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Published bySharleen Bruce Modified over 9 years ago
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Ethanol can be produced industrially by the fermentation of sugar.
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The sugar may come from sources such as molasses (a by-product of the sugar refining industry) or maize starch.
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Fermentation needs yeast, single-celled fungi containing enzymes that catalyse the conversion of sugar to ethanol.
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The mixture is maintained at around 40 °C.
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Fermentation produces up to 15% ethanol by volume, which kills the yeast and stops the process.
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Fermentation also produces carbon dioxide, which may be compressed and sold to fizzy drinks manufacturers.
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Ethanol can be produced industrially by the hydration of ethene with steam.
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A high temperature of about 300 °C is needed.
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A high pressure of about 60 atmospheres, 6000 kPa, is also needed.
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Concentrated phosphoric acid on a silica support is used as a catalyst.
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The two main processes for the industrial production of ethanol, fermentation and hydration of ethene, have different characteristics.
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They have different rates of reaction.
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They produce different percentage yields of ethanol.
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The purities of the initial products are different.
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They have different energy needs and use different types of resources.
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These are the advantages of producing ethanol by hydration of ethene.
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These are the advantages of producing ethanol by fermentation.
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Fermentation has economic and environmental advantages that mean it is often the process of choice, despite the advantages of the direct hydration of ethene.
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Epoxyethane is a cyclic ether.
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Epoxyethane has a three-membered ring structure.
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The ring is strained, with smaller bond angles than usual for an ether. This makes epoxyethane highly reactive.
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The carbon-oxygen bonds are easily broken and epoxyethane is readily hydrolysed by water.
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The reaction produces an alcohol called ethane-1,2-diol (also known as ethylene glycol).
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Ethane-1,2-diol is used as an antifreeze for car engines and in the manufacture of polyesters such as terylene.
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Epoxyethane is manufactured by the reaction between ethene and oxygen.
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A mixture of 5% to 20% ethene in air is heated to around 200 °C.
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It is pressurised to around 20 atmospheres or 2000 kPa.
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A finely divided silver catalyst is used to control the rate of reaction.
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Epoxyethane is very hazardous and its manufacture must be controlled carefully to reduce the risk of explosion.
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Epoxyethane is very hazardous and its manufacture must be controlled carefully to reduce the risk of explosion.
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