Copyright©2000 by Houghton Mifflin Company. All rights reserved. 1 Chemistry FIFTH EDITION by Steven S. Zumdahl University of Illinois

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 2 Chemistry FIFTH EDITION Chapter 20 Transition Metals and Coordination Chemistry

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 3 Figure 20.1 The Position of the Transition Elements on the Periodic Table

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 4 Figure 20.2 Plots of the First (Red Dots) and Third (Blue Dots) Ionization Energies for the First-Row Transition Metals

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 5 Figure 20.3 Atomic Radii of the 3d, 4d, and 5d Transition Series

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 6 Figure 20.4 The Structures of the Chromium (VI) Anions

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 7 Figure 20.5 The Ligand Arrangements for Coordination Numbers 2, 4, and 6

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 8 Figure 20.8 Some Classes of Isomers

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 9 Figure 20.9 NO 2 -

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 10 Figure Alloys Containing Copper

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 11 Figure Typical Compounds of Copper

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 12 Figure Unpolarized Light Consists of Waves Vibrating in Many Different Planes

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 13 Figure The Rotation of the Plane of Polarized Light by an Optically Active Substance

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 14 Figure A Human Hand Exhibits a Nonsuperimposable Mirror Image

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 15 Figure Isomers of I and II of Co(en) 3 3+ are Mirror Images That Cannot Be Superimposed

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 16 Figure The Optical Isomers of Co(en) 2 CI 2 +

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 17 Figure Hybrid Orbitals on Co 3+

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 18 Figure The Hybrid Orbitals Required for Tetrahedral, Square Planar, and Linear Complex Ions

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 19 Figure An Octahedral Arrangement of Point-Charge Ligands and the Orientation of the 3d Orbitals

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 20 Figure The Energies of the 3d Orbitals for a Metal Ion in an Octahedral Complex

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 21 Figure The Visible Spectrum

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 22 Figure Violet Light

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 23 Figure The d Orbitals in a Tetrahedral Arrangement of Point Charges

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 24 Figure The Crystal Field Diagrams for Octahedral and Tetrahedral Complexes

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 25 Figure The d Energy Diagrams for Square, Planar, and Linear Complexes

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 26 Figure The Heme Complex

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 27 Figure Chlorophyll

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 28 Figure Myoglobin

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 29 Figure Hemoglobin

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 30 Figure A Schematic Diagram of a Cyclone Separator

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 31 Figure A Schematic Representation of Zone Refining

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 32 Figure The Blast Furnace Used in the Production of Iron

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 33 Figure A Schematic Diagram of the Open Hearth Process for Steel Making

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 34 Figure The Basic Oxygen Process for Steelmaking