Scattering from imperfect crystals (see Cowley Sect. 7.1) Two types average lattice exists (point defects, dislocations, thermal vibrations) no average lattice (stacking faults, twinning) Two types average lattice exists (point defects, dislocations, thermal vibrations) no average lattice (stacking faults, twinning)
Scattering from imperfect crystals (see Cowley Sect. 7.1) Two types average lattice exists (point defects, dislocations, thermal vibrations) no average lattice (stacking faults, twinning) Two types average lattice exists (point defects, dislocations, thermal vibrations) no average lattice (stacking faults, twinning)
Scattering from imperfect crystals (see Cowley Sect. 7.1) Two types can't put in all atoms; consider average of atoms surrounding particular set of N atoms Two types can't put in all atoms; consider average of atoms surrounding particular set of N atoms
Scattering from imperfect crystals Two types can't put in all atoms; consider average of atoms surrounding particular set of N atoms for a monatomic solid Two types can't put in all atoms; consider average of atoms surrounding particular set of N atoms for a monatomic solid
Random vacancies (see Cowley Sect. 7.3) Suppose n random vacancies in monatomic solid w/ N atom sites Consider vectors r i - r j Suppose n random vacancies in monatomic solid w/ N atom sites Consider vectors r i - r j
Random vacancies (see Cowley Sect. 7.3) Suppose n random vacancies in monatomic solid w/ N atom sites Consider vectors r i - r j Suppose n random vacancies in monatomic solid w/ N atom sites Consider vectors r i - r j
Random vacancies Rearranging:
Random vacancies Rearranging: scattering power of ordered structure - no defects, reduced f Rearranging: scattering power of ordered structure - no defects, reduced f
Random vacancies Rearranging: scattering power of ordered structure - no defects, reduced fcont s distrib of scatt power - decreases w/ u - approx proportional to n Rearranging: scattering power of ordered structure - no defects, reduced fcont s distrib of scatt power - decreases w/ u - approx proportional to n
Random vacancies Rearranging: scattering power of ordered structure - no defects, reduced fcont s distrib of scatt power - decreases w/ u - approx proportional to n Rearranging: scattering power of ordered structure - no defects, reduced fcont s distrib of scatt power - decreases w/ u - approx proportional to n
Random vacancies Now consider Patterson Suppose n random vacancies in monatomic solid w/ N electron density fordeviation from ordered structure Now consider Patterson Suppose n random vacancies in monatomic solid w/ N electron density fordeviation from ordered structure
Random vacancies Now consider Patterson Suppose n random vacancies in monatomic solid w/ N electron density fordeviation from ordered structure Now consider Patterson Suppose n random vacancies in monatomic solid w/ N electron density fordeviation from ordered structure
Random vacancies
Vacancy clusters Use Patterson approach again
Interstitials Assume n small interstitials w/ negligible scattering power Average structure is Assume n small interstitials w/ negligible scattering power Average structure is
Interstitials Assume n small interstitials w/ negligible scattering power
Interstitials Assume n small interstitials w/ negligible scattering power
Thermal vibrations Einstein: monatomic, independent, harmonic, 1-D Spread electron density by Gaussian Einstein: monatomic, independent, harmonic, 1-D Spread electron density by Gaussian
Thermal vibrations Except for origin peak, all Patterson peaks spread by Except for origin peak, all Patterson peaks spread by
Thermal vibrations Except for origin peak, all Patterson peaks spread by Intensity is Except for origin peak, all Patterson peaks spread by Intensity is
Thermal vibrations Except for origin peak, all Patterson peaks spread by Intensity is Except for origin peak, all Patterson peaks spread by Intensity is
No average lattice Except for origin peak, all Patterson peaks spread by Except for origin peak, all Patterson peaks spread by
No average lattice Except for origin peak, all Patterson peaks spread by d(z) is a set of fcns (r) considered periodic in x,y Except for origin peak, all Patterson peaks spread by d(z) is a set of fcns (r) considered periodic in x,y
No average lattice Except for origin peak, all Patterson peaks spread by d(z) is a set of fcns (r) considered periodic in x,y reciprocal lattice Except for origin peak, all Patterson peaks spread by d(z) is a set of fcns (r) considered periodic in x,y reciprocal lattice
No average lattice Use Gaussian distrib w/ mean = c Use Gaussian distrib w/ mean = c
No average lattice Use Gaussian distrib w/ mean = c Use Gaussian distrib w/ mean = c
No average lattice