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Atomic transitions and electromagnetic waves
The interaction of an assembly of identical atoms with a radiation field spontaneous emission stimulated emission absorption
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Transition rates the photon energy density per unit frequency The interaction of an assembly of identical atoms with a radiation field transition rates the population densities of levels 1 and 2 spontaneous emission stimulated emission absorption
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Determination of the Einstein coefficients
We consider the case where the atoms are in a thermal equilibrium with a blackbody radiation field (Planck’s law) (total downward transition rate = total upward transition rate) (Boltzmann statistics)
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Conclusions for the LASER
We need a large photon concentration, this is achieved in an optical cavity We need population inversion, i.e., The LASER principle is based on non-thermal equilibrium.
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