Durham Technical Community College Hazard Communication Annual Training Requirement 2013 - 2014 Your “Right to Know” Note: if a web-link does not seem to work, click it a second time.

Five Stages of the Program (Material) Safety Data Sheets MSDSs and SDSs Labeling and Marking Systems Employee Training Written Plan Chemical Inventory List

Durham Technical Community College Hazard Communication (Material) Safety Data Sheets

Hazard Communication (Material) Safety Data Sheets Company Information Hazardous Ingredients Physical Data Fire and Explosion Data Health Hazard Data Reactivity Data Spill & Leak Procedures Special Protection Information Special Precautions Safety Data Sheets are replacing MSDSs after 2013.

(Material) Safety Data Sheets: Your Rights 1. Your employer must have an MSDS or SDS for every hazardous substance you use as part of your job. They are online at http://www.durhamtech.edu/faculty/safety/

Finding (M)SDS Information Online Main DTCC web under QuickLinks: Emergency and Safety Information Under DTCC Emergency Information: Chemical Safety Data Directly: www.durhamtech.edu/faculty/safety/

MSDS & SDS on www.durhamtech.edu/faculty/safety If you are in a Chemistry Lab, click the “Chemistry” link

Searching for (M)SDS Information Type Ctrl-f for search-box (will appear on top or bottom of window) Type part of the name or CAS# - the first ‘hit’ will be highlighted Press the Enter-key to go to the next match Click the link for (M)SDS

Hazards: (M)SDS SDS has the Hazards in Section 2. CLICK to View Actual Sheets Hazards: (M)SDS SDS has the Hazards in Section 2. MSDS has the Hazards in Section 3.

Every SDS Has These Sections Section 1, Identification Section 2, Hazard(s) Section 3, Composition/ingredients Section 4, First-aid & symptoms/effects Section 5, Fire-fighting measures Section 6, Accidental release measures Section 7, Handling and storage Section 8, Exposure controls & PPE.

Every SDS Has These Sections Section 9, Physical and chemical properties Section 10, Stability and reactivity. Section 11, Toxicological information Section 12, Ecological information Section 13, Disposal considerations Section 14, Transport information Section 15, Regulatory information Section 16, Other information

(Material) Safety Data Sheets: Your Rights 2. These MSDS or SDS must be available to you the entire time you are in the workplace. At DTCC (M)SDS sheets are available on-line and sometimes as a printed copy with the chemicals being used.

(Material) Safety Data Sheets: Your Rights If you request to see a copy of an MSDS/SDS for a product you use, and your supervisor cannot provide it after one working day, you may refuse to use that product or work in an area where it is being used. Note: Most (M)SDS are Online

(Material) Safety Data Sheets: Your Rights 4. If you request your own personal copy of an MSDS/SDS, your employer has 15 days to provide it. Ask your supervisor or the Safety Officer. Note: Online copies are printable

Durham Technical Community College Hazard Communication Labeling and Marking Systems

Labeling and Marking Systems NFPA Diamonds HMIS Labels GHS Labels and Pictograms Uniform Laboratory Hazard Signage System

Labeling and Marking Systems NFPA Diamonds Color coded, numerical rating system Will be located near main entrances, fire alarm panels, or on outside entrance doors Provide at-a-glance hazard information

Labeling and Marking Systems NFPA Diamonds Blue = Health Red = Flammability Yellow = Instability White = Special hazard information

Labeling and Marking Systems NFPA Diamonds 4= Deadly Hazard 3= Severe Hazard 2= Moderate Hazard 1= Slight Hazard 0= No Hazard

Labeling and Marking Systems HMIS Labels Designed to go on individual containers of products that don’t have the manufacturer’s labels Uses the same color code/numerical rating system as the NFPA diamonds 3 1 

Never use food containers for storage of hazardous chemicals! Labeling Containers You should never have any unattended, unlabeled hazardous chemical containers in your workplace! Never use food containers for storage of hazardous chemicals! Help with an unlabeled container: talk to your supervisor or the Safety Officer.

The Globally Harmonized System (GHS) for Hazard Classification and Labeling Replaces our current system Old labels gradually replaced Old NFPA Diamonds on bottles replaced by Pictograms Old NFPA 0-4 rating replaced by GHS category 5-1 MSDSs replaced by SDSs

NFPA compared to GHS Ratings Old New NFPA GHS Category 1 severe hazard Category 2 serious hazard Category 3 moderate hazard Category 4 slight hazard Category 5 minimal hazard 4 = severe 3 = serious 2 = Moderate 1 = Slight 0 = Minimal NOTE: 4 is severe in NFPA but corresponds to Category 1 in GHS Big numbers bad in NFPA but Little numbers are bad in GHS.

Pictograms Signify Hazards - Know These - Explosives, Self-reactives Gases under pressure Oxidizers Corrosive, Eye damage Aquatic toxicity ! Poison, Highly toxic, Fatal Systemic Effects: Carcinogen, Mutagen, Reproductive toxicity, Respiratory sensitizer, Target organ toxicity, Aspiration toxin Flammables, Pyrophoric, Organic peroxides Irritant, Skin sensitizer, Low toxicity, Narcotic effects

IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Explosives, Self-reactives

IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Flammable

IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Pressurized Gasses

IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Irritant

! IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Systemic or Organ toxic

IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Corrosives

IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Poisons

IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Oxidizers

! IDENTIFY The Circled Pictogram (2) (3) (5) (6) (7) (8) (9) (2) (3) (5) (6) (7) (8) (9) ! Explosives, Self-reactive Gases under pressure Aquatic toxicity Corrosive Oxidizers Poison, Highly toxic Organ toxicity; Carcinogen Flammable Irritant; Skin sensitizer CLICK answer in box above Environmental or Aquatic Toxin

GHS labels use SIGNAL Words, HAZARD Statements and PICTOGRAMS Pictograms (for hazard category 1 & 2) Instructions The 2 Signal Words are: Warning or Danger

YouTube video on GHS labels Watch this video for more information on GHS Labels GHS HazCom Training Video Click this link

Labeling and Marking Systems Uniform Laboratory Signage Located on laboratory and chemical storage area doors Pictographs depict worst hazards present in lab or area

Labeling and Marking Systems Uniform Laboratory Signage Always check with the appropriate personnel (lab manager, Safety Officer, etc.) before performing work or maintenance in a laboratory!

Durham Technical Community College Hazard Communication Employee Training

Hazard Communication Employee Training Training is required: Within the first 30 days of employment Whenever new hazards are introduced Annually

Hazard Communication Employee Training The training must cover: Requirements of regulations Location and availability of (M)SDSs Hazardous chemicals used in your workplace Physical and health hazards Measures for personal protection Details and location of the written plan

Hazard Communication Employee Training Safety is 1st YOUR responsibility. This presentation provides general safety “Right-To-Know” training. Your Supervisor or Instructor is responsible for their employee or student’s specific safety orientation. The DTCC Safety Officer may also be consulted with questions or concerns.

Personal Protective Equipment Examples Personal Protective Equipment Eyewear (Safety Glasses, Goggles, Face-Shields) Gloves (Hot-Cold, Electrical, Chemical) Aprons, Lab Coats Hearing Protection Breathing (Respirators, Dust, Self-Contained BA) Safety Shoes Hard Hats

Durham Technical Community College Hazard Communication The Written Plan

Hazard Communication The Written Plan You have a right to possess your own copy of DTCC’s written hazard communications plan available online at: http://www.durhamtech.edu/faculty/safety/HealthandSafetyManual.pdf Click this link for the printable document

Hazard Communication The Written Plan If you are exposed to a hazardous substance at work, you should report it at once to your supervisor.

Hazard Communication Chemical Inventory List Federal law requires an inventory of all chemicals on the DTCC campuses, and that it be updated annually. The Chemical Inventory List is available at: www.durhamtech.edu/faculty/safety Click this link for the page with the Excel inventory

Emergency Response If an emergency occurs in your area, have someone contact CAMPUS POLICE/SECURITY at x5555 or (919)536-7255 FIRE: Evacuate to outside locations posted on Evacuation Signage*. Use extinguisher if trained. SPILL: Evacuate area. Clean-up only if trained. EXPOSURE: rinse for 15 minutes with water. WEATHER: Move to Weather Shelter Rooms posted on Evacuation Signage*. SECURITY ISSUE: FLEE if safe - lock door and HIDE if not - FIGHT if necessary. *Posters are being installed in buildings now

Durham Technical Community College Hazard Communication BE SAFE, NOT SORRY! TO COMPLETE YOUR TRAINING GO TO THE NEXT SLIDE FOR A TEST OF YOUR KNOWLEDGE

TAKE THIS BRIEF TEST 10 Questions Use this button if you want to restart the test

Question 1: click the correct response 1. What is the purpose of an (M)SDS? It protects you from illegal or hazardous form of the substance It describes the hazards and properties of substances It contains all the information available about a substance It tests your knowledge about a chemical or substance.

Hazard Communication (Material) Safety Data Sheets Back INCORRECT – REVIEW & TRY AGAIN Hazard Communication (Material) Safety Data Sheets Company Information Hazardous Ingredients Physical Data Fire and Explosion Data Health Hazard Data Reactivity Data Spill & Leak Procedures Special Protection Information Special Precautions It describes the hazards and properties of substances Safety Data Sheets are replacing MSDSs after 2013.

It describes the hazards and properties of substances Question 1: CORRECT! 1. What is the purpose of an (M)SDS? It describes the hazards and properties of substances Next

Question 2: click the correct PICTOGRAM ! Question 2: click the correct PICTOGRAM Explosives, Self-reactives

Pictograms Signify Hazards Back INCORRECT – REVIEW & TRY AGAIN Pictograms Signify Hazards Explosives, Self-reactives Gases under pressure Oxidizers Corrosive, Eye damage Aquatic toxicity ! Poison, Highly toxic, Fatal Systemic Effects: Carcinogen, Mutagen, Reproductive toxicity, Respiratory sensitizer, Target organ toxicity, Aspiration toxin Flammables, Pyrophoric, Organic peroxides Irritant, Skin sensitizer, Low toxicity, Narcotic effects

Question 2: CORRECT! Explosives, Self-reactives Next

Question 3: click the correct PICTOGRAM ! Question 3: click the correct PICTOGRAM Corrosive!

Question 3: CORRECT! Corrosive! Next

Question 4: click the correct PICTOGRAM ! Question 4: click the correct PICTOGRAM Poison!

Question 4: CORRECT! Poison! Next

Question 5: click the correct PICTOGRAM ! Question 5: click the correct PICTOGRAM Flammable!

Question 5: CORRECT! Flammable Next

Question 6: click the correct PICTOGRAM ! Question 6: click the correct PICTOGRAM Irritant or Harmful if Swallowed

Irritant or Harmful if Swallowed Question 6: CORRECT! ! Irritant or Harmful if Swallowed Next

Question 7: click the correct PICTOGRAM ! Question 7: click the correct PICTOGRAM Oxidizer!

Question 7: CORRECT! Oxidizer! Next

Question 8: click the correct PICTOGRAM ! Question 8: click the correct PICTOGRAM Water Toxicity

Water or Aquatic Toxicity Question 8: CORRECT! Water or Aquatic Toxicity Next

Find the DTCC Safety Data Sheet for "o-Cresol" next Open a new web page window: http://www.durhamtech.edu (<-click) under QuickLinks click Emergency & Safety Information click Chemical Safety Data page click Chemistry and Biology section Click the DTCC-SDS for "o-Cresol “ (scroll or type “Ctrl-F” to search by name) After opening the SDS click the “Next” btn.

Question 9: using the information on the SDS, click the correct answer 9. What is the SIGNAL WORD for o-Cresol? Caution Warning Danger There is no signal word for this substance

Pictograms & Signal Word Back INCORRECT – REVIEW & TRY AGAIN Hazards: (M)SDS Look for the Hazards in Section 2. Note: this is not the SDS for the substance you are looking up. Pictograms & Signal Word

Question 9: CORRECT! 9. The SIGNAL WORD for o-Cresol is: Danger Next

There are no PICTOGRAMS for this substance Question 10: using the information on the SDS, click the correct answer 10. What are the PICTOGRAMS for o-Cresol? ! There are no PICTOGRAMS for this substance

Pictograms & Signal Word Back INCORRECT – REVIEW & TRY AGAIN Hazards: (M)SDS Look for the Hazards in Section 2. Note: this is not the SDS for the substance you are looking up. Pictograms & Signal Word

Question 10: CORRECT! 10. The PICTOGRAMS for o-Cresol are: Next

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