1. OSHA Hazard Communication
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OSHA Hazard Communication
29 CFR Subpart Z
Updated 5 May 2014
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The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

2. Subpart Z Toxic & Hazardous Substances
( – 1450)
Written program
Information and training
SDS’s for each chemical
SDS’s readily accessible
Labeling (old standard)
OSHA Most Cited 2012

3. All chemical manufacturers, importers, distributors and employers
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Phase in Period for GHS into
Hazard Communication Standard
Effective Completion Date Requirements Who
Train employees on the new label elements and SDS format
1 December 2013
Employers
Comply with all modified provisions of this final rule, except
1 June 2015
Chemical manufactures, importers, distributors and employers
Distribution may ship products labeled by manufactures under the old system until 1 December 2015
1 December 2015
Update alternative workplace labeling and hazard communication program as necessary and provide additional employee training for newly identified physical or health hazards
1 June 2016
Employers
Comply with either 29 CFR (final standard) or the current standard or both
All chemical manufacturers, importers, distributors and employers
Transition Period
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

4. What is the Purpose of 1910.1200 (a) Hazards Communication:
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What is the Purpose of (a) Hazards Communication:
(1) Purpose: Is to ensure that the hazards of all chemicals produced or imported are classified and that information concerning the classification hazards is transmitted to the employers and employees
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

5. What is the Purpose of 1910.1200 Hazards Communication:
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What is the Purpose of Hazards Communication:
The requirements of this section are intended to be consistent with the provisions of the United Nations Globally Harmonized System (GHS) of Classification and Labelling of Chemicals
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

6. 4/15/ :46 AM
29 CFR (d) (1)
Chemical manufacturers and importers shall evaluate chemicals produced in their workplaces or imported by them to classify the chemicals in accordance with this section. 
For each chemical, the chemical manufacturer or importer shall determine the hazard classes, and where appropriate, the category of each class that apply to the chemical being classified. 
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

7. 4/15/ :46 AM
29 CFR (d) (1)
Employers are not required to classify chemicals unless they choose not to rely on the classification performed by the chemical manufacturer or importer for the chemical to satisfy this requirement.
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

8. Classification: All hazards to be CLASSIFIED not Evaluated:
Identify the relevant data regarding the hazards of a chemical;
Review those data to ascertain the hazards associated with the chemical
Determine whether the chemical will be classified as hazardous according to the definition of hazardous chemical in this section.  In addition,
Classification for health and physical hazards includes the determination of the degree of hazard,
"Hazard class" means the nature of the physical or health hazards, e.g., flammable solid, carcinogen, oral acute toxicity.

9. Old 1910.1200 Haz Comm Standard: Required an employer to:
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Old Haz Comm Standard:
Required an employer to:
Have a written hazard communication program
Have each hazardous chemical in the workplace labeled
Have a Material Safety Data Sheet (MSDS) for each hazardous chemical in the workplace
Train his/her employees about the hazards associated with and precautionary measures required for each hazardous chemical in the workplace. Training is required initially and anytime a new hazardous chemical is introduces into the workplace.
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

10. How has Haz Comm Changed?
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How has Haz Comm Changed?
Hazards Classification rather than “hazard determination
Labels are more defined and will now require:
Product identifier
Pictogram
Signal word
Hazard statement(s)
Precautionary statement(s)
Name, address, and phone number
Safety Data Sheet (not Material Safety Data Sheet):
Uses a 16 section format
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

11. New Haz Comm Standard has 4 Basic Sections:
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New Haz Comm Standard has 4 Basic Sections:
29 CFR Subpart Z:
Written Program
Labeling and other Warnings
Safety Data Sheets (SDS)
Employee Info and Training
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

12. 1. Written Hazard Comm Program
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The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

13. Written Program 29 CFR 1910.1200 (e) (1)
Employers shall develop, implement and maintain at each workplace, a written hazard communication program which at least describes how the criteria specified in paragraphs (f), (g) and (h) of this section:
Labels and other forms of warning
Safety Data Sheets (SDS)
Employee information and training
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

14. Written Program 29 CFR 1910.1200 (e) (1)
Hazardous Chemical List:
(i) A list of the hazardous chemicals known to be present using a product identifier that is referenced on the appropriate safety data sheet
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

15. Written Program 29 CFR 1910.1200 (e) (1)
Methods:
(ii) The methods the employer will use to inform employees of the hazards of non-routine tasks (example , the cleaning of reactor vessels) and the hazards associated with the chemical contained in unlabeled pipes in their work areas.
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

16. Written Program 29 CFR 1910.1200 (e) (2)
Multi-employer workplaces:
Employers who produce, use or store hazardous chemicals at a workplace in such a way that the employees of other employer may be exposed shall additionally ensure that the hazards communication program developed and implemented under this paragraph:
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

17. Written Program 29 CFR 1910.1200 (e) (1) (2)
Multi-employer workplaces:
The methods the employer will use to provide SDS
The methods the employer will use to inform the other employers of any precautionary measures that need to be taken to protect employees during workplace’s normal operating conditions and in foreseeable emergencies
The methods the employer will use to inform the other employers of the labeling system used in the workplace
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

18. Written Program 29 CFR 1910.1200 (e) (4)
The employer shall make the written hazard communication program available upon request to employees
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

19. What are GHS Categories Hazards?
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What are GHS Categories Hazards?
The categories of hazards are:
Physical
Health
Environmental (non- mandatory)
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

20. GHS Physical Hazards: Explosive Flammable Gases Flammable aerosols
Oxidizing Gases
Gases under Pressure
Flammable Liquids
Self Reactive Substances
Pyrophoric Liquids
Pyrophoric Solids
Self Heating Substance
Substances which in contact
w/ water emit flammable gases
Oxidizing Liquids
Oxidizing Solids
Organic Peroxides
Corrosive to Metals
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

21. GHS Health Hazards: Acute Toxicity Skin Corrosion/Irritation
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GHS Health Hazards:
Acute Toxicity
Skin Corrosion/Irritation
Serious Eye Damage /Eye Irritation
Respiratory or Skin Sensitization
Germ Cell Mutagenicity
Carcinogenicity
Reproductive Toxicology
Target Organ Systemic Toxicity Single Exposure
Aspiration Toxicity
Target Organ Systemic Toxicity – Repeated Exposure
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

22. 2. Labels and other Warnings
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2. Labels and other Warnings
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

23. GHS Labeling Format: There is no label format or layout specified
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GHS Labeling Format:
There is no label format or layout specified
There are required label elements
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

24. GHS Labeling Elements:
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GHS Labeling Elements:
Product Identifier
Supplier Identifier
Hazard pictogram
Signal Word
Hazard statement
Precautionary information
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

25. Labeling Signal Words:
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Labeling Signal Words:
“Danger” or “Warning”
Used to emphasis hazards and indicate relative level of severity of the hazard assigned to a GHS hazard class and category
Only one signal word on a label
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

26. 4/15/ :46 AM
Hazard Statements:
Include appropriate statements for each GHS hazard on labels for products that possess more than one hazard
Examples of required hazards statements:
- Keep away from fire, sparks and heated surfaces
- Do not use in areas without adequate ventilation
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

27. 4/15/ :46 AM
Pictograms:
Pictograms have been standardized to convey health, physical and environmental hazard information, assigned to a GHS hazard class and category
HEALTH HAZARD
FLAME
EXCLAMATION MARK
GAS
CYLINDER
CORROSION
EXPLODING
BOMB
OVER
CIRCLE
ENVIRONMENT
SKULL
&
CROSSBONES
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

28. Pictogram: Health Hazard
Carcinogen
Mutagenicity
Reproductive Toxicity
Respiratory Sensitizer
Target Organ Toxicity
Aspiration Toxicity

29. Pictogram: Flame Flammables Pyrophoric Self-Heating
Emits Flammable Gas
Self-Reactives
Organic Peroxides
Pyrophoric chemicals are liquids and solids that will ignite spontaneously in air at about 130 degrees F.
Titanium dichloride and phosphorus are example of pyrophoric solids; tributylaluminum and related compounds are examples of pyrophoric liquids.
From Wikipedia on organic peroxides:
In polymer chemistry
Organic peroxides find numerous applications, often involving similar chemistry. Thus, peroxides serve as accelerators, activators, cross-linking agents, curing and vulcanization agents, hardeners, polymerisation initiators, and promoters. Drying oils, as found in many paints and varnishes function via the formation of hydroperoxides.
Methyl ethyl ketone peroxide, benzoyl peroxide and to a smaller degree acetone peroxide are used as initiators for radical polymerization of some resins, e.g. polyester and silicone, often encountered when making fiberglass.

30. Pictogram: Exclamation Mark
Irritant (skin and eye)
Skin Sensitizer
Acute Toxicity
Narcotic Effects
Respiratory Tract Irritant
Hazardous to Ozone Layer (Non-Mandatory)
Exclamation mark is for the weaker end.
Irritant (Skin Irritation Category
2 and Eye Irritation Category
2A),
Dermal Sensitizer (Category
1),
Acute Toxicity (Category 4,
harmful),
Target Organ Toxicity/
STOT Category 3 = narcotic
effects, respiratory irritation

31. Pictogram: Gas Cylinder
Gases Under Pressure

32. Pictogram: Corrosion Skin Corrosion/Burns Eye Damage
Corrosive to Metals
Acids have better warning properties than bases. Acids will burn quickly, the victim will seek water, FAST.
Caustics, poor warning properties: slippery feeling, break down proteins in the skin.

33. Pictogram: Exploding Bomb
Explosives
Self-Reactives
Organic Peroxides
Self-reactive Substances
What are unstable chemicals?
Unstable or self-reactive substances are chemicals which have the potential to vigorously polymerize, decompose, condense, or become self-reactive under conditions of shock, pressure, temperature, light, or contact with another material. Major types of highly reactive chemicals are explosives, peroxides, water-reactives, and pyrophorics.
What should I do when handling unstable chemicals?
• Always wear safety goggles, closed toe shoes, and gloves
• Handle under a hood if the reaction has the potential of creating gases
• If there is a chance of explosion, use barriers or other forms of isolation methods
• For some heat sensitive materials, temperature should be controlled.
• Date all containers when received or opened

34. Pictogram: Flame over Circle
Oxidizers
No ignition source (flame is necessary)
Used as rocket fuel in space
Bread with drops of peroxide + leather = hot flame
Mixing concentrated hydrogen peroxide with an organic material, in the presence of a catalyst will react on its own, causing a very hot flame.
Class 1 An oxidizing material whose primary hazard is that it may increase the burning rate of combustible material with which it comes in contact.
Class Rating Hazard Description
Class 2 An oxidizing material that will moderately increase the burning rate or which may cause spontaneous ignition of combustible material with which it comes in contact.
undergo vigorous self-sustained decomposition when catalyzed or exposed to heat.
Class 3 An oxidizing material that will cause a severe increase in the burning rate of combustible material with which it comes in contact or which will
Class 4 An oxidizing material that can undergo an explosive reaction when catalyzed or exposed to heat, shock or friction.
(as Classified by the NFPA)
TABLE 3 - Oxidizing Materials
Class 1
Class Rating Examples
ammonium persulfate
potassium dichromate
aluminum nitrate
potassium persulfate
barium chlorate
potassium nitrate
barium nitrate
sodium carbonate peroxide
barium peroxide
silver nitrate
sodium dichloro-s-triazinetrione
calcium chlorate
calcium peroxide
sodium dichromate
calcium nitrate
cupric nitrate
sodium nitrate
sodium perborate
hydrogen peroxide (8-27.5%)
sodium nitrite
sodium perborate tetrahydrate
lead nitrate
lithium peroxide
sodium perchlorate monohydrate
lithium hypochlorite
sodium persulfate
magnesium perchlorate
strontium chlorate
magnesium nitrate
magnesium peroxide
strontium nitrate
zinc chlorate
nickel nitrate
strontium peroxide
perchloric acid (<60% concen.)
zinc peroxide
nitric acid (<70% conc.)
potassium permanganate
Class 2 calcium hypochlorite (<50% wgt)
chromium trioxide (chromic acid)
sodium chlorite (<40% wgt.)
hydrogen peroxide ( % conc.)
sodium peroxide
halane
trichloro-s-triazinetrione
nitric acid (>70% conc.)
sodium permanganate
potassium chlorate
Class 3 ammonium dichromate
hydrogen peroxide (52-91% conc.)
potassium dichloroisocyanurate
perchloric acid ( % conc.)
sodium chlorate
calcium hypochlorite (>50% wgt.)
potassium bromate
sodium chlorite (>40% wgt.)
guanidine nitrate
ammonium permanganate
Class 4 ammonium perchlorate
perchloric acid (>72.5%)
hydrogen peroxide (>91% conc.)
potassium superoxide

35. Pictogram: Environmental
Aquatic Toxicity
(Non-Mandatory)
Straightforward. Dead fish, dead tree.

36. Pictogram: Skull and Crossbones
Acute Toxicity (fatal or toxic)

37. GHS Labeling Example: 4/15/2017 10:46 AM
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

38. 4/15/ :46 AM
Labeling (f) (8)
The employer is not required to label portable containers into which hazardous chemicals are transferred from labeled containers and which are intended for immediate use of the employee who performs the transfer.
Define immediate use?
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

39. 3. Safety Data Sheets (SDS)
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3. Safety Data Sheets (SDS)
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

40. Safety Data Sheets (SDS)
Prepared by the chemical manufacturer or importer and describes:
Physical hazards, such as fire and explosion
Health hazards, such as signs of exposure
Routes of exposure
Precautions for safe handling and use
Emergency and first-aid procedures
Control measures
Must be readily accessible to employees in their work area
(g)
Chemical manufacturers and importers must develop an MSDS for each hazardous chemical they produce or import, and must provide the MSDS at the time of the initial shipment to a downstream distributor or user. Distributors also must ensure that downstream employers are similarly provided an MSDS.
The MSDSs must be updated by the chemical manufacturer or importer within three months of learning of "new or significant information" regarding the chemical's hazard potential.
OSHA does not require that MSDSs be provided to purchasers of household consumer products (such as "windex" and "white‑out“) when the products are used in the workplace in the same manner that a consumer would use them, i.e.; where the duration and frequency of use (and therefore exposure) is not greater than what the typical consumer would experience. Employees who are required to work with hazardous chemicals in a greater duration and frequency of exposure than a normal consumer have a right to know about the properties of those hazardous chemicals.

41. Old Material Safety Data Sheet (MSDS)
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© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

42. The Standardized SDS Format 1910.1200 (g) (2) (i-xvi)
16 Sections – Standardized format:
Identification
Hazard(s) identification
Composition/information on ingredients
First-aid measures
Fire-fighting measures
Accidental release measures
Handling and storage
Exposure control/personal protection

43. The Standardized SDS Format 1910.1200 (g) (2) (i-xvi)
Format: 16 Sections (cont.):
Physical and chemical properties
Stability and reactivity
Toxicological information
Ecological information
Disposal information
Transport information
Regulatory information
Other information

44. 4/15/ :46 AM
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

45. 4/15/ :46 AM
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

46. 4/15/ :46 AM
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

47. 4/15/ :46 AM
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

48. 4/15/ :46 AM
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

49. 4/15/ :46 AM
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

50. 4/15/ :46 AM
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

51. OSHA Brief Booklet on Haz Comm Labels and Pictograms
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

52. 4. Employee Info and Training
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4. Employee Info and Training
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

53. 4/15/ :46 AM
Haz Comm Training (h)
(1) Employers shall provide employees with effective information and training on hazardous chemicals in their work area:
a. at the time of initial assignment
b. whenever a new chemical hazard the employees have not been previously been trained is introduced into the work area.
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

54. Haz Comm Information 1910.1200 (g)
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Haz Comm Information (g)
(2) Employees shall be informed of:
Any operations in their work area where hazardous chemicals are present
The location and availability of the written communication program
List of all hazardous chemicals
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

55. 4/15/ :46 AM
Haz Comm Training (3)
(i) Methods and observations that may be used to detect the presence or release of a hazardous chemical
(ii) The physical health aspects
(iii) The measures employees can take to protect themselves from these hazardous – PPE
(iv) The details of the hazard communication program developed by the employer – labeling and SDS
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.

56. Summary Hazard Communication 1910.1200 4/15/2017 10:46 AM
© 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries.
The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION.