1. NOAA’s Atmospheric Mercury Monitoring in the Gulf of Mexico Region [April 2007 summary] This summary is updated periodically, and the current version is posted (in PowerPoint and PDF formats) at: http://www.arl.noaa.gov/data/web/reports/cohen/grand_bay_atmos_hg.ppt http://www.arl.noaa.gov/data/web/reports/cohen/grand_bay_atmos_hg.pdf 1

2.  Assemble a long-term, publicly available data record  Discern trends in atmospheric mercury concentrations  Derive dry deposition estimates  Elucidate mercury source-receptor relationships  Establish correlations with meteorology and ancillary trace species to better understand the emission, transport, transformations, and fate of mercury in the atmosphere  Provide a data set for model evaluation In September 2006, the National Oceanic and Atmospheric Administration (NOAA) Air Resources Laboratory (ARL) and the Grand Bay NERR established a long-term atmospheric monitoring station for the measurement of speciated mercury compounds and ancillary trace species at the Grand Bay (Mississippi) National Estuarine Research Reserve (NERR) in Moss Point, MS. The measurements are designed to: 2

3. Grand Bay Estuarine Research Reserve 3

4. November 2006: Update –Grand Bay NERR Ancillary trace measurements added October 20, 2006: CO, O 3, SO 2 Site operator selected and given initial training, SOP guidelines and instructions, Instrument status forms, etc. Scaffold Tower added Oct. 20, 2006 Current height of Inlet: 4 m Will add dedicated Met system and new CO detector Dec. 2006 Discussions proceeding on renovation of Pavilion site, addition of tilt-down tower, Internet communications, etc. Will establish MDN measurements FY2007 Equipment procurement: SO 2, Trailer improvements/replacement, Internet, etc. 4

5. Recent Upgrades to Grand Bay NERR Site: Feb. 27-March 1, 2007 5 Added: Meteorological measurements Meteorological measurements (T, RH, WS, WD, Solar, (T, RH, WS, WD, Solar, Precip Rate/Amount) Precip Rate/Amount) Upgraded CO Detector Upgraded CO Detector Run side-by-side with Run side-by-side with original instrument for original instrument for QA, continuity of QA, continuity of measurements measurements New data acquisition New data acquisition software for CO, O 3, Met software for CO, O 3, Met 5

6. MeasurementType Start Date Elemental mercury A Sept 2006 Fine particulate mercury A Sept 2006 Reactive gaseous mercury A Sept 2006 Sulfur dioxide A Oct 2006 OzoneA Carbon Monoxide A Oct 2006 Nitrogen Oxides (NO, NOy) A* Wind speed C Feb 2007 Wind Direction C Feb 2007 Relative Humidity C Feb 2007 TemperatureC PrecipitationC Total mercury in precipitation B* Major ions in precipitation B* Type of Measurement: A = concentration in ambient air B = concentration in precipitation C = meteorological parameter April 2007: Status of Atmospheric Measurements at Grand Bay NERR, Mississippi at Grand Bay NERR, Mississippi * to be established 6 6

7. Planned Activities at Grand Bay NERR Site: April 30-May 3, 2007 7 Remove old CO detector Remove old CO detector (has been running side by (has been running side by side with new instrument side with new instrument for the last month) for the last month) Add freshly calibrated O 3 Add freshly calibrated O 3 detector to run side by side detector to run side by side with current O 3 detector for with current O 3 detector for about a month –QA about a month –QA Tekran maintenance, filter Tekran maintenance, filter and glassware changes as and glassware changes as needed needed Replace a/c unit in trailer Replace a/c unit in trailer Meet with contractors –fence, Meet with contractors –fence, power, etc. power, etc. 7

8. 8 Update on Planned Future Activities Initial cost estimate to extend roofline of Pavilion and add Initial cost estimate to extend roofline of Pavilion and add a secured private enclosure was almost $30K a secured private enclosure was almost $30K The new plan is to simply construct The new plan is to simply construct a wooden privacy fence near the a wooden privacy fence near the Pavilion, to hide and protect the Pavilion, to hide and protect the trailer and monitoring equipment trailer and monitoring equipment and to restrict access to a planned and to restrict access to a planned walk-up sampling scaffold (10m) walk-up sampling scaffold (10m) Procurement request Procurement request for trailer will be for trailer will be submitted in the submitted in the coming days. coming days. 8

9. 9 Update on Planned Future Activities Continued Continued Other activities planned for FY2007: Addition of MDN collector, NO/NO Y analyzer Addition of MDN collector, NO/NO Y analyzer Purchase and installation of new, upgraded trailer Purchase and installation of new, upgraded trailer Possible upgrade of SO 2 detector (subject to availability Possible upgrade of SO 2 detector (subject to availability of funds) of funds) Installation of second Tekran system to allow for Installation of second Tekran system to allow for evaluation of QA/QC protocols, and to provide a evaluation of QA/QC protocols, and to provide a continuous data stream. continuous data stream. Pavilion site upgrades as discussed above, including power Pavilion site upgrades as discussed above, including power and internet access and internet access 9

10. NOAA SEARCH USGS UWF/FSU MDN Monitoring Site coal-fired power plant waste incinerator manufacturing metallurgical other fuel combustion type of mercury emissions source total atmospheric mercury emissions (kg/yr, 1999 EPA NEI) 50 - 100 100 - 200 200 - 400 1 – 50 Barry Holcim Cement NOAA Grand Bay NERR Hg site Weeks Bay OLF Molino Pace Ellyson Jack Watson AL24 AL02 Crist Pascagoula MSW incin haz waste incin paper manuf Victor J. Daniel Location of the new NOAA Grand Bay NERR Atmospheric Mercury monitoring site, other atmospheric Hg monitoring sites, and major Hg point sources in the region (according to the EPA 1999 NEI emissions inventory) Mobile Bay Mobile Pascagoula MississippiAlabama 10

11. NOAA SEARCH USGS UWF/FSU MDN Monitoring Site coal-fired power plant waste incinerator manufacturing metallurgical other fuel combustion type of mercury emissions source Holcim Cement NOAA Grand Bay NERR Hg site AL24 AL02 Pascagoula MSW incin haz waste incin paper manuf Victor J. Daniel Location of the new NOAA Grand Bay NERR Atmospheric Mercury monitoring site, other atmospheric Hg monitoring sites, and major Hg point sources in the region (according to the EPA 1999 NEI emissions inventory) Weeks Bay Barry Jack Watson total atmospheric mercury emissions (kg/yr, 1999 EPA NEI) 50 - 100 100 - 200 200 - 400 1 – 50 Mobile Bay Mobile, AL Pascagoula, MS Mississippi Alabama 11

12. 10 km Pascagoula MSW Incinerator Pascagoula, MS 12

13. 1 km 30.4294, -88.4277 30.412, -88.404 13

14. Oct 2006 pictures of initial monitoring site 14

15. U.S. Fish and Wildlife Service Pavilion at Grand Bay NERR View looking south and west from the U.S. Fish and Wildlife Service Pavilion at Grand Bay NERR 15 Pictures of planned (eventual) monitoring site View looking east from the U.S. Fish and Wildlife Service Pavilion at Grand Bay NERR

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19. For additional information on these atmospheric measurements, please contact: winston.luke@noaa.gov steve.brooks@noaa.gov mark.cohen@noaa.gov 19