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Chemical Reaction Engineering Asynchronous Video Series Chapter 7, Part 1: PSSH Enzyme Kinetics H. Scott Fogler, Ph.D.

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Presentation on theme: "Chemical Reaction Engineering Asynchronous Video Series Chapter 7, Part 1: PSSH Enzyme Kinetics H. Scott Fogler, Ph.D."— Presentation transcript:

1 Chemical Reaction Engineering Asynchronous Video Series Chapter 7, Part 1: PSSH Enzyme Kinetics H. Scott Fogler, Ph.D.

2 Active Intermediates/Free Radicals

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4 Mechanism:

5 Active Intermediates/Free Radicals Mechanism:

6 Active Intermediates/Free Radicals Mechanism:

7 Active Intermediates/Free Radicals Mechanism:

8 Pseudo Steady State Hypothesis (PSSH) A * is an active intermediate that is highly reactive. It disappears as fast as it is formed.

9 Pseudo Steady State Hypothesis (PSSH) A * is an active intermediate that is highly reactive. It disappears as fast as it is formed.

10 Pseudo Steady State Hypothesis (PSSH) A * is an active intermediate that is highly reactive. It disappears as fast as it is formed.

11 Pseudo Steady State Hypothesis (PSSH) A * is an active intermediate that is highly reactive. It disappears as fast as it is formed.

12 Pseudo Steady State Hypothesis (PSSH) A * is an active intermediate that is highly reactive. It disappears as fast as it is formed.

13 Pseudo Steady State Hypothesis (PSSH) A * is an active intermediate that is highly reactive. It disappears as fast as it is formed.

14 Pseudo Steady State Hypothesis (PSSH)

15 Enzymes: Michaelis-Menten Kinetics

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18 Urea Decomposition A given enzyme can only catalyze only one reaction. Urea is decomposed by the enzyme urease, as shown below.

19 Urea Decomposition A given enzyme can only catalyze only one reaction. Urea is decomposed by the enzyme urease, as shown below.

20 Urea Decomposition A given enzyme can only catalyze only one reaction. Urea is decomposed by the enzyme urease, as shown below. Rate Laws:

21 Urea Decomposition A given enzyme can only catalyze only one reaction. Urea is decomposed by the enzyme urease, as shown below. Rate Laws:

22 Urea Decomposition A given enzyme can only catalyze only one reaction. Urea is decomposed by the enzyme urease, as shown below. Rate Laws: If

23 Urea Decomposition

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27 V MAX rPrP S KmKm

28 Urea Decomposition

29 Types of Enzyme Inhibition

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