinger “Kitten” states.

Schrödinger “Kitten” States Analogous states of harmonic oscillators can be formed with coherent states two coherent states  radians apart in their phase space trajectory. or more generally two coherent states 2  /N radians apart in their phase space trajectory.

Bohr-Sommerfeld Racetrack Ensemble Classical ensemble of runners with Bohr velocities Decay, revival, and fractional revival with classical ensemble, but the revival is on the wrong side of the track!

Bohr-Sommerfeld Racetrack Ensemble Proper phase of the full revival if we choose Bohr velocities with n + ½ but, then phase is wrong at ½ fractional revival! This can be understood via the semiclassical approximation to the quantum propagator. Propagation from the initial wave packet to the revival wave packets can be described in terms of the integral of the action over classical orbits. The classical orbits that contribute in general include all orbits, both those of the integer and non-integer Bohr orbits. At the fractional revivals only a discrete subset of the classical orbits contribute, sometimes the Bohr orbits, and sometimes other orbits. These discrete sets form other schemes for “quantization”.

Quantization of wave packet revival intervals Describe the system in an energy basis Given a wave packet Find times t such that so that The problem

The are orthogonal thus Towards a more general theory of wave packet revivals requires for some t for all n [ multiple of ] General solution not known, but often problem reduces to

Towards a more general theory of wave packet revivals where [ multiple of ] Eigenvalue problem with eigenvalues t and eigenfunctions We want to find the eigenvalues. Apply order N+1 difference operator to each side of the equation. is a polynomial of degree N in n for a given t [ multiple of ]

Towards a more general theory of wave packet revivals Finite difference equations for discrete polynomials Corresponding continuous variable problem is a Nth order polynomial in x and t, then Discrete version is an N th order polynomial in discrete variable n and continuous variable t

Towards a more general theory of wave packet revivals Necessary and sufficient condition for revivals Useful ancillary conditions [ multiple of ]

Towards a more general theory of wave packet revivals Example: Infinite square well problem has not been solved for general initial condition. Special case: Ladder States The only nonzero in the initial state are those satisfying or

Towards a more general theory of wave packet revivals Example: Infinite square well We also have the ancillary condition which is easily evaluated as or this is a necessary, but not sufficient condition. Substitute it back into the first difference equation

Towards a more general theory of wave packet revivals Example: Infinite square well The smallest integer R must contain all prime factors of not present in For the first revival of our ladder state then The spacing of the initially excited states determines time to first revival

Towards a more general theory of wave packet revivals Example: Infinite square well Even parity initial wave packets have only odd states in their expansion, b=1, d=2 Odd parity initial wave packets have only even states in their expansion, b=2, d=2

Towards a more general theory of wave packet revivals Example: Highly excited systems Autocorrrelation function compared with predicted revival times near second and third superrevivals.

Application of Schrödinger Kitten States Quantum discrete Fourier transform Energy basis and time basis are related by a transform. One can take a transform by preparing a state in one basis and reading out in the complementary basis. Ashok Muthukrishnan and CRS, J. Mod. Opt. 49, (2002)

Application of Schrödinger Kitten States Quantum discrete Fourier transform Energy basis and time basis are related by a transform. One can take a transform by preparing a state in one basis and reading out in the complementary basis. Ashok Muthukrishnan and CRS, J. Mod. Opt. 49, (2002) Generally quantum algorithms require entanglement. Can we entangle multi-particle systems in kitten states?

Entanglement of Schrödinger Kitten States N harmonic oscillators with nearest neighbor coupling Model for lattice of interacting Rydberg atoms Model for lattice of single-mode optical fibers.

N harmonic oscillators with nearest neighbor coupling introduce reciprocal-space variables which diagonalize the Hamiltonian

N harmonic oscillators with nearest neighbor coupling Solve the Heisenberg equation of motion apply to initial state with only first oscillator in a coherent state.

N harmonic oscillators with nearest neighbor coupling transform to the Schrödinger picture The time dependent state is a product of coherent states for the separate oscillators. No entanglement here.

N harmonic oscillators with nearest neighbor coupling Investigate the nature of the coherent states Each oscillator is in a coherent state with an amplitude that varies as a Bessel function.

Entangled coherent states of N harmonic oscillators Prepare initial oscillator in a kitten state

Entangled coherent states of N harmonic oscillators Prepare initial oscillator in a kitten state applying the time evolution operator to each term we find An N -particle GHZ state if the kittens were orthogonal.

Rydberg Wave Packet Kitten States For high enough excitation the kittens are orthogonal

Rydberg Wave Packet Kitten States For high enough excitation the kittens are orthogonal Multi-level logic possible with higher-order kitten states.

Making Rydberg Wave Packet Kitten States Laboratory creation of arbitrary kitten state “Shaping an atomic electron wave packet,” Michael W. Noel and CRS, Optics Express 1, 176 (1997).

Quantization via Fractional Revivals Conclusions For dynamics problems it may be useful to quantize via revivals rather stationary states. The resulting “kitten” states can be entangled. Quantum logic and encryption may be carried out using these states. Realizations of these states are possible with atoms and photons. Support by ARO, NSF and ONR.