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Modern Chemistry Chapter 5 The Periodic Law

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Presentation on theme: "Modern Chemistry Chapter 5 The Periodic Law"— Presentation transcript:

1 Modern Chemistry Chapter 5 The Periodic Law
Sections 1-3 History of the Periodic Table Electron Configurations and the Periodic Table Electron Configurations and Periodic Properties Chapter 5 Section 1 History of the Periodic Table pages

2 Electron Configurations and periodic properties
Section 3 Electron Configurations and periodic properties Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

3 Section 3 Vocabulary Atomic radius Ion Ionization Ionization Energy
Electron affinity Cation Anion Valence electrons Electronegativity Section 3 Vocabulary Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

4 Atomic Radii One half the distance between the nuclei of identical atoms bonded together p. 150 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

5 Atomic Radii Period Trend  Atomic radii decreases across a period
Electrons are added to the s and p in the same energy level Protons are added to the nucleus The nucleus is stronger and pulls in the electrons making the atom smaller Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

6 Atomic Radii Group Trend  Practice on page 152
Atomic radii increases down a group Exeption Al to Ga in group 13 Electrons exist in higher energy levels further from the nucleus Practice on page 152 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

7 Atomic radius image p. 151* Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

8 Ionization: any process that results in the formation of an ion
Ionization Energy Ion: an atom or group of bonded atoms that has a positive or negative charge Ionization: any process that results in the formation of an ion Ionization energy: The energy required to remove one electron from a neutral atom. Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

9 ion animation Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

10 First ionization energy = IE1 (energy to remove one electron)
Diagram on Page 153 and 154 A + energy  A+ + e- Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

11 Ionizaiton Energy Comic
p. ## Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

12 Ionization energy animation
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

13 Ionization energy vs. atomic number graph
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

14 Ionization Energy Period Trend  IE increases across a period
Increased nuclear charge holds e- thighter Elements with low IE lose e- easily Elements with high IE do not lose e- Generally nonmetals have higher IE than metals Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

15 Ionization Energy Group Trend  IE decreases down a group
An electron is removed from higher energy levels further from the nucleus In elements with many electron, the inner electrons in lower energy levels shield the outer electrons in the higher energy levels from the attraction of the nucleus Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

16 Ionization energy image
p. 153* Decrease Increase Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

17 Removing electrons from positive ions
Ionization Energy Removing electrons from positive ions More than one electron can be removed from an atom Second ionization energy = IE2 IE2 is higher than IE1 Because few electrons remain to shield the outer electrons from the nucleus Table on page 155 Practice page 156 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

18 1st- 5th Ionization energy chart
p. 55 Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

19 Electron Affinity The energy change that occurs when an electron is acquired by a neutral atom A + e-  A- + energy or A + e- + energy  A- Positive or less negative EA won’t likely gain electrons More negative EA will gain electrons easily Energy is released negative number Energy is absorbed positive number Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

20 Electron Affinity animation
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

21 Electron affinity Period Trend 
EA increases across the period (more neg.) Exception between group 14 and 16 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

22 Electron affinity Group Trend  EA decreases down a group (less neg.)
An increase in protons increases EA but an increase in radius decreases EA Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

23 Electron Affinity image
p. 157* Decrease Increase Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

24 Adding electrons to negative ions
Electron affinity Adding electrons to negative ions More difficult to add a second eletron All second EA are positive Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

25 Ionic Radii Positive Ions Cation Loss of electron
Smaller electron cloud; loss of highest energy level Electrons are drawn closer to the nucleus Na Na+ Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

26 Ionic Radii Negative ion Anions Gaining of electrons
The electron cloud spreads out because of the repeling of electrons Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

27 Cation - positive Anion - negative
ions Cation - positive Anion - negative Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

28 Ionic Radii Period Trend  Ionic radii decreases across a period
As protons increase the electrons are pulled in Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

29 Ionic Radii Group Trend  Ionic Radii increases down a group
More electrons in higher energy levels Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

30 Ionic RADIUS Image p. 159* Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

31 Located in the incompletely filled main energy level
Valence electrons Electrons available to be lost, gained or shared in the formation of compounds. Located in the incompletely filled main energy level For main group elements – outer s & p sublevels Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

32 Valence electrons animation
p. ## Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

33 Linus Pauling devised a scale from 0-4.
electronegativity A measure of an atom in a compound to attract electrons from another atom in the compound Linus Pauling devised a scale from 0-4. Fluorine is the most electronegative EN = 4.0 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

34 Electronegativities p.161
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

35 electronegativity animation
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

36 electronegativity Period Trend  EN increases across a period
There are exceptions. Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

37 electronegativity Group Trend  Practice Page 162
EN decreases down a group Practice Page 162 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

38 Electronegativity Electronegativity Decrease Increase p. 160*
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

39 Periodic Properties of the d and F block elements
Many exceptions in atomic radii, IE, and EN Most d block elements from 2+ ions Group 3 from 3+ ions Copper forms 1+ and 2+ ions Iron forms 2+ and 3+ ions Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages

40 Summary of trends Image
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages

41 Section 3 Homework Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages


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