1. Wacker Oxidation and Wacker-Type Reactions
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2. The Wacker Process

3. Overview on Wacker Oxidation

4. Mechanism of the Wacker Oxidation: High Cl- Concentration

5. Mechanism of the Wacker Oxidation: Low Cl- Concentration

6. By-Products Observed in the Wacker Oxidation: Isomerization of Alkenes

7. By-Products in the Wacker Oxidation: Chlorination Products

8. By-Products in the Wacker Oxidation: Allylic Oxidation Products

9. By-Products in the Wacker Oxidation: Oxidative Cleavage Products

10. Variation to the Classical Wacker Oxidation: Co-Oxidant

11. Variation to the Classical Wacker Oxidation: Co-Oxidant

12. Variation to the Classical Wacker Oxidation: Solid Phase Supported Catalyst

13. Variation to the Classical Wacker Oxidation: Phase Transfert Catalyst

14. Variation to the Classical Wacker Oxidation: Biphasic System

15. Chemoselectivity of Wacker Oxidation: Steric Hindrance

16. Chemoselectivity of Wacker Oxidation: External vs Internal Alkenes

17. Chemoselectivity of Wacker Oxidation: Steric Hindrance

18. Chemoselectivity of Wacker Oxidation: Compatibility with Functional Groups

19. Chemoselectivity of Wacker Oxidation: Compatibility with Functional Groups

20. Wacker-Type External Oxo-Nucleophiles Addition

21. Wacker-Type Amino Cyclisation (Oxidative Amination)

22. Wacker-Type Amino Cyclisation (Oxidative Amination)

23. Proposed Catalytic Cycle for Copper Free Wacker-Type Reaction

24. Wacker-Type External Amino-Nucleophile Addition

25. Asymmetric Wacker-Type Cyclization

26. Asymmetric Wacker-Type Cyclization

27. Catalytic Asymmetric Wacker-Type Cyclization: Limited to Tetrasubstituted Alkenes

28. Catalytic Asymmetric Wacker-Type Cyclization: Limited to Trisubstituted Alkenes

29. Catalytic Asymmetric Wacker-Type Cyclization: 6-Membereds Rings

30. Stereochemistry of the Oxypalladation Step

31. Stereochemistry of the Oxypalladation Step

32. Stereochemistry of the Oxypalladation Step

33. Stereochemistry of the Oxypalladation Step

34. Desymmetrization by Wacker-Type Cyclization

35. Desymmetrization by Wacker-Type Cyclization

36. Anti-Markovnikov Wacker Oxidation

37. Anti-Markovnikov Products: Steric Effect

38. Anti-Markovnikov Products: Proximal Complexing Function

39. Anti-Markonikov Products: Proximal Complexing Function

40. Anti-Markovnikov Products: Proximal Complexing Function

41. Anti-Markovnikov Products: Proximal Double Bond

42. Anti-Markovnikov Oxidative Amination

43. Anti-Markovnikov Products: Cationic Rhodium Complex

44. Formation of Allylic Acetates under Wacker Oxidation Conditions

45. Formation of Allylic Acetates in Wacker Conditions: Effect of Solvent

46. Formation of Branched Allylic Acetates

47. Formation of Branched Allylic Acetates

48. Formation of Linear Allylic Acetates

49. Application to the Total Synthesis of Garsubellin A

50. Application to the Total Synthesis of Calyculin A and B

51. Application to Total Synthesis

52. Conclusion

54. Anti-Markovnikov Products: Cationic Rhodium Complex

55. Anti-Markonikov Products: Proximal Complexing Function

56. To the Frontier of Wacker-Type Reactions: Wacker-Type Heteroannulation Process