Hazardous Materials: Information Resources Unit 3 Hazardous Materials: Information Resources

Introduction Chemical information available through variety of sources Shipper and facility required to maintain certain documents Know what information is available Understand how to interpret the information in common sources

Emergency Response Guidebook Known as the “DOT Book” or the “Orange Book” Published every four years Covers Canada, Mexico, and the USA http://hazmat.dot.gov/gydebook.htm DOT's NAERG is a well-known book for emergency responders. The NAERG book is commonly referred to as the DOT book or the orange book. Hazardous materials are transported through three countries. Therefore, the NAERG book was produced to cover the transportation of hazardous materials for all three countries. Available in English, French and Spanish. Chapter 26

Emergency Response Guidebook DOT makes one copy for every emergency response apparatus in the country Provides information regarding potential hazards Intended as a guide for first responders during the initial phases of a hazardous materials incident

Figure 26-1 The DOT Emergency Response Guidebook should be found in every emergency vehicle in the United States. It provides chemical emergency response information that is valuable to the first responder.

Emergency Response Guidebook Consists of these major sections: Placard information ADR/RID marking system information Listing by DOT identification number Alphabetical listing by shipping name Response guides Table of initial isolation and protective action distances List of dangerous water-reactive materials

Emergency Response Guidebook This Department of Transportation book provides a contact number for federal assistance, although responders should proceed initially by requesting local, state, and then federal assistance. Different emergency contact numbers for Canutec in Canada, USA and Mexico. Chapter 26

Emergency Response Guidebook You must be familiar with guide prior to an incident. Abbreviations are used in the DOT ERG. The guide provides a list of the hazard class system. It is important for first responders to read the DOT book prior to an incident because it provides a large amount of background material that could not be read during an emergency. Chapter 26

Emergency Response Guidebook Placard information Information about how to proceed at an incident where the only information available in a placard Guide for explosives

Emergency Response Guidebook Yellow section Numerical listing by DOT identification number Can be used when placard is visible Highlighted numbers – turn to orange and green sections The yellow section is a numerical listing by the identification, or ID, number. It is important to be familiar with the abbreviations used in the DOT NAERG. Chapter 26

Emergency Response Guidebook Blue section Alphabetical listing by chemical shipping name For reference with shipping papers High lightened numbers – turn to orange and green sections The blue section of the book mirrors the yellow section except it is sorted in alphabetical order by shipping name. Chapter 26

Emergency Response Guidebook Orange section Actual guide pages for more than 4,000 chemicals Sixty-one total response guides Three-digit number ·        The orange section makes up the actual guide pages. ·        A total of sixty-one guides are given for the more than 4,000 chemicals listed by the DOT. ·        Chapter 26

Emergency Response Guidebook Two pages per guide, divided into three sections Potential hazards Public safety Emergency response Each guide takes up two pages and is divided into three sections: potential hazards, public safety, and emergency response. ·        The potential hazards section lists the predominant hazard on the top line. ·        The public safety section provides information for the initial public protection options, as well as key issues for the safety of the responders. ·        The public safety section, and the Table of Initial Isolation and Protective Action Distances, make this book necessary for all responders. ·        The public safety section also lists the PPE recommendations and provides four basic PPE scenarios. ·        The emergency response section provides information regarding fires, spills, and first aid. ·        The spill or leak section lists some general tactical objectives and provides some specific information on certain substances. ·        The first-aid section provides information on basic medical treatment and some basic decontamination recommendations for chemical burns. Chapter 26

Using the DOT Emergency Response Guidebook Look up the three digit guide number of the material in either: ID number index Name of the material index Turn to the numbered guide

Emergency Response Guidebook Green section Table of initial isolation and protective action distances for highlighted chemicals Subdivided Small and large spills Day or night ·        The Table of Initial Isolation and Protective Action Distances is the green section in the back of the book. ·        This section is further subdivided between small spills and large spills, and both are divided between day and night distances. Chapter 26

Emergency Response Guidebook Evacuation distances List of dangerous water-reactive materials ·        The last subdivision included in the green section is the List of Dangerous Water-Reactive Materials. This section provides the evacuation distances for these materials if they contact water. Chapter 26

Emergency Response Guidebook WMD cross reference is now available. PPE levels of protection are listed. It is available for online reference and download.

Figure 26-13 A large spill of ethyl isocyanate (ID 2481) is listed as having an isolation distance of 1,700 feet in all directions. In such a case, responders need to protect those persons downwind for 7+ miles.

Using the DOT Emergency Response Guidebook Resist rushing in Approach incidents from an uphill/upwind direction Identify the material by finding one of the following: Four digit ID on placard/ID panel Four digit ID number on shipping document or package Name of material on shipping document, placard, or package

Material Safety Data Sheets Result of the hazard communication standard Employers with larger than “household quantities” must create MSDS Required to have a variety of information Intent is to protect employees working at the facility

Material Safety Data Sheets Quality of information varies from MSDS to MSDS Typical MSDS provides a worst-case scenario Firefighter should rely more on technical information on MSDS MSDS has remained the same since inception

Using the MSDS Wisely Always use more than one source of information Determine action plan using MSDS Determine chemical threat Don appropriate level PPE If material has released, follow evacuation procedure and secure building Determine which extinguishing agents are required

Accidents and How the MSDS Relates Chemical information on MSDS usually presents hazards associated with particular product Once product is placed in a process some factors may change Increase, decrease, or elimination of hazards Factors include: Reactions with other chemicals Changes in temperature, pressure, or physical characteristics

MSDS in the Workplace Employers to provide employees with an MSDS for every hazardous chemical An MSDS provides information on physical/chemical characteristics and first-aid procedures

MSDS in the Workplace Can be insufficient depending on provider Vagueness Technical jargon Understandability Product versus process Missing information

Shipping Papers Shipping papers generally provide the following information: Shipping company Destination of packages Emergency contact information Number and weight of packages Proper shipping name of materials Hazard class of materials Special notation for hazardous materials

Mode of Transportation Shipping papers are also called a bill of lading Papers should be close to the driver On tank trucks a duplicate set is located in a tube attached near landing gear Hazardous materials are sometimes color coded For rail, shipping papers are called consist or waybill and placed in control of the engineer

Mode of Transportation Most railcars are identified well Standard Transportation Commodity Code (STCC) Seven-digit number Number beginning with “49” are hazardous On a ship, papers are called dangerous cargo manifest (DCM) and placed in control of the captain In air, shipping paper are called Air Bills and placed in control of the captain

Facility Documents Those with an MSDS requirement: Tier 2 form Site plan Those with extremely hazardous substances (EHS) Emergency plan Many facilities leave MSDS binder at gate with security guard SARA reports updated annually and should be reviewed by responders

Chemtrec Chemical Transportation Emergency Center Information service provided by American Chemistry Council Chemtrec service Chemtrec is well connected Chemtrec does not make regulatory notifications

Chemtrec Responder should have the following information when calling Chemtrec: Caller’s name and phone number Name of the shipper or manufacturer Shipping paper information

Industrial Technical Assistance Each community usually has a technical specialist in a given field Many areas of the country have industrial mutual aid groups designed to assist each other Each industrial facility usually has a person responsible for safety and health Many facilities have industrial hygienists

Lessons Learned Obtain as much information as possible Information combined with reference sources can provide useful data Obtain as much information as possible prior to arriving on scene Responders should not take risks attempting to get this information