Fertilizers and Population Influencing the Nitrogen Cycle
Nitrogen and Plants Plants need nitrogen Proteins Nucleic Acids Plants can not use non-reactive nitrogen from the atmosphere N2 Plants can use reactive nitrogen from the soil NO3– (nitrate) NO2– (nitrite) Lots of atmospheric N2 Reactive soil N is limited
Nitrogen and Farms In a natural ecosystem (ie. a redwood forest), N is recycled when plants/animals die In a managed agricultural system (ie. a wheat farm), N is taken away when the crop is harvested Soil N must be replenished Crop rotation Compost/manure Artificial fertilizers
Fertilizer as Agricultural Input Fertilization allows for increased yields (kg food/acre) 200-300 lb/acre $100-$300/acre Not all fertilizer is used by the plants
Fertilizer as an Agricultural Input Both fertilizer use and agricultural yield/production have increased over the past 50 years
Nitrogen Cycle
Nitrogen Cycle How does N go from atmosphere (non-reactive) to soil (reactive)? Lightning Biological fixation by symbiotic bacteria Industrial fixation (fertilizers) How does N go from biosphere – plants and animals – to the soil? Decomposition Wastes (urine and feces)
Nitrogen Cycle
Nitrogen Cycle
Artificial Fertilizers Process developed by Haber and Bosch in early 20th century Uses N from atmosphere and H from methane to make ammonia (NH3) Requires lots of energy to generate heat and pressure
Haber-Bosch Process Nitrogen From air 400-450º C 200 atmospheres Iron catalyst Liquid Ammonia (NH3) Hydrogen from methane (natural gas) or petroleum What will run out first – nitrogen, hydrogen or the energy for heat/pressure?
Artificial v. Natural Artificial/Industrial Produced rapidly and in large quantities N is in form readily available to plants N levels are high and can be adjusted Fossil fuel intensive (both matter and energy) Natural Uses plants (compost) + animal wastes (manure) Process is slow N must be broken down to be available to plants N levels are lower than artificial fertilizers Does not require energy inputs/fossil fuels
The Questions Is human manipulation of the global nitrogen cycle good or bad? Pros: increased crop yields, increased food, increased profits Cons: impacts on soil, water and air Are increased crop yields worth the environmental costs? What evidence would inform this decision? Is the use of industrial fertilizers sustainable? If so, for how long? What evidence would inform this? Are there alternatives to industrial fertilizers? Are these alternatives more sustainable? What evidence would inform this?