Nutrient Removal Project: Chemical Phosphorus Removal Jill Crispell, Stephanie Wedekind, Sarah Rosenbaum.

Slides:



Advertisements
Similar presentations
Understanding Serial Dilutions and Concentration
Advertisements

CE Lab Jar Test.
Biological waste water treatment
Introduction The Oberlin College Living Machine (LM) is a wastewater treatment facility designed to model the functional processes of nutrient removal.
On-Site Wastewater Conditioning System for Phosphorus Removal An Interim Report NALMS Chris Mikolajczyk, CLM, Princeton Hydro, LLC Paul Sutphen,
Stoichiometry of Precipitation Reactions
The Basics of Phosphorus Removal
Phosphorus Removal at Sand Creek Water Reuse Facility by Duane “Bear” Steib and Kathy Bill/City of Aurora Steve Polson/CH2M HILL by Duane “Bear” Steib.
WEAO2012 Technical Conference USING ONLINE ANALYZER FOR OPTIMIZING CHEMICAL PHOSPHORUS REMOVAL PROCESS IN MUNICIPAL WASTEWATER TREATMENT Ottawa, Ontario,
Biochemical Oxygen Demand (BOD) CE Lab. Introduction The Biochemical Oxygen Demand (BOD) test measures the oxygen consumed by microorganisms in.
U5 - Water Water Use & Management. Water Use  More than 1 billion people lack access to clean freshwater  Water used for residential, industrial, or.
Chapter 4 Chemical Reactions.
Surface Water Treatment Plant
Stoichiometry: Quantitative Information about chemical reactions.
Objective:  write a formula equation, complete ionic equation, and net ionic equation that represent a reaction.
Chapter 15 Solutions. Chapter 15 Table of Contents Copyright © Cengage Learning. All rights reserved Solubility 15.2 Solution Composition: An Introduction.
Coagulation and Flocculation
Coagulation in Industrial water Treatment
Control of Struvite Deposition in Wastewater Treatment Plants
Characterization of Al-Humic Complexation and Coagulation Mechanism Removal of natural organic matter (NOM) by coagulation using metal coagulants (aluminium.
Jar Testing Coagulation Dosage Water Treatment Plants
Conventional Surface Water Treatment for Drinking Water.
The Solubility Product Principle. 2 Silver chloride, AgCl,is rather insoluble in water. Careful experiments show that if solid AgCl is placed in pure.
1 Solution Stoichiometry The concentration of a solution is the amount of solute present in a given quantity of solvent or solution. M = molarity = moles.
MOLARITY A measurement of the concentration of a solution Molarity (M) is equal to the moles of solute (n) per liter of solution M = n / V = mol / L 2.
Sample Titration Problems
Some Applications Involving Separable Differential Equations.
Soil Buffering and Management of Acid Soils. pH pH = - log (H + ) If (H + ) = 1 x mol/L (H + ) = mol/L pH = - log (1 x ) pH = - (-3)
Ksp and Solubility Equilibria
PHOSPHORUS REMOVAL FOR LAGOON OPERATORS WHY THE CONCERN OVER P.
Stoichiometry. The Basics  What is stoichiometry?  A method of determining the quantities of products produced in a chemical reaction or what amount.
Phosphorus Removal in a Membrane Reactor System— A Demonstration Study Wayne Lorenz, P.E. and Matthew J. Gavin Wright Water Engineers, Inc. and Newell.
The Living Machine & Leachate
Water Treatment Processes. Why do we need to treat our drinking water?  Industrial runoff  Agricultural runoff  Road runoff  Residential runoff.
112.3 PHOSPHATE ADSORPTION RESULTS Measuring Phosphorus Retention Capacity in the Marsh Substrate of an Ecologically Engineered Wastewater Treatment Facility.
The Drinking Water Treatment Process
Chemical Treatment Precipitation and Reduction/Oxidation (Section 9-4)
Stoichiometry Calculations based on chemical reactions.
The Phosphate Filter: Which Type of Soil? Noah Haibach Central Catholic HS
 Most reactions occur in aqueous solutions because water is cheap, easily accessible and dissolves many substances  Chemicals mix more completely when.
Chapter 19 Acids, Bases, and Salts 19.5 Salts in Solution
1 Lake water (raw) Flocculation Flash mix Gentle mix Quiescent condition Sedimentation Precipitation Coagulant.
Section 4.6 Solution Stoichiometry and Chemical Analysis.
Date: Monday, May 11 th 2015 Topic: Water Purification Objective: To recognize the stages of it.
Aqueous Reactions © 2015 Pearson Education, Inc. Compilation Presentation Chapter 4 [4.5] Reactions in Aqueous Solution James F. Kirby Quinnipiac University.
Stoichiometry A chemical equation shows the reactants (left side) and products (right side) in a chemical reaction. A balanced equation shows, in terms.
1 What weight of sulfur (FW = ) ore which should be taken so that the weight of BaSO 4 (FW = ) precipitate will be equal to half of the percentage.
A Study on Optimizing Biological Phosphorous Removal by Changing Aerobic Operating Times Phillip Dixon and Juan Diaz-Robles CEE 453 Laboratory Research.
Presentation by Chelsea Smith March 11, My Background Southern Wells (K-12) Graduated in 2010 Ball State University ( ) BS in Environmental.
Diluting a solution Amount of moles of solute before dilution Amount of moles of solute after dilution = c D V D = c C V C Practice problems: p. 321.
Titrations. Standard Solution Sample Solution Burette A titration is a volumetric analysis technique used to find the [unknown] of a sample solution by.
Percent Yield. “yield—” the amount of product actually made through a chemical reaction. Why is this value important? Theoretical yield— calculated amount.
 Concerned with identifying the identity of a substance  Or whether a specific substance is present  i.e. flame test, litmus tests.
Section 15.1 Forming Solutions Steven S. Zumdahl Susan A. Zumdahl Donald J. DeCoste Gretchen M. Adams University of Illinois at Urbana-Champaign Chapter.
Stoichiometry: Quantitative Information About Chemical Reactions Chapter 4.
© 2009, Prentice-Hall, Inc. Molarity Two solutions can contain the same compounds but be quite different because the proportions of those compounds are.
ENVIRONMENTAL SCIENCE 5.4 The Waterworks. At the Waterworks When reservoirs or rivers are the source of drinking water, the water must be treated to remove.
The Waterworks Section 5.4. How does fresh water reach you? Ancient Romans built aqueducts – canals to carry water from the mountains to the city… some.
Course TEN-702 Industrial waste management unit-2
Sudan Raj Panthi Advanced Remediation and Treatment (ART), Lab Biological Phosphorus Removal.
Research on Tube Settlers and Flocculation
Lecture (8): liquid wastes treatment (primary, vital, advanced).
Particle separation: Chemical precipitation
One of the most important substances on Earth.
Streaming Current Detectors
Water Treatment.
TERTIARY TREATMENT METHODS
Jar Testing of Chemical Dosages
Water Treatment.
Water Quality Vocabulary Oct 18, 2011
Presentation transcript:

Nutrient Removal Project: Chemical Phosphorus Removal Jill Crispell, Stephanie Wedekind, Sarah Rosenbaum

Objectives Reduce the concentration of phosphorus in the effluent of the wastewater treatment plant by precipitating the phosphorus with varying concentrations of metallic salts Total phosphates should not exceed a concentration of 50ug/L in a stream entering a lake or reservoir

Hypothesis As the concentration of a metallic salt added increases, the concentration of phosphorus in the effluent should decrease from 4 mg/L to a value less than 50  g/L. The final phosphorus concentration will be independent from the concentration of metallic salts at high metallic salts concentrations. Metallic salts conc. Phosphorus Conc.

Setup

Setup Flow Rate: – 450 mL/min Reagents: – Phosphorus solution: 200 mg/L KH 2 PO 4 – Alum solution: 400 mg/L Al 2 (SO 4 ) 3 o 14H 2 O – Ferric Chloride: 200 mg/L FeCl 3

Methods First experiment: Effect of flocs – In each cycle, phosphorus and water added to bring concentration to 4 mg/L – Only in first cycle alum (12.5 mg/L) or ferric chloride (6.8 mg/L) Al 2 (SO 4 ) 3­ o 14H 2 O + 2PO 4 3-  2AlPO 4 + 3SO H 2 O FeCl 3 + PO 4 3-  FePO 4 + 3Cl -

Results: First experiment Alum was more effective than ferric chloride in removing phosphorus. Discovered original influent water contained ferric chloride Flocs remaining in tank continued to react with the phosphorus added

Results: First experiment cont.

Solutions to our Discoveries: – Decided to pump tap water into the plant from a large jug. – Completely drain the tank. – Added two new states, rinse and rinse effluent, to clean out the tank of all flocs.

Second experiment: Increasing concentration of alum Different concentrations, 10 mg/L, 12.5 mg/L, 15 mg/L and 25 mg/L, of alum were used to determine which concentration removes phosphorus most efficiently All samples were analyzed using the spectrophotometer to determine the amount of phosphorus remaining in the effluent.

Results: Second experiment As alum concentration in the plant increased, phosphorus concentration decreased and percent removal increased based on samples with 10 mg/L, 12.5 mg/L, 15 mg/L and 25 mg/L of alum respectively

Results: Second experiment cont.

Although we did not meet our goal of 50  g/L, our high percent removal indicates that the alum is effective Generally, the trend appears to be decreasing

Results: Second experiment cont. More testing is necessary to determine if the phosphorus reaches a minimum concentration There cannot be 100% removal (and thus a linear solution) because there is a saturation level in which additional alum no longer effects phosphorus removal

Results: Second experiment cont. According to the stoichiometry of the equations, we should have only needed to use a concentration of 12.5 mg/L of alum to completely react with the 4 mg/L of phosphorus, but much more is needed. Reasons: other reactants in water, more mixing time.

In the future we would… Test higher concentrations of alum Try mixing alum and FeCl 3 Adjust the pH to be in the optimum range of the coagulants (4.5-5 for FeCl 3, for Alum) – Our pH was between 8.3 and 8.4

THE END Have a great summer!