Organic Light-Emitting Diode

Organic Light-Emitting Diode

Computer monitor Organic light-emitting diode
Organic light-emitting diode (OLED) monitors provide higher contrast and better viewing angles than LCDs but they require more power when displaying documents with white or bright backgrounds. In 2011, a 25 in (64 cm) OLED monitor cost $7500, but the prices are expected to drop.

Flexible organic light-emitting diode - Technical Details and Applications
An OLED emits light due to the electroluminescence of thin films of organic semiconductors approximately 100 nm thick. Regular OLEDs are usually fabricated on a glass substrate, but by replacing glass with a flexible plastic such as polyethylene terephthalate (PET) among others, OLEDs can be made both bendable and lightweight.

Such materials may not be suitable for comparable devices based on inorganic semiconductors due to the need for lattice matching and the high temperature fabrication procedure involved.

In contrast, flexible OLED devices can be fabricated by deposition of the organic layer onto the substrate using a method derived from inkjet printing, allowing the inexpensive and roll-to-roll fabrication of printed electronics.

Flexible OLEDs may be used in the production of rollable displays, electronic paper, or bendable displays which can be integrated into clothing, wallpaper or other curved surfaces. Prototype displays have been exhibited by companies such as Sony, which are capable of being rolled around the width of a pencil.

Flexible organic light-emitting diode - Disadvantages
Both flexible substrate itself as well as the process of bending the device introduce stress into the materials. There may be residual stress from the deposition of layers onto a flexible substrate, thermal stresses due to the different coefficient of thermal expansion of materials in the device, in addition to the external stress from the bending of the device.

Stress introduced into the organic layers may lower the efficiency or brightness of the device as it is deformed, or cause complete breakdown of the device altogether

Encapsulation is another challenge for flexible OLED devices

Light-emitting diode - Organic light-emitting diodes (OLEDs)
In an organic light-emitting diode (OLED), the electroluminescent material comprising the emissive layer of the diode is an organic compound. The organic material is electrically conductive due to the delocalization of pi electrons caused by conjugation over all or part of the molecule, and the material therefore functions as an organic semiconductor. The organic materials can be small organic molecules in a crystalline phase, or polymers.

Light-emitting diode - Organic light-emitting diodes (OLEDs)
The potential advantages of OLEDs include thin, low-cost displays with a low driving voltage, wide viewing angle, and high contrast and color gamut. Polymer LEDs have the added benefit of printable and flexible displays. OLEDs have been used to make visual displays for portable electronic devices such as cellphones, digital cameras, and MP3 players while possible future uses include lighting and televisions.

Organic light-emitting diode
An 'OLED' ('organic light-emitting diode') is a light-emitting diode (LED) in which the emission (electromagnetic radiation)|emissive electroluminescence|electroluminescent layer is a film of organic compound which emits light in response to an electric current

There are two main families of OLED: those based on small molecules and those employing polymers

An OLED display works without a backlight. Thus, it can display deep black levels and can be thinner and lighter than a liquid crystal display (LCD). In low ambient light conditions such as a dark room an OLED screen can achieve a higher contrast ratio than an LCD, whether the LCD uses cold cathode|cold cathode fluorescent lamps or LED-backlit LCD television|LED backlight.

Organic light-emitting diode - History
The first observations of electroluminescence in organic materials were in the early 1950s by André Bernanose and co-workers at the Nancy-Université, France

In 1960, Martin Pope and co-workers at New York University developed ohmic dark-injecting electrode contacts to organic crystals

Pope's group reported in 1965 that in the absence of an external electric field, the electroluminescence in anthracene crystals is caused by the recombination of a thermalized electron and hole, and that the conducting level of anthracene is higher in energy than the exciton energy level

Electroluminescence from polymer films was first observed by Roger Partridge at the National Physical Laboratory (United Kingdom)|National Physical Laboratory in the United Kingdom. The device consisted of a film of poly(N-Vinylcarbazole|n-vinylcarbazole) up to 2.2 micrometres thick located between two charge injecting electrodes. The results of the project were patented in 1975Partridge, Roger Hugh, Radiation sources , Issue date: November 30, 1976 and published in 1983.

The first diode device was reported at Eastman Kodak by Ching W. Tang and Steven Van Slyke in This device used a novel two-layer structure with separate hole transporting and electron transporting layers such that recombination and light emission occurred in the middle of the organic layer. This resulted in a reduction in operating voltage and improvements in efficiency and led to the current era of OLED research and device production.

Research into polymer electroluminescence culminated in 1990 with J. H. Burroughes et al. at the Cavendish Laboratory in Cambridge reporting a high efficiency green light-emitting polymer based device using 100nm thick films of poly(p-phenylene vinylene).

Organic light-emitting diode - Working principle
A typical OLED is composed of a layer of organic materials situated between two electrodes, the anode and cathode, all deposited on a substrate (materials science)|substrate

Originally, the most basic polymer OLEDs consisted of a single organic layer

During operation, a voltage is applied across the OLED such that the anode is positive with respect to the cathode

Phosphorescent organic light-emitting diodes make use of spin–orbit interactions to facilitate intersystem crossing between singlet and triplet states, thus obtaining emission from both singlet and triplet states and improving the internal efficiency.

Indium tin oxide (ITO) is commonly used as the anode material

Experimental research has proven that the properties of the anode, specifically the anode/hole transport layer (HTL) interface topography plays a major role in the efficiency, performance, and lifetime of organic light emitting diodes

Single carrier devices are typically used to study the chemical kinetics|kinetics and charge transport mechanisms of an organic material and can be useful when trying to study energy transfer processes

Organic light-emitting diode - Small molecules
Efficient OLEDs using small molecules were first developed by Dr. Ching W. Tang et al. at Eastman Kodak. The term OLED traditionally refers specifically to this type of device, though the term SM-OLED is also in use.

Molecules commonly used in OLEDs include organometallic chelation|chelates (for example Tris(8-hydroxyquinolinato)aluminium|Alq3, used in the organic light-emitting device reported by Tang et al.), fluorescent and phosphorescent dyes and conjugated dendrimers

The production of small molecule devices and displays usually involves Evaporation (deposition)|thermal evaporation in a vacuum

Coherent emission from a laser dye-doped tandem SM-OLED device, excited in the pulsed regime, has been demonstrated. The emission is nearly diffraction limited with a spectral width similar to that of broadband dye lasers.

Organic light-emitting diode - Polymer light-emitting diodes
Polymer light-emitting diodes (PLED), also light-emitting polymers (LEP), involve an electroluminescence|electroluminescent conductive polymer that emits light when connected to an external voltage. They are used as a thin film for full-spectrum colour displays. Polymer OLEDs are quite efficient and require a relatively small amount of power for the amount of light produced.

Vacuum deposition is not a suitable method for forming thin films of polymers

Typical polymers used in PLED displays include derivatives of poly(p-phenylene vinylene)|poly(p-phenylene vinylene) and polyfluorene

While unsubstituted poly(p-phenylene vinylene) (PPV) is typically insoluble, a number of PPVs and related poly(naphthalene vinylene)s (PNVs) that are soluble in organic solvents or water have been prepared via ring opening metathesis polymerization.

Organic light-emitting diode - Phosphorescent materials
Phosphorescent organic light emitting diodes use the principle of electrophosphorescence to convert electrical energy in an OLED into light in a highly efficient manner, with the internal quantum efficiencies of such devices approaching 100%.

Typically, a polymer such as poly(N-Vinylcarbazole|n-vinylcarbazole) is used as a host material to which an organometallic Coordination complex|complex is added as a dopant. Organoiridium compound|Iridium complexes such as Ir(mppy)3 are currently the focus of research, although complexes based on other heavy metals such as platinum have also been used.

The heavy metal atom at the centre of these complexes exhibits strong spin-orbit coupling, facilitating intersystem crossing between Singlet state|singlet and Triplet state|triplet states. By using these phosphorescent materials, both singlet and triplet excitons will be able to decay radiatively, hence improving the internal quantum efficiency of the device compared to a standard PLED where only the singlet states will contribute to emission of light.

Applications of OLEDs in solid state lighting require the achievement of high brightness with good CIE 1931 color space|CIE coordinates (for white emission). The use of macromolecular species like polyhedral oligomeric silsesquioxanes (POSS) in conjunction with the use of phosphorescent species such as Ir for printed OLEDs have exhibited brightnesses as high as 10,000cd/m2.

Organic light-emitting diode - Structure
; Bottom or top emission: Bottom or top distinction refers not to orientation of the OLED display, but to the direction that emitted light exits the device

; Transparent OLEDs: Transparent OLEDs use transparent or semi-transparent contacts on both sides of the device to create displays that can be made to be both top and bottom emitting (transparent). TOLEDs can greatly improve contrast, making it much easier to view displays in bright sunlight. This technology can be used in Head-up displays, smart windows or Augmented Reality applications.

; Graded Heterojunction: Graded heterojunction OLEDs gradually decrease the ratio of electron holes to electron transporting chemicals. This results in almost double the quantum efficiency of existing OLEDs.

; Stacked OLEDs: Stacked OLEDs use a pixel architecture that stacks the red, green, and blue subpixels on top of one another instead of next to one another, leading to substantial increase in gamut and color depth, and greatly reducing pixel gap. Currently, other display technologies have the RGB (and RGBW) pixels mapped next to each other decreasing potential resolution.

; Inverted OLED: In contrast to a conventional OLED, in which the anode is placed on the substrate, an Inverted OLED uses a bottom cathode that can be connected to the drain end of an n-channel TFT especially for the low cost amorphous silicon TFT backplane useful in the manufacturing of AMOLED displays.

Organic light-emitting diode - Patterning technologies
Patternable organic light-emitting devices use a light or heat activated electroactive layer. A latent material (PEDOT-TMA) is included in this layer that, upon activation, becomes highly efficient as a hole injection layer. Using this process, light-emitting devices with arbitrary patterns can be prepared.

Colour patterning can be accomplished by means of laser, such as radiation-induced sublimation transfer (RIST).

Organic vapour jet printing (OVJP) uses an inert carrier gas, such as argon or nitrogen, to transport evaporated organic molecules (as in Organic Vapor Phase Deposition). The gas is expelled through a micron sized nozzle or nozzle array close to the substrate as it is being translated. This allows printing arbitrary multilayer patterns without the use of solvents.

Like ink jet material depositioning, inkjet etching (IJE) deposits precise amounts of solvent onto a substrate designed to selectively dissolve the substrate material and induce a structure or pattern

Organic light-emitting diode - Backplane technologies
For a high resolution display like a TV, a Thin-film transistor|TFT backplane is necessary to drive the pixels correctly. Currently, low temperature polycrystalline silicon (LTPS) - thin-film transistor (TFT) is used for commercial AMOLED displays. LTPS-TFT has variation of the performance in a display, so various compensation circuits have been reported.

Organic light-emitting diode - Backplane technologies
Due to the size limitation of the excimer laser used for LTPS, the AMOLED size was limited. To cope with the hurdle related to the panel size, amorphous-silicon/microcrystalline-silicon backplanes have been reported with large display prototype demonstrations.

Organic light-emitting diode - Fabrication
Transfer-printing is an emerging technology with the capability to assemble large numbers of parallel OLED and AMOLED devices under efficient conditions

Organic light-emitting diode - Advantages
The different manufacturing process of OLEDs lends itself to several advantages over flat panel displays made with LCD technology.

; Lower cost in the future: OLEDs can be printed onto any suitable substrate (printing)|substrate by an inkjet printer or even by screen printing, theoretically making them cheaper to produce than LCD or plasma displays

; Lightweight and flexible plastic substrates: OLED displays can be fabricated on flexible plastic substrates leading to the possible fabrication of flexible organic light-emitting diodes for other new applications, such as rollable display|roll-up displays embedded in fabrics or clothing. As the substrate used can be flexible substrate|flexible such as polyethylene terephthalate (PET), the displays may be produced inexpensively.

; Wider viewing angles and improved brightness: OLEDs can enable a greater artificial contrast ratio (both dynamic range and static, measured in purely dark conditions) and a wider viewing angle compared to LCDs because OLED pixels emit light directly. OLED pixel colors appear correct and unshifted, even as the viewing angle approaches 90° from Surface normal|normal.

; Better power efficiency and thickness: LCDs filter the light emitted from a backlight, allowing a small fraction of light through

; Response time: OLEDs also can have a faster response time than standard LCD screens. Whereas LCD displays are capable of between Liquid crystal display#Specifications|1 and 16 ms response time offering a refresh rate of 60 to 480Hz, an OLED theoretically can have a response time less than 0.01 ms, enabling a refresh rate up to 100,000Hz .. OLEDs also can be run as a flicker display, similar to a CRT, in order to eliminate the sample-and-hold effect that creates motion blur on OLEDs.

Organic light-emitting diode - Disadvantages
; Current costs: OLED manufacture currently requires process steps that make it extremely expensive. Specifically, it requires the use of low-temperature polysilicon backplanes; LTPS backplanes, in turn, require laser annealing from an amorphous silicon start, so this part of the manufacturing process for AMOLEDs starts with the process costs of standard LCD, and then adds an expensive, time-consuming process that cannot currently be used on large-area glass substrates.

; Lifespan: The biggest technical problem for OLEDs was the limited lifetime of the organic materials

; Color balance issues: Additionally, as the OLED material used to produce blue light degrades significantly more rapidly than the materials that produce other colors, blue light output will decrease relative to the other colors of light

; Efficiency of blue OLEDs: Improvements to the efficiency and lifetime of blue OLEDs is vital to the success of OLEDs as replacements for LCD technology

; Water damage: Water can damage the organic materials of the displays. Therefore, improved sealing processes are important for practical manufacturing. Water damage especially may limit the longevity of more flexible displays.

; Outdoor performance: As an emissive display technology, OLEDs rely completely upon converting electricity to light, unlike most LCDs which are to some extent reflective

; Power consumption: While an OLED will consume around 40% of the power of an LCD displaying an image that is primarily black, for the majority of images it will consume 60%–80% of the power of an LCD

Organic light-emitting diode - Manufacturers and commercial uses
OLED technology is used in commercial applications such as displays for mobile phones and portable digital media players, car radios and digital cameras among others

OLEDs have been used in most Motorola and Samsung color cell phones, as well as some HTC Corporation|HTC, LG and Sony Ericsson models.Electronic News, [ OLEDs Replacing LCDs in Mobile Phones], April 7, 2005, retrieved on July 28, 2007

The Google and HTC Nexus One smartphone includes an AMOLED screen, as does HTC's own HTC Desire|Desire and HTC Legend|Legend phones. However due to supply shortages of the Samsung-produced displays, certain HTC models will use Sony's S-LCD|SLCD displays in the future, while the Google and Samsung Nexus S smartphone will use Super Clear LCD instead in some countries.

OLED displays were used in watches made by Fossil (JR-9465) and Diesel (DZ-7086).

Other manufacturers of OLED panels include Anwell Technologies Limited (Hong Kong), AU Optronics (Taiwan), Chimei Innolux Corporation (Taiwan), LG (Korea), and others.

In 2009, Shearwater Research introduced the Predator as the first color OLED diving computer available with a user replaceable battery.

DuPont stated in a press release in May 2010 that they can produce a 50-inch OLED TV in two minutes with a new printing technology. If this can be scaled up in terms of manufacturing, then the total cost of OLED TVs would be greatly reduced. Dupont also states that OLED TVs made with this less expensive technology can last up to 15 years if left on for a normal eight hour day.

The use of OLEDs may be subject to patents held by Eastman Kodak, DuPont, General Electric, Philips|Royal Philips Electronics, numerous universities and others.OLED-Info.com, [ Kodak Signs OLED Cross-License Agreement], retrieved on March 14, There are by now thousands of patents associated with OLEDs, both from larger corporations and smaller technology companies.

Research In Motion|RIM, the maker of BlackBerry smartphones, have unofficially announced that their upcoming BlackBerry 10 devices will use OLED displays. This marks the upcoming BB10 smartphones as some of the first to use OLED displays.

Foldable OLED smartphones could be as much as a decade away because of the cost of producing them

Organic light-emitting diode - Fashion
Textiles incorporating OLEDs are an innovation in the fashion world and pose for a way to integrate lighting to bring inert objects to a whole new level of fashion

Organic light-emitting diode - Samsung applications
By 2004 Samsung, South Korea's largest conglomerate (company)|conglomerate, was the world's largest OLED manufacturer, producing 40% of the OLED displays made in the world, and as of 2010 has a 98% share of the global AMOLED market

Samsung SDI announced in 2005 the world's largest OLED TV at the time, at . This OLED featured the highest resolution at the time, of 6.22 million pixels. In addition, the company adopted active matrix based technology for its low power consumption and high-resolution qualities. This was exceeded in January 2008, when Samsung showcased the world's largest and thinnest OLED TV at the time, at 31inches (78cm) and 4.3mm.

In May 2008, Samsung unveiled an ultra-thin 12.1inch (30cm) laptop OLED display concept, with a 1,280×768 resolution with infinite contrast ratio. According to Woo Jong Lee, Vice President of the Mobile Display Marketing Team at Samsung SDI, the company expected OLED displays to be used in notebook PCs as soon as 2010.

In October 2008, Samsung showcased the world's thinnest OLED display, also the first to be flappable and bendable

In the same month, Samsung unveiled what was then the world's largest OLED Television at 40-inch with a Full HD resolution of 1920×1080 pixel.40-inch OLED panel from Samsung. Hdtvinfo.eu ( ) In the FPD International, Samsung stated that its 40-inch OLED Panel is the largest size currently possible. The panel has a contrast ratio of 1,000,000:1, a colour gamut of 107% NTSC, and a luminance of 200cd/m² (peak luminance of 600cd/m²).

At the Consumer Electronics Show|Consumer Electronics Show (CES) in January 2010, Samsung demonstrated a laptop computer with a large, transparent OLED display featuring up to 40% transparency and an animated OLED display in a photo ID card.

Samsung's latest AMOLED smartphones use their Super AMOLED trademark, with the Samsung Wave S8500 and Samsung i9000 Galaxy S being launched in June In January 2011 Samsung announced their Super AMOLED Plus displays, which offer several advances over the older Super AMOLED displays: real stripe matrix (50% more sub pixels), thinner form factor, brighter image and an 18% reduction in energy consumption.

At CES 2012, Samsung introduced the first 55 TV screen that uses Super OLED technology.Clark, Shaylin ( ). [ CES 2012: Samsung’s OLED TV Rakes In Awards]. WebProNews. Retrieved on

On January 8, 2013, at CES Samsung unveiled a unique curved 4K Ultra S9 OLED television, which they state provides an IMAX-like experience for viewers.Rougeau, Michael ( ). [ Techradar. Retrieved on

On August 13, 2013, Samsung announced availability of a 55-inch curved OLED TV (model KN55S9C) in the US at a price point of $ Boylan, Chris ( ). Big Picture Big Sound. Retrieved on

On September 6, 2013, Samsung launched its 55-inch curved OLED TV (model KE55S9C) in the United Kingdom with John Lewis.

Samsung introduced the Galaxy Round smartphone in the Korean market in October The device features a 1080p screen, measuring , that curves on the vertical axis in a rounded case. The corporation has promoted the following advantages: A new feature called Round Interaction that allows users to look at information by tilting the handset on a flat surface with the screen off, and the feel of one continuous transition when the user switches between home screens.

Organic light-emitting diode - Sony applications
The Sony CLIÉ PEG-VZ90 was released in 2004, being the first PDA to feature an OLED screen. Other Sony products to feature OLED screens include the MZ-RH1 portable minidisc recorder, released in 2006 and the Walkman X Series.

At the 2007 Las Vegas Valley|Las Vegas Consumer Electronics Show (CES), Sony showcased 11-inch (28cm, resolution 960×540) and 27-inch (68.5cm), full HD resolution at 1920×1080) OLED TV models.Sony announces a 27-inch OLED TV

In May 2007, Sony publicly unveiled a video of a 2.5-inch flexible OLED screen which is only 0.3 millimeters thick

In July 2008, a Japanese government body said it would fund a joint project of leading firms, which is to develop a key technology to produce large, energy-saving organic displays

In October 2008, Sony published results of research it carried out with the Max Planck Institute over the possibility of mass-market bending displays, which could replace rigid LCDs and plasma screens. Eventually, bendable, see-through displays could be stacked to produce 3D images with much greater contrast ratios and viewing angles than existing products.

Sony exhibited a 24.5 (62cm) prototype OLED 3D television during the Consumer Electronics Show in January 2010.

In January 2011, Sony announced the PlayStation Vita handheld game console (the successor to the PlayStation Portable|PSP) will feature a 5-inch OLED screen.

On February 17, 2011, Sony announced its 25 (63.5cm) OLED Professional Reference Monitor aimed at the Cinema and high end Drama Post Production market.

On June 25, 2012, Sony and Panasonic announced a joint venture for creating low cost mass production OLED televisions by 2013.

Organic light-emitting diode - LG applications
As of 2010, LG Electronics produced one model of OLED television, the 15inch 15EL9500[ LG 15EL9500 OLED Television]

Organic light-emitting diode - Mitsubishi applications
Lumiotec is the first company in the world developing and selling, since January 2011, mass-produced OLED lighting panels with such brightness and long lifetime. Lumiotec is a joint venture of Mitsubishi Heavy Industries, ROHM, Toppan Printing, and Mitsui Co.

Organic light-emitting diode - Mitsubishi applications
On June 1, 2011, Mitsubishi installed a 6-meter OLED 'sphere' in Tokyo's Science Museum [ MITSUBISHI ELECTRIC News Releases Installs 6-Meter OLED Globe at Science Museum]. Mitsubishielectric.com ( ). Retrieved on

Organic light-emitting diode - Recom Group/video name tag applications
On January 6, 2011, Los Angeles based technology company Recom Group introduced the first small screen consumer application of the OLED at the Consumer Electronics Show in Las Vegas

LED - Organic light-emitting diodes (OLEDs)
In an organic light-emitting diode (organic light-emitting diode|OLED), the electroluminescence|electroluminescent material comprising the emissive layer of the diode is an organic compound. The organic material is electrically conductive due to the Delocalized electron|delocalization of pi electrons caused by conjugated system|conjugation over all or part of the molecule, and the material therefore functions as an organic semiconductor.

LED - Organic light-emitting diodes (OLEDs)
The potential advantages of OLEDs include thin, low-cost displays with a low driving voltage, wide viewing angle, and high contrast and color gamut. Polymer LEDs have the added benefit of printable and flexible organic light-emitting diode|flexible displays. OLEDs have been used to make visual displays for portable electronic devices such as cellphones, digital cameras, and MP3 players while possible future uses include lighting and televisions.

Organic light-emitting diode roll-up display
A 'flexible organic light emitting diode (FOLED)' is a type of organic light-emitting diode (OLED) incorporating a flexible plastic Substrate (semiconductor)|substrate on which the electroluminescence|electroluminescent organic semiconductor is deposited. This enables the device to be bent or rolled while still operating. Currently the focus of research in industrial and academic groups, flexible OLEDs form one method of fabricating a rollable display.

Organic light-emitting diode roll-up display - Technical details and applications
An OLED emits light due to the electroluminescence of thin films of organic semiconductors approximately 100nm thick. Regular OLEDs are usually fabricated on a glass Substrate (semiconductor)|substrate, but by replacing glass with a flexible plastic such as polyethylene terephthalate (PET) among others, OLEDs can be made both bendable and lightweight.

Organic light-emitting diode roll-up display - Technical details and applications
Such materials may not be suitable for comparable devices based on inorganic semiconductors due to the need for lattice matching and the high temperature fabrication procedure involved.

Organic light-emitting diode roll-up display - Disadvantages
Both flexible substrate itself as well as the process of bending the device introduce Stress (mechanics)|stress into the materials. There may be residual stress from the deposition of layers onto a flexible substrate, thermal stresses due to the different coefficient of thermal expansion of materials in the device, in addition to the external stress from the bending of the device.

Organic light-emitting diode roll-up display - Disadvantages
Encapsulation is another challenge for flexible OLED devices

Display examples - Organic light-emitting diode
[ rpi.edu – Lighting industry, Structure and technology in the transition to solid state]

Display examples - Organic light-emitting diode
2003 Active-matrix OLED (AMOLED):[ WP-de Organische Leuchtdiode]

Phosphorescent organic light-emitting diode
'Phosphorescent organic light-emitting diodes' ('PHOLED') are a type of OLED|organic light-emitting diode (OLED) that use the principle of phosphorescence to obtain higher internal efficiencies than fluorescent OLEDs. This technology is currently under development by many industrial and academic research groups.

Phosphorescent organic light-emitting diode - Method of operation
Like all types of OLED, phosphorescent OLEDs emit light due to the electroluminescence of an organic semiconductor layer in an electric current. Electrons and electron hole|holes are injected into the organic layer at the electrodes and form excitons, a bound state of the electron and hole.

Electrons and holes are both fermions with half integer spin (physics)|spin. An exciton formed by the recombination of two such particles may either be in a singlet state or a triplet state, depending on how the spins have been combined. Statistically, there is a 25% probability of forming a singlet state and 75% probability of forming a triplet state. Decay of the excitons results in the production of light through spontaneous emission.

In OLEDs using fluorescent organic molecules only, the decay of triplet excitons is quantum mechanically forbidden by selection rules, meaning that the lifetime of triplet excitons is long and phosphorescence is not readily observed

However, phosphorescent OLEDs generate light from both triplet and singlet excitons, allowing the internal quantum efficiency of such devices to reach nearly 100%.

This is commonly achieved by doping a host molecule with an organometallic Coordination complex|complex

Phosphorescent organic light-emitting diode - Applications
Due to their potentially high level of energy efficiency, even when compared to other OLEDs, PHOLEDs are being studied for potential use in large-screen displays such as computer monitors or television screens, as well as general lighting needs

Phosphorescent organic light-emitting diode - Challenges
One problem that currently hampers the widespread adoption of this highly energy efficient technology is that the average lifetimes of red and green PHOLEDs are often tens of thousands of hours longer than those of blue PHOLEDs. This may cause displays to become visually distorted much sooner than would be acceptable for a commercially viable device.

Polyfluorene - Organic light-emitting diodes (OLEDs)
In recent years many industrial efforts have focused on tuning the color of lights using polyfluorenes

Polyfluorene - Organic light-emitting diodes (OLEDs)
Substitution at the nine position with various moieties has also been examined as a means to control the color emitted by polyfluorene. In the past researchers have tried putting alkyl substituents on the ninth position, however it has been found that by putting bulkier groups, such as alkoxyphenyl groups, the polymers had enhanced blue emission stability and superior polymer light-emitting diode performance (compared to polymers which have alkyl substituents at the ninth position).

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