Presentation on theme: "Solid State Physics (1) Phys3710"— Presentation transcript:
1Solid State Physics (1) Phys3710 Lecture 1Department of PhysicsDr Mazen AlshaaerSecond semester 2013/2014Ref.: Prof. Charles W. Myles, Department of Physics, Texas Tech University
2Introduction to Solid State Physics, by Charles Kittel, 8th Edition. Primary TextbookIntroduction to Solid State Physics, by Charles Kittel, 8th Edition.1. Elementary Solid State Physics: Principles & Applications, M. Ali Omar2. Solid State Physics, by Neil W. Ashcroft & N. David Mermin.Course ObjectiveTo expose students to the rich, broad, varied field ofSOLID STATE PHYSICSSolid State Physics is about many different kinds of solids. We'll discuss the microscopic physics of mostly, CRYSTALLINE solids, including metals, insulators, & semiconductors.
4The (Common) Phases of Matter GASESLIQUIDS and LIQUID CRYSTALSSOLIDSThis doesn’t includePlasmas, but these are the “common” phases!!“Condensed Matter” includesboth of these. We’ll focus on Solids!
5GasesGases have atoms or molecules that do not bond to one another in a range of pressure, temperature & volume.These molecules haven’t any particular order & move freely within a container.
6Liquids & Liquid Crystals Similar to gases, Liquids have no atomic/molecular order & they assume the shape of their containers.Applying low levels of thermal energy can easily break the existing weak bonds.Liquid Crystals have mobile molecules, but a type of long range order can exist; the molecules have a permanent dipole. Applying an electric field rotates the dipole & establishes order within the collection of molecules.6
7SolidsSolids consist of atoms or molecules undergoing thermal motion about their equilibrium positions, which are at fixed points in space.Solids can be crystalline, polycrystalline, or amorphous.Solids (at a given temperature, pressure, volume) have stronger interatomic bonds than liquids.So, Solids require more energy to break the interatomic bonds than liquids.
8Crystal Structure Topics 1. Periodic Arrays of Atoms 2. Fundamental Types of Lattices3. Index System for Crystal Planes4. Simple Crystal Structures5. Direct Imaging of Crystal Structure6. Non-ideal Crystal Structures7. Crystal Structure Data
9At the end of this Chapter, you should: ObjectivesAt the end of this Chapter, you should:1. Be able to identify a unit cell in a symmetrical pattern.2. Know that (in 3 dimensions) there are7 Possibleunit cell shapes.3. Be able to define cubic, tetragonal, orthorhombic & hexagonal unit cell shapes
10Experimental Evidence of periodic structures. (See Kittel, Fig. 1.) Periodic Arrays of AtomsExperimental Evidence of periodic structures. (See Kittel, Fig. 1.)The external appearance of crystals gives some clues to this. Fig. 1 shows that when a crystal is cleaved, we can see that it is built up of identical “building blocks”. Further, the early crystallographers noted that the index numbers that define plane orientations are exact integers.Cleaving a Crystal
12The Three General Types of Solids Single CrystalPolycrystallineAmorphousEach type is characterized by the size ofthe ordered region within the material.An ordered region is a spatial volume in which atoms ormolecules have a regular geometric arrangement or periodicity.
13Crystalline SolidsA Crystalline Solid is the solid form of a substance in which the atoms or molecules are arranged in a definite, repeating pattern in three dimensions.Single Crystals, ideally have a high degree of order, or regular geometric periodicity, throughout the entire volume of the material.
14A Single Crystal has an atomic structure that repeats periodically across its whole volume. Even at infinite length scales, each atom is related to every other equivalent atom in the structure by translational symmetry.Single CrystalsSingle PyriteCrystalAmorphousSolid
15Polycrystalline Solids A Polycrystalline Solid is made up of an aggregate of many small single crystals (crystallites or grains). Polycrystalline materials have a high degree of order over many atomic or molecular dimensions. These ordered regions, or single crystal regions, vary in size & orientation with respect to one another. These regions are called grains (or domains) & are separated from one another by grain boundaries.The atomic order can vary from one domain to the next. The grains are usually 100 nm microns in diameter. Polycrystals with grains that are < 10 nm in diameter are called nanocrystallites.PolycrystallinePyriteGrain
16Amorphous SolidsAmorphous (Non-crystalline) Solids are composed of randomly orientated atoms, ions, or molecules that do not form defined patterns or lattice structures. Amorphous materials have order only within a few atomic or molecular dimensions. They do not have any long-range order, but they have varying degrees of short-range order. Examples of amorphous material include amorphous silicon, plastics, & glasses.
17Departures From the “Perfect Crystal” A “Perfect Crystal” is an idealization that does not exist in nature. In some ways, even a crystal surface is an imperfection, because the periodicity is interrupted there.Each atom undergoes thermal vibrations around their equilibrium positions for temperatures T > 0K. These can also be viewed as “imperfections”.Also, Real Crystals always have foreign atoms (impurities), missing atoms (vacancies), & atoms in between lattice sites (interstitials) where they should not be. Each of these spoils the perfect crystal structure.
18CrystallographyCrystallography ≡ The branch of science that deals with the geometric description of crystals & their internal arrangements. It is the science of crystals & the math used to describe them. It is a VERY OLD field which pre-dates Solid State Physics by about a century! So (unfortunately, in some ways) much of the terminology (& theory notation) of Solid State Physics originated in crystallography. The purpose of Ch. 1 of Kittel’s book is mainly to introduce this terminology to you.
19Started in the early 20th Century when the fact that Solid State PhysicsStarted in the early 20th Century when the fact thatCrystals Can Diffract X-rayswas discovered.This was around the same time that the new theory ofQuantum Mechanicswas being accepted & applied to various problems. Some of the early problems it was applied to were the explanation of observed X-ray diffraction patterns for various crystals & (later) the behavior of electrons in a crystalline solid.
20A Basic Knowledge of Elementary Crystallography is Essential for Solid State Physicists!!!A crystal’s symmetry has a profound influence on many of its properties.A crystal structure should be specified completely, concisely & unambiguously.Structures are classified into different types according to the symmetries they possess.In this course, we only consider solids with “simple” structures.
21(Scanning Tunneling Microscope) Crystal LatticeCrystallography focuses on the geometric properties of crystals. So, we imagine each atom replaced by a mathematical point at the equilibrium position of that atom. A Crystal Lattice (or a Crystal) ≡ An idealized description of the geometry of a crystalline material. A Crystal ≡ A 3-dimensional periodic array of atoms. Usually, we’ll only consider ideal crystals. “Ideal” means one with no defects, as already mentioned. That is, no missing atoms, no atoms off of the lattice sites where we expect them to be, no impurities,…Clearly, such an ideal crystal never occurs in nature. Yet, 85-90% of experimental observations on crystalline materials is accounted for by considering only ideal crystals!PlatinumPlatinum SurfaceCrystal Lattice &Structure of Platinum(Scanning Tunneling Microscope)
22A Lattice is Defined as an Infinite Array of Points in Space Crystal Lattice2 Dimensional ExampleMathematicallyA Lattice is Defined as an Infinite Array of Points in Spacein which each point has identical surroundings to all others. The points are arranged exactly in a periodic manner.αabCBEDOAyx22
23The simplest structural unit for a given solid is called the BASIS Ideal Crystal ≡An infinite periodic repetition of identical structural units in space.The simplest structural unit we can imagine is a Single Atom. This corresponds to a solid made up of only one kind of atom ≡ An Elemental Solid.However, this structural unit could also be a group of several atoms or even molecules.The simplest structural unit for a given solid is called the BASIS
24Crystal Structure ≡ Lattice + Basis The structure of an Ideal Crystal can be described in terms of a mathematical construction called a Lattice.A Lattice ≡A 3-dimensional periodic array of points in space. For a particular solid, the smallest structural unit, which when repeated for every point in the lattice is called the Basis.The Crystal Structure is defined once both the lattice & the basis are specified. That isCrystal Structure≡ Lattice + Basis
25Crystalline Periodicity In a crystalline material, the equilibrium positions of all the atoms form a crystalCrystal Structure ≡ Lattice + BasisFor example, see Fig. 2.Lattice Basis CrystalStructure
26Crystalline Periodicity Crystal Structure ≡ Lattice + BasisFor another example, see the figure.Crystal StructureLatticeBasis