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Vaporization.

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Presentation on theme: "Vaporization."— Presentation transcript:

1 Vaporization

2 Vaporization Evaporation in an open container. Condensation rate will probably never be as high as evaporation rate.

3 Vaporization

4 Vaporization Evaporation in a closed container. Condensation rate will eventually equal evaporation rate.

5 Vaporization

6 What factors affect the rate of evaporation?

7 How Temperature Affects Evaporation Rate

8 What factors affect the rate of evaporation?
Temperature Surface area Strength of intermolecular attractive forces

9 What factors affect equilibrium vapor pressure?

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15 What factors affect equilibrium vapor pressure?
Temperature Strength of intermolecular attractive forces

16 Boiling

17 Boiling

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19 An Exponential Equation for Pressure
P = β exp(-ΔHvap /RT) ln P = ln β + ln exp(-ΔHvap / RT) ln P = ln β - ΔHvap / RT ln P = ln β - (ΔHvap / R) (1 / T) Y = b + mX Plot ln P against 1 / T. Slope = -ΔHvap/R ΔHvap = -R . Slope where R = J / K mol

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21 The 2-Point Clausius-Clapeyron Equation
ln P = ln β - (ΔHvap / R) (1 / T) ln P2 = ln β - (ΔHvap / R) ( 1 / T2) Ln P1 = ln β - (ΔHvap / R) (1 / T1) ln P2 - ln P1 = (ΔHvap / R) (1 / T / T2) Ln (P2 / P1) = (ΔHvap / R) (1 / T1 - 1 / T2)

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