1. FOSSIL FUELS I PETROLEUM

2. Should the Keystone XL pipeline be built? 1. Yes 2. No

3. Should ANWR be opened up to oil drilling 1. Yes 2. No

4. Approximately 84% of the energy used in the US comes from fossil fuels Approximately 84% of the energy used in the US comes from fossil fuels  Oil and Natural Gas (Petroleum)  Coal  Oil Shale and Tar Sand  Nonrenewable Resource (Fuel)

5. Formation Process Formation takes 10’s to 100’s of million years. Formation takes 10’s to 100’s of million years. 1. Dead plants and Animals accumulate on ancient sea floor. 2. Sandstone layer forms over source bed. 3. High Pressure and Temperature results in a loss of Oxygen in the compounds

6. 4. Results in various hydrocarbons (organic compounds with mostly Hydrogen and Carbon in them…more later). These can be solid liquid or gas. 5. Liquid and gas migrate through porous rock layer (sand stone) until they get caught in a trap or escape.

7. Types of Oil Traps Fold Salt Dome Fold Salt Dome

8. Faults

9. 1 st Oil Well Titusville PA

10. La Brea Tar Pits

11. Typical Deposit A few miles across A few miles across Approximately 1 mile down (sometimes more. Approximately 1 mile down (sometimes more. VERY HARD TO FIND

12. Tools for Searching for Deposits Gravitational/Magnetic Anomalies Gravitational/Magnetic Anomalies Easy to do over a wide area, but is a very coarse measurement. Good to pick out regions for further study Geological Survey Geological Survey Look at the rocks and minerals in the region. Certain types are indicative of hydrocarbon deposits.

13. Seismic Survey Gives a detailed picture of the subsurface Gives a detailed picture of the subsurface Very expensive Very expensive Used over limited but promising areas. Used over limited but promising areas.

14. Example Seismic Image

15. Eventually you must drill a wildcat well. (1 st well in a region.) Eventually you must drill a wildcat well. (1 st well in a region.) Even with all of the research, only 1 out of 9 wildcat wells results in a commercially viable well. Even with all of the research, only 1 out of 9 wildcat wells results in a commercially viable well. Historically, it takes about 11 years for a new discovery to begin producing. Historically, it takes about 11 years for a new discovery to begin producing. https://www.youtube.com/watch?v=uNATp0aCkQg https://www.youtube.com/watch?v=uNATp0aCkQg https://www.youtube.com/watch?v=uNATp0aCkQg

16. A Which of the following is not a typical oil trap? 1. Fault 2. Fold 3. Fracture 4. Salt Dome

17. US Oil & Gas Locations

18. Production Primary Recovery gets 15% of oil Primary Recovery gets 15% of oil Secondary Recovery (pumping water down the well) gets another 20%. Secondary Recovery (pumping water down the well) gets another 20%. 65% is still down there. 65% is still down there.

19. Enhanced Production Much more expensive Much more expensive Works by reducing surface tension and viscosity of the oil Works by reducing surface tension and viscosity of the oil

20. Enhanced Production Methods Pump in pressurized Carbon Dioxide to reduce viscosity Pump in pressurized Carbon Dioxide to reduce viscosity Pump in steam to reduce viscosity Pump in steam to reduce viscosity Add detergent to reduce surface tension with surrounding rock (then flood with water. Add detergent to reduce surface tension with surrounding rock (then flood with water.

21. Petroleum Production Methods Primary 15% recovered 85% remaining Primary 15% recovered 85% remaining Secondary add’l 20% recovered 65% remaining Secondary add’l 20% recovered 65% remaining Enhanced add’l 10% recovered 55% remaining Enhanced add’l 10% recovered 55% remaining

22. Oil shale is sedimentary rock such as shale or marl, containing kerogen Oil shale is sedimentary rock such as shale or marl, containing kerogen Kerogen is a waxy oil precursor not yet transformed into petroleum Kerogen is a waxy oil precursor not yet transformed into petroleum The rock is mined, and synthetic oil is produced The rock is mined, and synthetic oil is produced Energy yield much lower than conventional oil Energy yield much lower than conventional oil

23. US Oil Shale Locations

24. Oil sands are unconsolidated sandstone deposits, containing bitumen or heavy crude oil Oil sands are unconsolidated sandstone deposits, containing bitumen or heavy crude oil Bitumen is a viscous or semi-solid form of petroleum Bitumen is a viscous or semi-solid form of petroleum The sand is mined or recovered by steam injection The sand is mined or recovered by steam injection Refined by cracking or blending, then processed in conventional refinery Refined by cracking or blending, then processed in conventional refinery

25. Oil Sand Locations

26. Oil sand recovery process is more efficient than that of oil shale Oil sand recovery process is more efficient than that of oil shale

27. How much oil is left in the ground after recovery? 1. 10% 2. 15% 3. 20% 4. 55%

28. What is in Oil Hydrocarbons, These are the Alkanes C n H 2n+2 The proportion of hydrocarbons in the petroleum mixture is highly variable between different oil fields and ranges from as much as 97% by weight in the lighter oils to as little as 50% in the heavier oils and bitumens.oil fieldsbitumens

29. Crude oil ~ 85% carbon Crude oil ~ 85% carbon Oil has about 45 MJ/kg of energy Oil has about 45 MJ/kg of energy

30. Generally we must treat oil from the ground Fractional: Distillation: The vapors of different hydrocarbons condense at different temperatures. Fractional: Distillation: The vapors of different hydrocarbons condense at different temperatures.

31. Oil Refinery Refining Video Refining Video Refining Video

32. Problem: Generally have too many heavy compounds and not enough light ones. Problem: Generally have too many heavy compounds and not enough light ones. Solution: Break apart long hydrocarbons into shorter pieces. Solution: Break apart long hydrocarbons into shorter pieces. Two techniques: Two techniques: 1.Cracking: uses high pressure and temperature 2.Catalytic conversion: pass petroleum over an Al-Si mixture:

33. ProductPercent of Total Lubricants0.9 % Other Refined Products1.5 % Asphalt and Road Oil1.9 % Liquefied Refinery Gas2.8 % Residual Fuel Oil3.3 % Marketable Coke5.0 % Still Gas5.4 % Jet Fuel12.6 % Distillate Fuel Oil15.3 % Finished Motor Gasoline51.4 % One barrel contains 42 gallons of crude oil. The total volume of products made from crude oil based origins is 48.43 gallons on average - 6.43 gallons greater than the original 42 gallons of crude oil. This represents a "processing gain" due to the additional other petroleum products such as alkylates are added to the refining process to create the final products. Additionally, most gasoline contains approximately 10 percent by volume of ethanol, a non-petroleum-based additive that brings the total processing gain to 8.59 gallons (or 50.59 total gallons).

34. You can also form long hydrocarbon chains by combining light ones You can also form long hydrocarbon chains by combining light ones Important for forming material such as nylon, rayon and plastics. Important for forming material such as nylon, rayon and plastics.

35. Fun Fact… The refining of oil is a very energy intensive process. Approximately 7.5% of the total US energy consumption goes into running oil refineries.

36. Gasoline Octane Rating Normal gasoline is composed of hydrocarbons with 5-10 Carbon atoms Normal gasoline is composed of hydrocarbons with 5-10 Carbon atoms Each one burns differently Each one burns differently Octane: C 8 H 18 is a standard for comparison, it burns very smoothly. Octane: C 8 H 18 is a standard for comparison, it burns very smoothly. Heptane: C 7 H 16 burns explosively, causes inefficiency and engine “knock” Heptane: C 7 H 16 burns explosively, causes inefficiency and engine “knock”

37. Octane rating Octane rating Pure Octane: 100 Pure Octane: 100 Pure Heptane: 0 Pure Heptane: 0 90% Oct, 10% Hep 90 90% Oct, 10% Hep 90 We may use additives to produce a fuel with the same level of “engine knock” as a given Octane-Heptane mix. This is given the same octane rating (tetraethyl lead was the old additive… it is now illegal.)

38. For diesel, the Cetane number is used For diesel, the Cetane number is used Cetane is C 16 H 34 Cetane is C 16 H 34 Cetane has the opposite effect of octane Cetane has the opposite effect of octane

39. Burning of Gasoline Ideal Ideal 2C 8 H 18 + 25O 2  16 CO 2 + 18H 2 O + energy 2C 8 H 18 + 25O 2  16 CO 2 + 18H 2 O + energy Gas + Air  Carbon Dioxide + Water + energy Gas + Air  Carbon Dioxide + Water + energy More realistic More realistic 2C 8 H 18 + 25O 2  14 CO 2 + 2CO + O 2 + 18H 2 O + energy. 2C 8 H 18 + 25O 2  14 CO 2 + 2CO + O 2 + 18H 2 O + energy.

40. The CO 2 by burning fossil fuels is generally believed to be causing significant changers to the earth’s climate. The CO 2 by burning fossil fuels is generally believed to be causing significant changers to the earth’s climate. In addition, nitrogen in the air combines to produce nitrous oxides (big part of smog) NOx N 2 +2O 2  2NO 2 N 2 +O 2  2NO

41. Oil refining is an energy intensive process 1. True 2. False

42. Which of the following retards combustion? 1. Heptane 2. Octane 3. Cetane

43. WORLD & US OIL RESERVES 2003 WORLD 1644 billion barrels WORLD 1644 billion barrels US 36 billion barrels (2.2%) US 36 billion barrels (2.2%) Lifetime of US supply based on Rate equation: 10 yrs Lifetime of US supply based on Rate equation: 10 yrs

44. Proven Reserves (2013)

46. Oil Producers and Consumers

47. US Oil Produced and Found

48. Net Difference Between Annual World Oil Reserves Additions and Annual Consumption.

49. Hubbert Analysis 1956 Marion King Hubbert 1956 Marion King Hubbert Analysis for natural resources. Analysis for natural resources. Applied to fossil fuels. Applied to fossil fuels. Rate of production tends to follow a bell-shaped curve. Rate of production tends to follow a bell-shaped curve.

50. Hubbert Analysis Rate of production tends to follow a bell-shaped curve. Rate of production tends to follow a bell-shaped curve. –Early (pre-peak): rate increases due to discovery of reserves & building infrastructure. –Later (post-peak): rate decreases due to resource depletion.

51. Hubbert Analysis In 1956 Hubbert predicted US oil production would peak in late 60’ or early 70’s. In 1956 Hubbert predicted US oil production would peak in late 60’ or early 70’s. It peaked in 1970. It peaked in 1970.

52. Hubbert Analysis World

54. Hubbert analysis can be applied to which of the following 1. Only fossil fuels 2. Only non- renewable resources 3. Only renewable resources 4. Any natural resource

55. Table II-1. Projections of the Peaking of World Oil Production. Projected Date of World Peak Production Source of ProjectionBackground 2006-2007Bakhitari, A.M.S.Iranian Oil Executive 2007-2009Simmons, M.R.Investment Banker After 2007Skrebowski, C.Petroleum journal Editor Before 2009Deffeyes, K.S.Oil company geologist Before 2010Goodstein, D.Vice Provost, Cal Tech Around 2010Campbell, C.J.Oil company geologist After 2010World Energy Council World Non-Government Org. 2010-2020LaHerrere, J.Oil company geologist 2016EIA nominal case DOE analysis/information. After 2020CERAEnergy consultants 2025 or laterShellMajor oil company No visible peakLynch, M.C.Energy economist

56. What about ANWR

57. What about ANWR? The Alaska National Interest Lands Conservation Act (1980) established the Arctic National Wildlife Refuge (ANWR). In section 1002 of that act, Congress deferred a decision regarding future management of the 1.5-million-acre coastal plain in recognition of the area’s potentially enormous oil and gas resources and its importance as wildlife habitat. A report on the resources, including petroleum, of the 1002 area was submitted to Congress in 1987 by the Department of the Interior (DOI). Since completion of that report, numerous wells have been drilled and oil fields discovered near ANWR, new geologic and geophysical data have become available, seismic processing and interpretation capabilities have improved, and the economics of North Slope oil development have changed significantly.

58. What about ANWR? The government estimates up to 16 billion barrels of oil in ANWR are technically recoverable, although much of that would be too expensive to produce at today's prices. With prices were at or above $35 a barrel, energy companies could economically recover an estimated 6 billion barrels of oil from ANWR. Note: the US use about 7.5 billion barrels of oil per year.

59. Should ANWR be opened up to oil drilling 1. Yes 2. No