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Median Median Absolute Deviation MAD % Relative Median Absolute Deviation %RMAD = MAD / median x 100.

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Presentation on theme: "Median Median Absolute Deviation MAD % Relative Median Absolute Deviation %RMAD = MAD / median x 100."— Presentation transcript:

1 Median Median Absolute Deviation MAD % Relative Median Absolute Deviation %RMAD = MAD / median x 100

2 Intralaboratory precision Interlaboratory precision Within Between

3  ICP vs colorimetry to analyze P  Calculated CEC  Salt pH  Combustion C and CaCO 3  Nitrate analysis  Scooping versus weighing  Hot-water and Mehlich-3 B  Micropipette method for soil texture

4 ICP vs colorimetry to analyze P

5 ICP vs colorimetric P ICP labs = 39 colorimetric labs = 21

6 ICP vs colorimetric P

7

8 Calculated CEC

9 1 M NH4OAc CEC at pH 7 = sum of bases + acidity Calculated CEC ?

10 Ca Mg K

11

12 Exchangeable acidity = 12.6 – (1.64 x soil pH) – (0.48 SMP buffer pH)

13 Exchangeable acidity = 12 x (7 – SMP buffer pH)

14 Acidity = 8 x (7.5 – SMP buffer pH)

15

16 Salt pH

17 1:1 line

18

19 Nitrate analysis

20 critical value

21 Combustion C and CaCO 3

22

23

24 Scooping versus weighing

25 M3 assumes 1.18 g / cm 3 M1 assumes 1.25 g / cm 3

26 % sand % OM g / cm 3

27 M3 assumes 1.18 g / cm 3 + 40% - 40%

28 1.7 cm 3 scoop & 1.18 g / cm 3

29 Hot-water and Mehlich-3 B

30

31 2 g 20 mL 10 g 20 mL Limit of quantification = 0.05 mg/L

32

33 Micropipette method for soil texture

34 1:1 line


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