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Pressure
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Define vapour pressure in terms of observable and measurable properties.
Construct and interpret a graph of vapour pressure versus temperature. Describe vaporization at the molecular level using diagrams. Define normal boiling temperature and boiling temperature in terms of vapour pressure.
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Air is a gas...it must also be exerting pressure.
Pressure is defined as force per unit area. Air is a gas...it must also be exerting pressure. Called air pressure or atmospheric pressure.
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The standard unit of atmospheric pressure (at sea level):
1 atmosphere = 760 mmHg = kPa kilopascals millimeters of Mercury
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Closed container (constant temperature)
As liquid continues to vaporize, a point is reached: For every molecule that vapourizes, another condenses (equilibrium)
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equilibrium
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Pressure of gas at equilibrium with its liquid in a closed container is known as the vapour pressure. characteristic physical property
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A manometer measures pressure..
Measures difference in height on both sides.
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IMFs determine the rate of vapourization.
Lower IMFs - faster vapourization - more particles (before equilibrium) - higher vapour pressure.
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Heat increases particles kinetic energy - breaks IMF.
Increases rate of vapourization - pressure increases.
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Boiling – temperature remains constant.
Boiling Point: vapour pressure is equal to atmospheric pressure. (1 atmosphere, kPa, 760 mmHg)
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Strong IMFs need more energy to produce gas with enough pressure to equal atmospheric pressure.
Any change in air pressure will produce a change in the boiling point.
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Longer cooking time to prepare foods at higher altitudes.
At lower pressure the water boils at a lower temperature – longer cooking time.
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