Chapter 8 – Continuous Absorption Physical Processes Definitions Sources of Opacity Hydrogen bf and ff H- H2 He Scattering How does kn affect the spectrum? More continuous absorption, less continuum light at that wavelength More continuous absorption, lines must form in shallower layers, at lower optical depth Need kn to determine T(t) relation

Many physical processes contribute to opacity Bound-Bound Transitions – absorption or emission of radiation from electrons moving between bound energy levels. Bound-Free Transitions – the energy of the higher level electron state lies in the continuum or is unbound. Free-Free Transitions – change the motion of an electron from one free state to another. Electron Scattering – deflection of a photon from its original path by a particle, without changing its wavelength Rayleigh scattering – photons scatter off bound electrons. (Varies as l-4) Thomson scattering –photons scatter off free electrons (Independent of wavelength) Photodissociation may occur for molecules

What can various particles do? Free electrons – Thomson scattering Atoms and Ions – Bound-bound transitions Bound-free transitions Free-free transitions Molecules – BB, BF, FF transitions Photodissociation Most continuous opacity is due to hydrogen in one form or another

Monochromatic Absorption Coefficient Recall dtn = knrdx. We need to calculate kn, the absorption coefficient per gram of material First calculate the atomic absorption coefficient an (per absorbing atom or ion) Multiply by number of absorbing atoms or ions per gram of stellar material (this depends on temperature and pressure) MOSTLY HYDROGEN

Bound-Bound Transitions Bound-bound transitions produce spectral lines At high temperatures (as in a stellar interior) these may often be neglected. But even at T~106K, the line absorption coefficient can exceed the continuous absorption coefficient at some densities Remember the hydrogen atom: R is the Rydberg Constant, R = 1.1 x 10-3 Å-1 As m > ∞, the transition approaches a bound-free condition. For photons of higher energy, the hydrogen atom is ionized

Bound Free Transitions An expression for the bound-free coefficient was derived by Kramers (1923) using classical physics. A quantum mechanical correction was introduced by Gaunt (1930), known as the Gaunt factor (gbf is not the statistical weight!) (for the nth bound level below the continuum and l < ln) where a0 = 1.044 x 10–26 for l in angstroms and gbf is of order 1 The atomic absorption coefficient abf(H) has units of cm2 per neutral H atom

Must also consider level populations Back to Boltzman and Saha! gn = 2n2 is the statistical weight u0(T) = 2 is the partition function So, the abs. coef. per neutral H atom is (summing over all levels n):

One more step Terms with n > n0+2 can be replaced with an integral (according to Unsöld) Plus a little manipulation, gives This is the absorption coefficient per neutral hydrogen atom Here, I is the ionization potential, NOT the intensity!

Model Flux Distributions Sharp edges are the result of sudden drop in bound-free opacities due to ionization

Free-Free Absorption from H I Much less than bound free absorption Kramers (1923) + Gaunt (1930) again Absorption coefficient depends on the speed of the electron (slower electrons are more likely to absorb a photon because their encounters with H atoms take longer) Adopt a Maxwell-Boltzman distribution for the speed of electrons Again multiply by the number of neutral hydrogen atoms:

Opacity from Neutral Hydrogen Neutral hydrogen (bf and ff) is the dominant source of opacity in stars of B, A, and F spectral type Discussion Questions: Why is neutral hydrogen not a dominant source of opacity in O stars: Why not in G, K, and M stars?

Opacity from the H- Ion Bound–free and free-free Only one known bound state for bound-free absorption 0.754 eV binding energy So l < 16,500A = 1.65 microns Requires a source of free electrons (ionized metals) Major source of opacity in the Sun’s photosphere Not a source of opacity at higher temperatures because H- becomes too ionized (average e- energy too high)

More H- Bound-Free Opacity Per atom absorption coefficient for H- can be parameterized as a polynomial in l: Units of cm2 per neutral hydrogen atom

H- Bound-Free Absorption Coefficient Two theoretical calculations Important in the optical and near infrared Peaks at 8500Å

H- Free-Free Absorption Coefficient The free-free H- absorption coefficient depends on the speed of the electron Possible because of the imperfect shielding of the hydrogen nucleus by one electron Proportional to l3 Small at optical wavelengths Comparable to H- bf at 1.6 microns Increases to the infrared

H- Free Free Absorption Coefficient H- ff is important in the infrared combining H- bf and ff gives an opacity minimum at 1.6 microns H- ff parameterized as the f’s are functions of logl and q is 5040/T Units are cm2 per neutral H atom

Molecular H2, H2+, H2- Opacities H2 is more common than H in stars cooler than mid-M spectral type (think brown dwarfs!!) Recall that these are important in L and T dwarfs! Also in cool white dwarfs… Not important in optical region (H2+ less than 10% of H- in the optical) H2 in the infrared H2+ in the UV, H2- has no stable bound state, but ff absorption is important in cooler stars

Collision induced opacity of molecular hydrogen Linsky/JILA Collision induced opacity of molecular hydrogen H2 has no dipole moment - no rotation or vibration-rotation spectrum Collisions with (H2, He, H) can induce transient dipole moments Fundamental VR band at 4162 cm-1 (2.4 microns). First overtone VR band at 8089 cm-1 (1.2 microns). Second overtone VR band at 11786 cm-1 (0.2 microns). Collisions are fast - individual spectral lines broad and overlap H2CIO is important for computing the temperature structure of brown dwarfs because it is a near-continuous opacity source that fills in the opacity gaps between the molecular absorption lines.

Helium Absorption He in hot stars only, O and early B stars – c1=19.7eV, I1=24.6 eV, I2=54.4 eV He I absorption mimics H He II also mimics H, but x4 in energy, ¼ in l Bound-free He- absorption is negligible (excitation potential of 19 eV!) Free-free He- can be important in cool stars in the IR BF and FF absorption by He is important in the hottest stars (O and early B)

Electron Scattering vs. Free-Free Transition Electron scattering (Thomson scattering) – the path of the photon is altered, but not the energy Free-Free transition – the electron emits or absorbs a photon. A free-free transition can only occur in the presence of an associated nucleus. An electron in free space cannot gain the energy of a photon.

Why Can’t a Lone Electron Absorb a Photon? Consider an electron at rest that is encountered by a photon, and let it absorb the photon…. Conservation of momentum says Conservation of energy says Combining these equations gives So v=0 (the photon isn’t absorbed) or v=c (not allowed)

Electron Scattering Thomson scattering (photons scatters off a free electron, no change in l, just direction): Independent of wavelength In hot stars (O and early B) where hydrogen is ionized (Pe~0.5Pg), k(e)/Pe is small unless Pe is small In cool stars, e- scattering is small compared to other absorbers for main sequence star but is more important for higher luminosity stars

Rayleigh Scattering Photons scatter off bound electrons (varies as l-4) Generally can be neglected But – since it depends on l-4, it is important as a UV opacity source in cool stars with molecules in their atmospheres. H2 can be an important scattering agent

Other Sources Metals: C, Si, Al, Mg, Fe produce bound-free opacity in the UV Line Opacity: Combined effect of millions of weak lines Detailed tabulation of lines Opacity distribution functions Statistical sampling of the absorption Molecules: CN-, C2-, H20- , CH3, TiO are important in late and/or very late stars

Sources of Opacity for Teff=4500 Log g = 1.5

Opacity Sources at 5143K

Opacity at 6429 K

Opacity at 7715 K

Opacity at 11600 K

Opacity vs. Spectral Type Main Sequence Supergiants

Dominant Opacity vs. Spectra Type Low Electron scattering (H and He are too highly ionized) Low pressure – less H-, lower opacity Electron Pressure He+ He Neutral H H- H- High (high pressure forces more H-) O B A F G K M

Class Exercise – Electron Scattering Estimate the absorption coefficient for electron scattering for the models provided at a level where T=Teff Recall that and with m in AMU and k=1.38x10-16 How does ke compare to kRosseland

Class Investigation Compare kbf at l=5000A and level T=Teff for the two models provided Recall that and k=1.38x10-16, a0 =1x10-26 And Use the hydrogen ionization chart from your homework.