1. Ternary Compounds

2. Ternary Compound – an ionic compound that contains more than two different elements
Polyatomic ion – an ion that is made up of more than one atom
The charge given to a polyatomic ion applies to the entire group of atoms. The polyatomic ion acts as an individual ion.

3. Examples of polyatomic ions:
Sulfate SO4-2
Phosphate PO4-3
Hydroxide OH-
Because a polyatomic ion exists as a unit, never change the subscripts of the atoms within the ion. If more than one polyatomic ion is needed, place parentheses around the ion and write the appropriate subscript outside the parentheses.

4. Writing the Formula for an Ionic Compound containing a POLYATOMIC ION
Example 1: Write the formula for calcium phosphate. Step 1: Analyze the Problem. First write each ion along with its charge Ca+2 PO4-3

5. Ca+2 ( PO4)-3 Step 2: Solve for the unknown
Six is the smallest number evenly divided by both ionic charges. Therefore a total of six electrons were transferred. The amount of the negative charge of two phosphate ions equals the amount of positive charge of three calcium ions.
Ca+2 ( PO4)-3
“cross charges”

6. Ca+2 (PO4)-3
To use a subscript to indicate more than one unit of a polyatomic ion, you must place the polyatomic ion in parentheses and add the subscript to the outside. The correct formula is :
Ca3(PO4)2

7. Practice Problems Write the correct formulas for each compound
Sodium nitrate
Calcium chlorate
Aluminum carbonate
Potassium sulfate

8. Practice Problems Write the correct formulas for each compound
Magnesium phosphate
Iron (III) nitrate
Copper (I) hydroxide
Sodium acetate

9. Naming Compounds that contain Polyatomic Ions
Naming compounds that contain polyatomic ions is really no different than naming other ionic compounds except that the ending of the name does NOT change.
Name of cation + Name of Polyatomic Ion

10. USE ROMAN NUMERALS Remember, if the 1st element is a TRANSITION METAL
or a
metal with MORE THAN 1 CHARGE
USE ROMAN NUMERALS

11. Practice Problems Name the following compounds.
KOH
Cu(NO3)2
AlPO4

12. Practice Problems Name the following compounds
NaC2H3O2
NaCN
PbSO4