Lecture 0202 Atomic Weights and the Periodic Table

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Presentation transcript:

Lecture 0202 Atomic Weights and the Periodic Table

Quick Quiz © 2009, Prentice-Hall, Inc.

Symbols of Elements Elements are symbolized by one or two letters. © 2009, Prentice-Hall, Inc.

Atomic Number All atoms of the same element have the same number of protons: The atomic number (Z) © 2009, Prentice-Hall, Inc.

Atomic Mass The mass of an atom in atomic mass units (amu) is the total number of protons and neutrons in the atom. © 2009, Prentice-Hall, Inc.

Isotopes Isotopes are atoms of the same element with different masses. Isotopes have different numbers of neutrons. 11 6 C 12 6 C 13 6 C 14 6 C © 2009, Prentice-Hall, Inc.

Practice Exercise 2.1 The diameter of a US penny is 19 mm. The diameter of a silver atom, by comparison, is only 2.88 Å. How many silver atoms could be arranged side by side in a straight line across the diameter of a penny? © 2009, Prentice-Hall, Inc.

Practice Exercise 2.2 How many protons, neutrons, and electrons are in (a) an atom of 197Au; (b) an atom of strontium-90? © 2009, Prentice-Hall, Inc.

Atomic Mass Atomic and molecular masses can be measured with great accuracy with a mass spectrometer. Figure 2.13 © 2009, Prentice-Hall, Inc.

Average Mass Because in the real world we use large amounts of atoms and molecules, we use average masses in calculations. Average mass is calculated from the isotopes of an element weighted by their relative abundances. © 2009, Prentice-Hall, Inc.

Practice Exercise 2.3 Naturally occurring chlorine is 75.78% 35Cl, which has an atomic mass of 34.969 amu, and 24.22% 37Cl, which has an atomic mass of 36.966 amu. Calculate the average atomic mass (that is, the atomic weight) of chlorine. © 2009, Prentice-Hall, Inc.

Practice Exercise 2.4 Give the chemical symbol, including mass number, for each of the following ions: (a) The ion with 22 protons, 26 neutrons, and 19 electrons; (b) the ion of sulfur that has 16 neutrons and 18 electrons. © 2009, Prentice-Hall, Inc.

Periodic Table It is a systematic catalog of the elements. Elements are arranged in order of atomic number. © 2009, Prentice-Hall, Inc.

Periodicity When one looks at the chemical properties of elements, one notices a repeating pattern of reactivity's. © 2009, Prentice-Hall, Inc.

Periodic Table The rows on the periodic chart are periods. Columns are groups. Elements in the same group have similar chemical properties. © 2009, Prentice-Hall, Inc.

Groups These five groups are known by their names. © 2009, Prentice-Hall, Inc.

Periodic Table Nonmetals are on the right side of the periodic table (with the exception of H). © 2009, Prentice-Hall, Inc.

Periodic Table Metalloids border the stair-step line (with the exception of Al, Po, and At). © 2009, Prentice-Hall, Inc.

Periodic Table Metals are on the left side of the chart. © 2009, Prentice-Hall, Inc.

Chemical Formulas The subscript to the right of the symbol of an element tells the number of atoms of that element in one molecule of the compound. © 2009, Prentice-Hall, Inc.

Chemical Formulas Molecular compounds are composed of molecules and almost always contain only nonmetals. © 2009, Prentice-Hall, Inc.

Diatomic Molecules 1 + 6 = 7 diatomic elements These seven elements occur naturally as molecules containing two atoms. © 2009, Prentice-Hall, Inc.

Types of Formulas Empirical formulas give the lowest whole-number ratio of atoms of each element in a compound. Molecular formulas give the exact number of atoms of each element in a compound. Example: B2H6 vs. BH3 © 2009, Prentice-Hall, Inc.

Types of Formulas Structural formulas show the order in which atoms are bonded. Perspective drawings also show the three-dimensional array of atoms in a compound. © 2009, Prentice-Hall, Inc.

© 2009, Prentice-Hall, Inc.

Ions When atoms lose or gain electrons, they become ions. Cations are positive and are formed by elements on the left side of the periodic chart. Anions are negative and are formed by elements on the right side of the periodic chart. © 2009, Prentice-Hall, Inc.

Ionic Bonds Ionic compounds (such as NaCl) are generally formed between metals and nonmetals. © 2009, Prentice-Hall, Inc.

Writing Formulas Because compounds are electrically neutral, one can determine the formula of a compound this way: The charge on the cation becomes the subscript on the anion. The charge on the anion becomes the subscript on the cation. If these subscripts are not in the lowest whole-number ratio, divide them by the greatest common factor. © 2009, Prentice-Hall, Inc.

Common Cations © 2009, Prentice-Hall, Inc.

Common Anions © 2009, Prentice-Hall, Inc.

Practice Exercise 2.5 What are the empirical formulas of the compounds formed by (a) Al3+ and Cl– ions, (b) Al3+ and O2– ions, (c) Mg2+ and NO3– ions? © 2009, Prentice-Hall, Inc.