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Chapter 6 Notes: Solutions, Acids and Bases
Chapters 22: Solutions Section 1: How Solutions Form Mrs. Chilton
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A. Solutions and Other Mixtures
All matter is either a pure substance or a mixture Types of mixtures Homogeneous = solution; same composition throughout Heterogeneous = not the same composition throughout Pure substances Elements Compounds
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B. Solutions Solution is a homogeneous mixture
Made up of solute and solvent Solute = what is dissolved Solvent = substance doing the dissolving Most common solvent? Water! Why?
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B. Solution Examples KoolAid Unsweet tea Sweetened tea Saltwater
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C. Dissolving Molecules are constantly in motion according to…
Kinetic Theory of Motion When particles collide, energy is transferred When ionic compounds dissolve in water, ions separate in solution Example: NaCl in water becomes Na+ and Cl-
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D. Solvents Water is universal solvent b/c of its polarity
If something can dissolve in something else, it is said to be soluble If it cannot dissolve, it is said to be insoluble “Like dissolves like”
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D. Solvents “Like Dissolves Like” NONPOLAR POLAR
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E. Solvation First... Then... Solvation – the process of dissolving
solute particles are surrounded by solvent particles First... solute particles are separated and pulled into solution Then...
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NaCl(s) Na+(aq) + Cl–(aq)
E. Solvation Dissociation separation of an ionic solid into aqueous ions NaCl(s) Na+(aq) + Cl–(aq)
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E. Solvation Non- Electrolyte Weak Electrolyte Strong Electrolyte
+ sugar - + acetic acid - + salt Non- Electrolyte Weak Electrolyte Strong Electrolyte solute exists as molecules only solute exists as ions and molecules solute exists as ions only
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F. Factors Affecting Solubility
Solubility = amount of a substance that will dissolve in a liquid Smaller pieces of a substance dissolve faster b/c of larger surface area Stirring or shaking speeds dissolving b/c particles are moving faster and colliding more Heating speeds dissolving (see above) Not all substances dissolve
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F. Solubility Solids are more soluble at...
high temperatures. Gases are more soluble at... low temperatures & high pressures (Henry’s Law). EX: nitrogen narcosis, the “bends,” soda
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G. Solubility Solubility Curves
maximum grams of solute that will dissolve in 100 g of solvent at a given temperature varies with temp based on a saturated soln
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G. Solubility Solubility Curve
shows the dependence of solubility on temperature
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HNO3(aq) + H2O(l) H3O+(aq) + NO3–(aq)
B. Solvation Ionization breaking apart of some polar molecules into aqueous ions HNO3(aq) + H2O(l) H3O+(aq) + NO3–(aq)
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B. Solvation C6H12O6(s) C6H12O6(aq) Molecular Solvation
molecules stay intact C6H12O6(s) C6H12O6(aq)
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B. Solvation Soap/Detergent polar “head” with long nonpolar “tail”
dissolves nonpolar grease in polar water
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H. Concentration The more solute or less solvent in a solution, the more concentrated the solution becomes The less solute or more solvent in a solution, the more dilute the solution becomes A saturated solution is one in which no more solute can dissolve A supersaturated solution is one in which the solvent is heated and can dissolve more solute
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H. Concentration UNSATURATED SOLUTION more solute dissolves
no more solute dissolves SUPERSATURATED SOLUTION becomes unstable, crystals form concentration
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Chapter 23 Acids, Bases & Salts
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Review – Acid Names HCl H2SO4 HNO3 H2SO3 HC2H3O2 Hydrochloric acid Sulfuric acid Nitric acid Sulfurous acid Acetic acid
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What are acids? Compounds that donate H+ ions in water Taste sour
Concentrated acids can burn skin and eyes On pH scale, found below 7 Stronger acids closer to 1 Examples: citric acid, stomach acid, soda, coffee
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What are bases? Compounds that donate OH- ions in water
Taste bitter, are slippery Can be dangerous as well Often cleaning products pH above 7 Stronger bases closer to 14 Examples: bleach, baking soda, antacids
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Neutral All neutral solutions have a pH of 7
Water is a neutral solution
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pH Scale
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HCl + NaOH H2O + NaCl Neutralization Example:
Reaction between an acid and a base to produce water and a salt H+ + OH- H2O Example: HCl + NaOH H2O + NaCl Do not always produce a neutral solution
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Indicators Chemical dyes whose color are affected by acidic and basic solutions are called acid-base indicators
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Summary BASES ACIDS electrolytes electrolytes sour taste
bitter taste turn litmus red turn litmus blue Donate H+ (HCl) Donate OH- (NaOH) vinegar, milk, soda, apples, citrus fruits ammonia, lye, antacid, baking soda
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