Presentation is loading. Please wait.

Presentation is loading. Please wait.

 What is Evaporation?  What is Boiling point?  Comparison between Evaporation and Boiling Point.

Similar presentations


Presentation on theme: " What is Evaporation?  What is Boiling point?  Comparison between Evaporation and Boiling Point."— Presentation transcript:

1

2  What is Evaporation?  What is Boiling point?  Comparison between Evaporation and Boiling Point

3  Occurs faster when: - The surface of exposed area is larger - The temperature is higher - The humidity is lower - There is wind - Surface tension is higher( vapor pressure )

4  Occurs at: - Any temperature - Only on the surface - Rate changes when atmosphere pressure changes

5  Look at the 2 molecules in the liquid.  Molecule 1 on the surface experiences less attractive cohesive forces than Molecule 2 as half of it is exposed to the air while Molecule 2 is surrounded by water molecule all around it.

6  Molecules never stop vibrating - When they vibrate, they collide with each other and kinetic energy is passed on to each other. Therefore some molecules will posses more kinetic energy than others. - The amount of kinetic needed to break free from the attractive cohesive forces is less on the surface than under the surface as explained on the previous slide

7  Thus, evaporation only occurs on the surface of the liquid.

8 A B - B has more molecules exposed to the air than A, thus, more molecules can escape from the attractive cohesive forces. - Thus, with a larger area of exposed surface, the rate of evaporation would increase.

9 -Heat -With a higher temperature, there would be more heat energy and would result in higher kinetic present in the molecule, this would allow the molecule to escape more quickly. -Thus, a higher temperature would allow the rate of evaporation to increase.

10  If the surface tension is lower, the molecule would need to posses less kinetic energy to overcome the attractive cohesive forces.  And thus, a lower surface tension would result in a increased rate of evaporation.

11  There is a point where is saturated vapor point is reached. ( when no more vapor can evaporate anymore)  When the humidity is higher, the amount of vapor that can evaporate into the surrounding is small.  Thus, the rate of evaporation decreases as the humidity rises.

12  With wind, more air is brought over the surface of the liquid.  Thus, the air over the surface does not get saturated with water vapor. And so the rate of evaporation rises when wind is present.

13  Why when your sweat evaporate, you would feel cooler.  When the faster moving molecules leave the liquid, only the slower moving molecules are left in the liquid, making it lose heat.

14  The formula for calculating heat consumed by evaporation  g = Θ A (x s - x) (1) where g = amount of evaporated water (kg/h) Θ = (25 + 19 v) = evaporation coefficient (kg/m 2 h) v = velocity of air above the water surface (m/s) A = water surface area (m 2 ) x s = humidity ratio in saturated air at the same temperature as the water surface (kg/kg)humidity ratio in saturated air x = humidity ratio in the air (kg/kg)humidity ratio in the air Note! The units don't match since the equation is empirical (a result of experiments).

15

16  Factors that affect temperature of boiling point - Atmospheric pressure - Vapor pressure

17  Properties of boiling point( also known as saturation temperature ) - Occurs when vapor pressure is greater than atmospheric pressure. - Occurs in the entire volume of the liquid - Corresponds to the temperature at which vapor pressure is greater than atmospheric pressure.

18  Saturation pressure ( pressure where liquid boils into vapor corresponding the saturation temperature ) increases as saturation temperature rises  The higher the vapor pressure, the lower the boiling point  The boiling point does not increase even when more heat is added

19  Formula to calculate boiling point where: T B = the normal boiling point, K R = the ideal gas constant, 8.314 J · K -1 · mol -1ideal gas constant P 0 = is the vapor pressure at a given temperature, atm ΔH vap = the heat of vaporization of the liquid, J/mol T 0 = the given temperature, K ln = the natural logarithm to the base enatural logarithme

20  How boiling occurs -when vapor pressure is greater than atmosphere pressure

21  As the liquid is heated, its vapor pressure increases until it is greater then the atmospheric pressure.  To form vapor, the molecules must overcome the attractive cohesive forces

22  Is boiling point is lowered when the atmpsoheric pressure is lower.  As less energy (heat) is needed to increase to vapor pressure to meet the atmospheric pressure  In other words, the boiling point is determined by the atmospheric pressure and the vapor pressure

23  Different liquids boils at different temperature as they have different vapor pressure which is a factor that determines the boiling point.  Example

24 Boiling pointEvaporation Occurs in the entire liquidOccurs only on the surface Not affected by temperatureRate of evaporation increases as temperature increases Not affected by humidityRate of evaporation increase as humidity decreases Not affected by windRate of evaporation increases if wind is present Not affected by area of exposed surface areaRate of evaporation increases when area of exposed surface area increase Boiling point increases as atmospheric pressure decreases Rate of evaporation increases as atmospheric pressure decreases Occurs only vapor pressure is greater than atmospheric pressure Occurs in any temperature Boiling point decreases as surface tension decreases Rate of evaporation increases as surface tension decreases

25  http://www.engineeringtoolbox.com/evapora tion-water-surface-d_690.html http://www.engineeringtoolbox.com/evapora tion-water-surface-d_690.html  htthttp://www.chem.purdue.edu/gchelp/liqui ds/boil. htmlp://www.sciencedaily.com/articles/e/eva poration.htm htthttp://www.chem.purdue.edu/gchelp/liqui ds/boil. htmlp://www.sciencedaily.com/articles/e/eva poration.htm  http://en.wikipedia.org/wiki/Boiling_point http://en.wikipedia.org/wiki/Boiling_point


Download ppt " What is Evaporation?  What is Boiling point?  Comparison between Evaporation and Boiling Point."

Similar presentations


Ads by Google