1. (b) Analytical solutions of the material balance equation Using numerical method: Euler method or 4 th order Runge-Kutta method to Integrate the differential equation set.

2. Fig. 1 Snapshots of stationary 2D spots (A) and stripes (B) in a thin layer and 2D images of the corresponding 3D structures (A→B, C; B→E to G) in a capillary. T Bánsági et al. Science 2011;331:1309-1312 Published by AAAS

3. Fig. 3 Stationary structures in numerical simulations. T Bánsági et al. Science 2011;331:1309-1312 Published by AAAS Stationary structures in numerical simulations. Spots (A), hexagonal close-packing (B), labyrinthine (C), tube (D), half-pipe (E), and lamellar (F) emerging from asymmetric [(A), (B), and (E)], symmetric [(D) and (F)], and random (C) initial conditions in a cylindrical domain. Numerical results are obtained from the model: dx/dτ = (1/ε)[fz(q – x)/(q + x) + x(1 – mz)/(ε1 + 1 – mz) – x2] + ∇ 2 x; dz/dτ = x(1 – mz)/(ε1 + 1 – mz) – z + dz ∇ 2 z, where x and z denote the activator, HBrO2 and the oxidized form of the catalyst, respectively; dz is the ratio of diffusion coefficients Dz/Dx; and τ is the dimensionless time. Parameters (dimensionless units): q = 0.0002; m = 0.0007; ε1 = 0.02; ε = 2.2; f = (A) 1.1, (B) 0.93, [(C) to (F)] 0.88; and dz = 10. Size of domains (dimensionless): diameter = 20 [(A) to (C) and (F)]; 14 [(D) and (E)]; height = 40.

4. Transition State Theory (Activated complex theory) Using the concepts of statistical thermodynamics. Steric factor appears automatically in the expression of rate constants.

5. 24.4 The Eyring equation The transition state theory pictures a reaction between A and B as proceeding through the formation of an activated complex in a pre-equilibrium: A + B ↔ C ‡ ( `‡` is represented by `±` in the math style) The partial pressure and the molar concentration have the following relationship: p J = RT[J] thus The activated complex falls apart by unimolecular decay into products, P, C ‡ → P v = k ‡ [C ‡ ] So Define v = k 2 [A][B]

6. (a) The rate of decay of the activated complex k ‡ = κv where κ is the transmission coefficient. κ is assumed to be about 1 in the absence of information to the contrary. v is the frequency of the vibration-like motion along the reaction-coordinate.

7. (b) The concentration of the activated complex Based on Equation 17.54 (or 20.54 in 7 th edition), we have with ∆E 0 = E 0 (C ‡ ) - E 0 (A) - E 0 (B) are the standard molar partition functions. provided hv/kT << 1, the above partition function can be simplified to Therefore we can write q C‡ ≈ where denotes the partition function for all the other modes of the complex. K ‡ =

8. (c) The rate constant combine all the parts together, one gets then we get (Eyring equation) To calculate the equilibrium constant in the Eyring equation, one needs to know the partition function of reactants and the activated complexes. Obtaining info about the activated complex is a challeging task.

9. (d) The collisions of structureless particles A + B → AB Because A and B are structureless atoms, the only contribution to their partition functions are the translational terms:

10. 24.5 Thermodynamic aspects

11. Kinetics Salt Effect Ionic reaction A + B ↔C ‡ C ‡ → P d[P]/dt = k ‡ [C ‡ ] the thermodynamic equilibrium constant Then d[P]/dt = k 2 [A][B] Assuming is the rate constant when the activity coefficients are 1 ( ) Debye-Huckle limiting law with A = 0.509 log(k 2 ) = log( ) + 2AZ A Z B I 1/2 (Analyze this equation)

12. Experimental tests of the kinetic salt effect

13. Example: The rate constant for the base hydrolysis of [CoBr(NH 3 ) 5 ] 2+ varies with ionic strength as tabulated below. What can be deduced about the charge of the activated complex in the rate-determining stage? I0.00500.01000.01500.02000.02500.0300 k/k o 0.7180.6310.5620.5150.4750.447 Solution: I 1/2 0.0710.1000.1220.1410.1580.173 Log(k/k o )-0.14-0.20-0.25-0.29-0.32-0.35

14. 24.6 Reactive Collisions Properties of incoming molecules can be controlled: 1. Translational energy. 2. Vibration energy. 3. Different orientations. The detection of product molecules: 1. Angular distribution of products. 2. Energy distribution in the product.

15. Detection techniques

17. 24.7 Potential energy surface Can be constructed from experimental measurements or from Molecular Orbital calculations, semi-empirical methods,…… Contour plot

18. Potential energy is a function of the relative positions of all the atoms taking part in the reaction.

19. Potential energy surfaces, pt. 2.

20. Various trajectories through the potential energy surface

21. 24.8 Results from experiments and calculations (a) The direction of the attack and separation

22. Attractive and repulsive surfaces

23. Crossing crowded dance floors. S Bradforth Science 2011;331:1398-1399 Published by AAAS

24. Classical trajectories