Lecture 112/14/05 Exam 1 Wednesday: Come early if you want extra time Review session today 4 – TSC 006
pH: Describes the concentration of H 3 O + pX = -log X pH = -log [H 3 O + ] [H 3 O + ] = 10 -pH So if [H 3 O + ] = M, pH = ? If pH = 6, [H 3 O + ] = ?
Autoionization of Water H 2 O + H 2 O ↔ H 3 O + + OH - K w = [H 3 O + ][OH - ] What is the definition of neutral, acidic, and basic solutions? Neutral: [H 3 O + ] = [OH - ] Acid: [H 3 O + ] >[OH - ] Base: [H 3 O + ] < [OH - ]
K w = [H 3 O + ][OH - ] THUS at 25°C, neutral pH = 7
T (°C)KwKw x x x x x x Neutral pH = 7.27 Neutral pH = 6.92
pH and pOH K w = [H 3 O + ][OH - ] At 25 °C =[H 3 O + ][OH - ] -log ( =[H 3 O + ][OH - ]) -log ( ) = -log([H 3 O + ][OH - ]) -log ( ) = -log[H 3 O + ]-log[OH - ] 14 = pH + pOH
How do you measure pH? What is the pH range? pH meter Indicator (color change)
pH of some common substances pH Bleach12.5 Baking soda8.4 Egg White7.7 Milk6.8 Unpolluted rain5.6 Coffee4.9 Coke2.9 Stomach acid1.2
Degree of ionization
pH of strong acid? What is the pH of a M HNO 3 solution?