1. Vincent J. Giblin, General President 1293 Airport Road Beaver, WV 25813 Phone: (304) 253-8674 Fax: (304) 253-7758 E-mail: hazmat@iuoeiettc.org Hazard Communication 29 CFR 1910.1200 & 29 CFR 1926.59

2. This material was produced under grant number 46C5-HT16 from the Occupational Safety and Health Administration, U.S. Department of Labor. It does not necessarily reflect the views or policies of the U.S. Department of Labor, nor does mention of trade names, commercial products, or organizations imply endorsement by the U.S. Government.

3. Operating Engineers National Hazmat Program 3 PURPOSE OF THE STANDARD TO MAKE SURE ALL HAZARDOUS CHEMICALS PRODUCED, IMPORTED, OR USED IN THE U.S. ARE EVALUATED AND THAT THIS INFORMATION IS PASSED ON TO EMPLOYERS AND EMPLOYEES THAT MAY BE EFFECTED.

4. Operating Engineers National Hazmat Program 4 REQUIREMENTS OF EMPLOYER USE ONLY LABELED PRODUCTS. OBTAIN AND PROVIDE MSDS ON ALL PRODUCTS. PROVIDE TRAINING TO ALL EMPLOYEES. HAVE A WRITTEN HAZCOM PROGRAM. –LABELS ON CONTAINERS OR OTHER POSTERS,PLACARDS OR WARNINGS

5. Operating Engineers National Hazmat Program 5 MSDS CONTENTS MANUFACTUER’S INFORMATION. HAZARDOUS INGREDIENTS / PRODUCT IDENITY. PHYSICAL/ CHEMICAL CHARACTERISTICS. FIRE / EXPLOSION DATA. HEALTH HAZARD DATA. PRECAUTIONS/ SAFE HANDLING. CONTROL MEASURES.

6. Operating Engineers National Hazmat Program 6 MANUFACTURER’S INFORMATION WHO MAKES IT. HOW TO CONTACT THE COMPANY. –ADDRESS, PHONE NUMBER, ETC.. DATE PREPARED.

7. Operating Engineers National Hazmat Program 7 HAZARDOUS INGREDIENTS CHEMICAL INFORMATION PEL- PERMISSABLE EXPOSURE LIMITS/ LAW ! TLV’S- THRESHOLD LIMIT VALUES/ ACGIH

8. Operating Engineers National Hazmat Program 8 HAZARDOUS INGREDIENTS STEL- SHORT TERM EXPOSURE LIMIT/ NOT TO EXCEED 15 MIN. IN A WORKING DAY. CEILING- AN EXPOSURE LEVEL THAT CANNOT BE EXCEEDED.

9. Operating Engineers National Hazmat Program 9 TIME WEIGHTED AVERAGE. (TWA) PPM x TIME EXPOSED = TWA 8 HOURS

10. Operating Engineers National Hazmat Program 10 PHYSICAL/ CHEMICAL CHARACTERISTICS APPEARANCE AND ODOR. BOILING POINT. VAPOR PRESSURE AND DENSITY. SPECIFIC GRAVITY. SOLUBILITY. MELTING POINT. EVAPORATION RATE.

11. Operating Engineers National Hazmat Program 11

12. Operating Engineers National Hazmat Program 12

13. Operating Engineers National Hazmat Program 13

14. Operating Engineers National Hazmat Program 14

15. Operating Engineers National Hazmat Program 15 FIRE AND EXPLOSION FLASH POINT. LOWER AND UPPER EXPLOSIVE LIMITS EXTINGUISING MEDIA. SPECIAL FIRE FIGHTING PROCEDURES. UNUSUAL FIRE HAZARDS

16. Operating Engineers National Hazmat Program 16

17. Operating Engineers National Hazmat Program 17

18. Operating Engineers National Hazmat Program 18 REACTIVITY STABILITY. CONDITIONS TO AVOID ( STABILITY) INCOMPATIBILITY. HAZARDOUS DECOMPOSITION PRODUCTS. HAZARDOUS POLYMERIZATION. CONDITIONS TO AVOID. (POLYMERIZATION)

19. Operating Engineers National Hazmat Program 19 HEALTH HAZARDS THIS SECTION SHOULD BE REVIEWED INITIALLY TO DETERMINE POTENTIAL CARCINOGEN AND OTHER SERIOUS HEALTH EFFECTS

20. Operating Engineers National Hazmat Program 20 HEALTH HAZARDS ROUTES OF ENTRY TARGET ORGANS CARCINOGENIC

21. Operating Engineers National Hazmat Program 21 HEALTH HAZARDS SIGNS AND SYMPTOMS OF OVER EXPOSURE. MEDICAL CONDITION AGGRAVATED BY EXPOSURE. EMERGENCY FIRST AID.

22. Operating Engineers National Hazmat Program 22 HEALTH HAZARDS ACUTE- IMMEDIATE AFFECT. CHRONIC-LONG TERM EFFECT. –USUALLY PERMANENTION/NON- REVERSIBLE

23. Operating Engineers National Hazmat Program 23 PRECAUTIONS/ SAFE HANDLING PROCEDURES FOR MATERIAL SPILL/ RELEASE. NEUTRALIZING AGENT. WASTE DISPOSAL. SAFE HANDLING/ STORAGE.

24. Operating Engineers National Hazmat Program 24 CONTROL MEASURES SUBSTITUTION ENGINEERING CONTROLS ADMINISTRATIVE PROCEDURES. PPE

25. This material was produced under grant number 46C5-HT16 from the Occupational Safety and Health Administration, U.S. Department of Labor. It does not necessarily reflect the views or policies of the U.S. Department of Labor, nor does mention of trade names, commercial products, or organizations imply endorsement by the U.S. Government.

26. Operating Engineers National Hazmat Program 26 END This publication was made possible by grant numbers 5 U45 ES06182-13 AND 5 U45 ES09763-13 from the National Institute of Environmental Health Sciences (NIEHS), NIH. Its contents are solely the responsibility of the authors and do not necessarily represent the official views of the NIEHS, NIH.